Safety of 1-(4-Nitrophenyl)ethanone. Recently I am researching about ASYMMETRIC TRANSFER HYDROGENATION; DIALKYL PHOSPHINE OXIDES; CYCLOHEXENE OXIDE; BORANE REDUCTION; CO2; COPOLYMERIZATION; DERIVATIVES; ALCOHOLS; ACID; CARBODIIMIDES, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21572151]; Natural Science Foundation of the Jiangsu Higher Education Institutions of ChinaNational Natural Science Foundation of China (NSFC) [19KJA320007]; project of scientific and technologic infrastructure of Suzhou [SZS201708]; PAPD. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Sun, YL; Lu, CR; Zhao, B; Xue, MQ. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone
Four chiral dinuclear rare-earth metal complexes [REL1](2) (RE = Y(1), Eu(2), Nd(3), La (4)) stabilized by Trost proligand H3L1 (H3L1 = ( S,S) -2, 6-b is [2- (hydroxydiph enylmethyl)pyrrolidin-1-ylmethyl]-4-methyl-phenol) were first prepared, and all were characterized by X-ray diffraction. Complex 4 was employed as the catalyst for enantioselective hydroboration reaction of substituted ketones, and the corresponding secondary alcohols with excellent yields and high ee values were obtained using reductant HBpin. The same result was also achieved using the combination of lanthanium amides La[N(SiMe3)(2)](3) with Trost proligand H3L1 in a 1:1 molar ratio. The experimental findings and DFT calculation revealed the possible mechanism of the enantioselective hydroboration reaction and defined the origin of the enantioselectivity in the current system.
Safety of 1-(4-Nitrophenyl)ethanone. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Sun, YL; Lu, CR; Zhao, B; Xue, MQ or concate me.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem