Day: October 11, 2021

Recommanded Product: 1-(4-Nitrophenyl)ethanone. I found the field of Chemistry very interesting. Saw the article Acetyl nitrate mediated conversion of methyl ketones to diverse carboxylic acid derivatives published in 2021.0, Reprint Addresses Perez, LJ (corresponding author), Rowan Univ, Dept Chem & Biochem, 201 Mullica Hill Rd, Glassboro, NJ 08028 USA.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone.

The development of a novel acetyl nitrate mediated oxidative conversion of methyl ketones to carboxylic acid derivatives is described. By analogy to the haloform reaction and supported by experimental and computational investigation we propose a mechanism for this transformation.

Recommanded Product: 1-(4-Nitrophenyl)ethanone. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Capilato, JN; Pellegrinelli, PJ; Bernard, J; Schnorbus, L; Philippi, S; Mattiucci, J; Hoy, EP; Perez, LJ or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Detection of endogenous hydrogen peroxide in living cells with para-nitrophenyl oxoacetyl rhodamine as turn-on mitochondria-targeted fluorescent probe WOS:000513878700018 published article about REACTIVE OXYGEN; SELECTIVE DETECTION; CANCER; EMISSION; ACID in [Gu, Tianchu; Mo, Shanyan; Mu, Yingqi; Huang, Xin; Hu, Liming] Beijing Univ Technol, Coll Life Sci & Bioengn, Beijing Key Lab Environm & Oncol, Beijing 100124, Peoples R China in 2020.0, Cited 54.0. HPLC of Formula: C8H7NO3. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

Hydrogen peroxide (H2O2) is a small molecule of reactive oxygen species, mainly produced by cell mitochondria, which plays an important role in physiological processes. Excess of H2O2 in normal cells could causes a variety of diseases. For that reason, it is very significant to emerge a detection method with high-precision for H2O2. Herein, we reported a structurally novel fluorescent probe, para-nitrophenyl oxoacetyl rhodamine (RhB-NIR) for the detection of H2O2 levels in living cells. The results show that the Stokes shift for RhB-NIR is 140 nm, much larger than those for other reported rodamine derivatives. RhB-NIR shows satisfactory specificity and high sensitivity for the detection of H2O2. Excellent linear relationship with H2O2 within a certain concentration range (0-10 mu M) was displayed, and the limit of detection (LOD) is 61 nM. More importantly, RhB-NIR realized fluorescence imaging of H2O2 in living cells. In addition, RhB-NIR also shows great potential for targeting mitochondria in cell colocalization experiments, in which the Pearson’s coefficient is 0.91 using Rhodamine 123 as a reference. This probe will be a promising tool for detecting H2O2 in the future research.

About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Gu, TC; Mo, SY; Mu, YQ; Huang, X; Hu, LM or concate me.. HPLC of Formula: C8H7NO3

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Name: 1-(4-Nitrophenyl)ethanone. I found the field of Polymer Science very interesting. Saw the article High-performance polyimides based on pyridine and xanthene pendant groups; synthesis, characterization, photoactivity, thermal, antibacterial, and Cr(VI) ion adsorption properties published in 2020.0, Reprint Addresses Amininasab, SM (corresponding author), Univ Kurdistan, Fac Sci, Dept Chem, Polymer Chem Res Lab, Sanandaj 6617715175, Iran.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone.

A group of new polyimides (PIs) containing xanthene bulky groups and heterocyclic pyridine ring were synthesized by polycondensation reaction by using new symmetric and asymmetric diamines with available dianhydrides. The prepared diamines and PIs were characterized by Fourier transform infrared, elemental analysis, and proton nuclear magnetic resonance spectroscopy and carbon nuclear magnetic resonance spectroscopy. The PIs have desirable solubility in common aprotic solvents like dimethyl sulfoxide, N-methyl-2-pyrrolidone, dimethylacetamide, and pyridine as a less polar solvent. The PIs with inherent viscosities in the range of 0.51-0.72 dL/g were amorphous in nature, showed glass transition temperatures (T(g)s) of about 270-300 degrees C, and 10% weight loss at temperatures 384-443 degrees C. They showed fluorescence emission (quantum yield 7-12%) due to the presence of xanthene and pyridine groups in their structure. The prepared PIs showed tensile strength of 81-91 MPa with elongation at break of 19-23%. The antibacterial properties of the PIs against Gram negative and Gram positive bacteria and funguses were investigated. Also, a membrane of PI prepared by electrospinning method was used for the removal of different concentrations of Cr(VI) from aqueous solutions.

About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Amininasab, SM; Esmaili, S; Shami, Z or concate me.. Name: 1-(4-Nitrophenyl)ethanone

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Visible-light-driven photochemical activity of ternary Ag/AgBr/TiO(2)nanotubes for oxidation C(sp(3))-H and C(sp(2))-H bonds WOS:000579576200011 published article about AG-AT-AGCL; HIGHLY EFFICIENT; SELECTIVE OXIDATION; PHOTOCATALYTIC ACTIVITY; BENZYL ALCOHOL; AEROBIC OXIDATION; ESCHERICHIA-COLI; STYRENE; EPOXIDATION; DEGRADATION in [Hosseini-Sarvari, Mona; Dehghani, Abdulhamid] Shiraz Univ, Dept Chem, Shiraz 7194684795, Iran in 2020.0, Cited 79.0. SDS of cas: 100-19-6. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

The Ag/AgBr/TiO2 ternary component nanotube as a heterogeneous photocatalyst was used for the solvent-free oxidation of the benzylic C(sp(3))-H bond to the corresponding carbonyl compound or the solvent-controlled selective oxidative cleavage of the CQC double bond of styrene to benzaldehyde under visible light at room temperature. A wide variety of carbonyl compounds were successfully synthesized through the developed photocatalytic process. Several advantages such as solvent-free conditions, sans additional oxidant, simple reaction, short reaction time, and easy separation of the product promote the reaction to be green. Moreover, the Ag/AgBr/TiO2 nanotubes could be used several times without reduction in their photocatalytic activity.

SDS of cas: 100-19-6. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Hosseini-Sarvari, M; Dehghani, A or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Yamamoto, Y; Fukui, M; Tanaka, A; Hashimoto, K; Kominami, H in [Yamamoto, Yuhei; Fukui, Makoto] Kindai Univ, Interdisciplinary Grad Sch Sci & Engn, Mol & Mat Engn, 3-4-1 Kowakae, Higashiosaka, Osaka 5778502, Japan; [Tanaka, Atsuhiro; Hashimoto, Keiji; Kominami, Hiroshi] Kindai Univ, Dept Appl Chem, Fac Sci & Engn, 3-4-1 Kowakae, Higashiosaka, Osaka 5778502, Japan published Hydrogen-and noble metal-free conversion of nitro aromatics to amino aromatics having reducible groups over an organically modified TiO2 photocatalyst under visible light irradiation in 2019.0, Cited 42.0. SDS of cas: 100-19-6. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

A titanium.IV) oxide photocatalyst modified with 2,3-dihydroxynaphthalene (DHN/TiO2) responds to visible light, and electrons are photogenerated to the conduction band of TiO2 under light irradiation in the presence of a suitable hole scavenger. The reducing potential of DHN/TiO2 was applied for photocatalytic conversion of a nitro group to an amino group of aromatics having other reducible groups under hydrogenfree and noble metal-free conditions at room temperature. Various nitro aromatics having vinyl, chloro, bromo, and acetyl groups were converted to amino aromatics with high yields with the reducible groups being preserved. Some parameters affecting the catalytic performance were investigated, and the reaction rate was almost determined by the amount of the substrate adsorbed on DHN/TiO2.

About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Yamamoto, Y; Fukui, M; Tanaka, A; Hashimoto, K; Kominami, H or concate me.. SDS of cas: 100-19-6

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Category: benzodioxans. Liu, LL; Wang, N; Dai, CY; Han, Y; Yang, S; Huang, ZB; Zhao, YS in [Liu, Lingling; Wang, Ning; Dai, Chenyang; Han, Yi; Yang, Shan; Huang, Zhibin; Zhao, Yingsheng] Soochow Univ, Coll Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, 199 Renai St, Suzhou 215123, Jiangsu, Peoples R China published Rh(III)-Catalyzed Direct Amination of Aromatic Ketoximes Enabled by Potassium Acetate in 2019.0, Cited 54.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

A method to achieve rhodium(III)-catalyzed, potassium acetate enabled intermolecular C-H amination of ketoximes using various benzenesulfonamide, especially 4-nitrobenzenesulfonamide is reported. Various aryl ketoximes substituted with electron-withdrawing functional groups were all well tolerated and produced the corresponding products in moderate to good yields. A preliminary mechanistic study revealed that potassium acetate is essential to realizing intermolecular amination.

Category: benzodioxans. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Liu, LL; Wang, N; Dai, CY; Han, Y; Yang, S; Huang, ZB; Zhao, YS or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

In 2019 NAT CHEM published article about CROSS-COUPLINGS; ALKYL BROMIDES; ACETYLENE; NICKEL; ARYL; METHODOLOGY; DERIVATIVES; ALDEHYDES; HYDROGEN; IODIDES in [Dong, Xiao-Yang; Zhang, Yu-Feng; Ma, Can-Liang; Wang, Fu-Li; Jiang, Sheng-Peng; Liu, Xin-Yuan] Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen, Guangdong, Peoples R China; [Dong, Xiao-Yang; Zhang, Yu-Feng; Ma, Can-Liang; Gu, Qiang-Shuai; Wang, Fu-Li; Li, Zhong-Liang; Jiang, Sheng-Peng; Liu, Xin-Yuan] Southern Univ Sci & Technol, Dept Chem, Shenzhen, Guangdong, Peoples R China; [Gu, Qiang-Shuai; Li, Zhong-Liang] Southern Univ Sci & Technol, Acad Adv Interdisciplinary Studies, Shenzhen, Guangdong, Peoples R China in 2019, Cited 54. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3. Category: benzodioxans

Continued development of the Sonogashira coupling has made it a well established and versatile reaction for the straightforward formation of C-C bonds, forging the carbon skeletons of broadly useful functionalized molecules. However, asymmetric Sonogashira coupling, particularly for C(sp(3))-C(sp) bond formation, has remained largely unexplored. Here we demonstrate a general stereoconvergent Sonogashira C(sp(3))-C(sp) cross-coupling of a broad range of terminal alkynes and racemic alkyl halides (>120 examples) that are enabled by copper-catalysed radical-involved alkynylation using a chiral cinchona alkaloid-based P,N-ligand. Industrially relevant acetylene and propyne are successfully incorporated, laying the foundation for scalable and economic synthetic applications. The potential utility of this method is demonstrated in the facile synthesis of stereoenriched bioactive or functional molecule derivatives, medicinal compounds and natural products that feature a range of chiral C(sp(3))-C(sp/sp(2)/sp(3)) bonds. This work emphasizes the importance of radical species for developing enantioconvergent transformations.

Category: benzodioxans. About 2,2-Diphenylacetonitrile, If you have any questions, you can contact Dong, XY; Zhang, YF; Ma, CL; Gu, QS; Wang, FL; Li, ZL; Jiang, SP; Liu, XY or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article ZrO2/SO42-/Cu as a Multifunctional, Durable, Efficient, and Heterogeneous Recoverable Inorgano-Nanocatalyst for the Green Preparation of Quinolines WOS:000479139200018 published article about SULFATED ZIRCONIA; FRIEDLANDER SYNTHESIS; SCHIFF-BASES; SOLVENT-FREE; CATALYST; COMPLEX; ACID; ALCOHOLS; NANOPARTICLES; ZRO2 in [Nasseri, Mohammad Ali; Alavi, Seyyedeh Ameneh; Kazemnejadi, Milad; Allahresani, Ali] Univ Birjand, Fac Sci, Dept Chem, POB 97175-615, Birjand, Iran in 2019.0, Cited 55.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Recommanded Product: 100-19-6

An efficient, simple and highly versatile method for the preparation of quinoline derivatives was developed via the Friedlander annulation reaction of 2-aminoarylketones with carbonyl compounds using copper-incorporated sulfated zirconium oxide (ZrO2/SO42-/Cu) as a heterogeneous recyclable nanocatalyst. The catalyst was characterized by FTIR, TG-DTG, XRD, EDX, FE-SEM and TEM analyses. Surface acidity of the catalyst was measured by pyridine adsorption followed by FTIR spectroscopy. The catalyst contains various Lewis- and Bronsted acid sites, which along with the incorporated copper, provides high to excellent yields for all compounds in water as a green solvent at room temperature for short reaction times. The catalyst could be efficiently reused for several runs without any appreciable loss of activity. In addition, the scalability of the process was investigated in this work. Finally, a plausible reaction mechanism was suggested for this transformation.

About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Nasseri, MA; Alavi, SA; Kazemnejadi, M; Allahresani, A or concate me.. Recommanded Product: 100-19-6

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

I found the field of Chemistry very interesting. Saw the article Synthesis of Pyrido[2,3-b]indoles via Bronsted-Acid-Promoted Decarboxylative Annulation of 3-Bromopropenals and Ethyl 2-Amino-1H-indole-3-carboxylates published in 2020.0. Product Details of 100-19-6, Reprint Addresses Yao, CF (corresponding author), Natl Taiwan Normal Univ, Dept Chem, Taipei, Taiwan.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone

The present methodology describes a versatile pathway to furnish alpha-carbolines from relatively stable 2-amino indole derivatives and 3-bromopropenal. High substrate tolerance, nonmetallic, more efficient, and mild reaction conditions are important aspects.

Product Details of 100-19-6. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Yang, TH; Kavala, V; Kuo, CW; Yao, CF or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

I found the field of Plant Sciences; Pharmacology & Pharmacy very interesting. Saw the article Usnic Acid Enaminone-Coupled 1,2,3-Triazoles as Antibacterial and Antitubercular Agents published in 2020. Category: benzodioxans, Reprint Addresses Kantevari, S (corresponding author), CSIR Indian Inst Chem Technol, Fluoro & Agrochem Div, Hyderabad 500007, Telangana, India.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone

(+)-Usnic acid, a product of secondary metabolism in lichens, has displayed a broad range of biological properties such as antitumor, antimicrobial, antiviral, anti-inflammatory, and insecticidal activities. Interested by these pharmacological activities and to tap into its potential, we herein present the synthesis and biological evaluation of new usnic acid enaminone-conjugated 1,2,3-triazoles 10-44 as antimycobacterial agents. (+)-Usnic acid was condensed with propargyl amine to give usnic acid enaminone 8 with a terminal ethynyl moiety. It was further reacted with various azides A1-A35 under copper catalysis to give triazoles 10-44 in good yields. Among the synthesized compounds, saccharin derivative 36 proved to be the most active analogue, inhibiting Mycobacterium tuberculosis (Mtb) at an MIC value of 2.5 mu M. Analogues 16 and 27, with 3,4-difluorophenacyl and 2-acylnaphthalene units, respectively, inhibited Mtb at MIC values of 5.4 and 5.3 mu M, respectively. Among the tested Gram-positive and Gram-negative bacteria, the new derivatives were active on Bacillus subtilis, with compounds 18 [3-(trifluoromethyl)phenacyl] and 29 (N-acylmorpholinyl) showing inhibitory concentrations of 41 and 90.7 mu M, respectively, while they were inactive on the other tested bacterial strains. Overall, the study presented here is useful for converting natural (+)-usnic acid into antitubercular and antibacterial agents via incorporation of enaminone and 1,2,3-triazole functionalities.

Category: benzodioxans. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Bangalore, PK; Vagolu, SK; Bollikanda, RK; Veeragoni, DK; Choudante, PC; Misra, S; Sriram, D; Sridhar, B; Kantevari, S or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem