SDS of cas: 100-19-6. Goswami, B; Feuerstein, TJ; Yadav, R; Koppe, R; Lebedkin, S; Kappes, MM; Roesky, PW in [Goswami, Bhupendra; Feuerstein, Thomas J.; Yadav, Ravi; Koeppe, Ralf; Roesky, Peter W.] Karlsruhe Inst Technol KIT, Inst Inorgan Chem, Engesserstr 15, D-76131 Karlsruhe, Germany; [Lebedkin, Sergei; Kappes, Manfred M.] Karlsruhe Inst Technol KIT, Inst Nanotechnol, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany; [Kappes, Manfred M.] Karlsruhe Inst Technol KIT, Inst Phys Chem, Fritz Haber Weg 2, D-76131 Karlsruhe, Germany published Enantiopure Calcium Iminophosphonamide Complexes: Synthesis, Photoluminescence, and Catalysis in 2021.0, Cited 88.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.
The synthesis of calcium complexes ligated by three different chiral iminophosphonamide ligands, L-H (L=[Ph2P{N(R)CH(CH3)Ph}(2)]), L ‘-H (L ‘=[Ph2P{NDipp}{N(R)CH(CH3)Ph}]), (Dipp=2,6-(Pr2C6H3)-Pr-i), and L ”-H (L ”=[Ph2P{N(R)CH(CH3)naph}(2)]), (naph=naphthyl) is presented. The resulting structures [L2Ca], [L ‘ Ca-2], and [L ” Ca-2] represent the first examples of enantiopure homoleptic calcium complexes based on this type of ligands. The calcium complexes show blue-green photoluminescence (PL) in the solid state, which is especially bright at low temperatures. Whereas the emission of [L ” Ca-2] is assigned to the fluorescence of naphthyl groups, the PL of [L2Ca] and [L ‘ Ca-2] is contributed by long-lived phosphorescence and thermally activated delayed fluorescence (TADF), with a strong variation of the PL lifetimes over the temperature range of 5-295 K. Furthermore, an excellent catalytic activity was found for these complexes in hydroboration of ketones at room temperature, although no enantioselectivity was achieved.
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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem