70918-54-6, Name is (S)-1,4-Benzodioxane-2-carboxylic acid, belongs to benzodioxans compound, is a common compound. Product Details of 70918-54-6In an article, once mentioned the new application about 70918-54-6.
Cycloalkylation of C(sp3)-H Bond with Neighboring Carboxylic Acid as Traceless Activating Group
Selective functionalization of inert C(sp3)-H bond is one of cutting-edge challenges in chemical synthesis. A novel strategy for selective C(sp3)-H bond cycloalkylation is developed with neighboring carboxylic acid as a traceless activating group. Primary and secondary alkyl carboxylic acids undergo decarboxylation/alpha-C(sp3)-H cleavage/cycloalkylation to give the five-membered cyclization products, while tertiary acids undergo decarboxylation/beta-C(sp3)-H cleavage/cycloalkylation to generate the six-membered cyclization products.
Do you like my blog? If you like, you can also browse other articles about this kind. Thanks for taking the time to read the blog about 70918-54-6
Reference£º
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem