SDS of cas: 100-19-6. Recently I am researching about C-H; DIRECT ACYLOXYLATION; BENZOXYLATION; BONDS; ACTIVATION; ARYL; NOX, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21361130021]; China Postdoctoral Science FoundationChina Postdoctoral Science Foundation [2014M560494]; Postdoctoral Science Foundation of Zhejiang ProvinceChina Postdoctoral Science Foundation. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Xiong, X; Mao, YJ; Hao, HY; He, YT; Xu, ZY; Luo, G; Lou, SJ; Xu, DQ. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone
A nitrate-promoted Pd-catalysed mild cross-dehydrogenative C(sp(2))-H bond oxidation of oximes or azobenzenes with diverse carboxylic acids has been developed. In contrast to the previous catalytic systems, this protocol features mild conditions (close to room temperature for most cases) and a broad substrate scope (up to 64 examples), thus constituting a versatile method to directly prepare diverseO-aryl esters. Moreover, the superiority of the nitrate additive in this mild transformation was further determined by experimental and computational evidence.
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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem