Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner.In a patent, 20632-12-6, name is 1-(2,3-Dihydrobenzo[b][1,4]dioxin-6-yl)propan-1-one, introducing its new discovery. Quality Control of 1-(2,3-Dihydrobenzo[b][1,4]dioxin-6-yl)propan-1-one
Cu-Catalyzed [3 + 3] Annulation for the Synthesis of Pyrimidines via beta-C(sp3)-H Functionalization of Saturated Ketones
A novel, efficient, and facile approach for the synthesis of structurally important pyrimidines has been successfully developed by Cu-catalyzed and 4-HO-TEMPO-mediated [3 + 3] annulation of commercially available amidines with saturated ketones. This method provides a new protocol for the synthesis of pyrimidines by a cascade reaction of oxidative dehydrogenation/annulation/oxidative aromatization via direct beta-C(sp3)-H functionalization of saturated ketones followed by annulation with amidines.
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 20632-12-6, help many people in the next few years.Quality Control of 1-(2,3-Dihydrobenzo[b][1,4]dioxin-6-yl)propan-1-one
Reference£º
Benzodioxan,
1,4-Benzodioxane | C8H8O2 – PubChem