Recently I am researching about ASYMMETRIC TRANSFER HYDROGENATION; TRANSITION-METAL-COMPLEXES; MAGNETIC-PROPERTIES; AMINOPHOSPHONATES; DERIVATIVES; SPECTROSCOPY; CYTOTOXICITY; RHENIUM; DIPHOSPHINE; 2-PROPANOL, Saw an article supported by the University of Carthage; Tunisian Ministry of Higher Education and Scientific Research. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Hkiri, S; Gourlaouen, C; Touil, S; Samarat, A; Semeril, D. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone. Computed Properties of C8H7NO3
Three alpha-aminophosphonates, namely diethyl[(5-phenyl-1,3,4-oxadiazol-2-ylamino)(4-trifluoromethylphenyl) methyl]phosphonate (3a), diethyl[(5-phenyl-1,3,4-oxadiazol-2-ylamino)(2-methoxyphenyl)methyl]phosphonate (3b) and diethyl[(5-phenyl-1,3,4-oxadiazol-2-ylamino)(4-nitrophenyl)methyl]phosphonate (3c), were synthetized via the Pudovik-type reaction between diethyl phosphite and imines, obtained from 5-phenyl-1,2,4-oxadiazol-2-amine and aromatic aldehydes, under microwave irradiation. Compounds 3a-c underwent complexation with a ruthenium(ii) precursor, selectively at the more basic nitrogen atom of the oxadiazole ring, leading to the corresponding ruthenium complexes 4a-c of the formula [RuCl2(L)(p-cymene)] (L = alpha-aminophosphonates 3a-c). Complexes 4a-c proved to be efficient catalysts for the transfer hydrogenation of ketones to alcohols. All new compounds were fully characterised by elemental analysis, infrared, mass and NMR spectroscopy. An X-ray structure of the alpha-aminophosphonate 3b was obtained and revealed the presence, in the solid state, of an infinite chain of 3b units supramolecularly interlinked. Two X-ray diffraction studies carried out on ruthenium complexes confirm the specific coordination of the electron-enricher nitrogen atom of the oxadiazole ring.
Welcome to talk about 100-19-6, If you have any questions, you can contact Hkiri, S; Gourlaouen, C; Touil, S; Samarat, A; Semeril, D or send Email.. Computed Properties of C8H7NO3
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem