Recently I am researching about C-H FUNCTIONALIZATION; CARBENE MIGRATORY INSERTION; ASYMMETRIC RING-EXPANSION; N-TOSYLHYDRAZONES; SUBSTITUTED PYRROLES; ORGANIC-SYNTHESIS; DIAZO-COMPOUNDS; BOND FORMATION; ARYL IODIDES; CONSTRUCTION, Saw an article supported by the Program for Changjiang Scholars and Innovative Research Team in UniversityProgram for Changjiang Scholars & Innovative Research Team in University (PCSIRT) [IRT17R94]; NSFCNational Natural Science Foundation of China (NSFC) [21662044, 81760621, 21672184, 21861042, 21602169]; Program for Innovative Research Team (in Science and Technology) in University of Yunnan Province; Training Program for Young and Middle-aged Academic and Technical Leaders in Yunnan Province [2015HB004]; Foundation of Yunling Scholar Program of Yunnan Province [YNWR-YLXZ-2014009]; Program for Excellent Young Talents, Yunnan University. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Luo, KX; Mao, S; He, K; Yu, XL; Pan, JH; Lin, J; Shao, ZH; Jin, Y. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone. Name: 1-(4-Nitrophenyl)ethanone
An efficient [4+1C](insert) approach to the coupling of enaminones with donor/acceptor or donor/donor carbenes by the AgOTf-catalyzed C-C bond carbenoid formal insertion/cyclization/[1,5]-shift cascade reaction was successfully developed, providing distinct chemo- and regioselective multisubstituted pyrroles. The plausible reaction mechanism involves two catalytic cycles: in the first one, silver ions regioselectively catalyze the C-C bond formal insertion reaction; in the second one, silver ions chemo- and regioselectively control the cyclization and [1,5]-shift reactions. This method not only provides convenience and applies atom economy in the synthesis of multisubstituted pyrroles but also presents an entry point for further pyrrole diversification via facile modification of resulting 4H-pyrrole products, as displayed by a short formal synthesis of the natural product lamellarin L.
Welcome to talk about 100-19-6, If you have any questions, you can contact Luo, KX; Mao, S; He, K; Yu, XL; Pan, JH; Lin, J; Shao, ZH; Jin, Y or send Email.. Name: 1-(4-Nitrophenyl)ethanone
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem