Lin, SCA; Liu, YH; Peng, SM; Liu, ST in [Lin, Shih-Chieh Aaron; Liu, Yi-Hung; Peng, Shie-Ming; Liu, Shiuh-Tzung] Natl Taiwan Univ, Dept Chem, Taipei, Taiwan published Diruthenium complex catalyzed reduction of nitroarenes-investigation of reaction pathway in 2019.0, Cited 23.0. Application In Synthesis of 1-(4-Nitrophenyl)ethanone. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.
A diruthenium complex, [(L)Ru-2(eta(6)-C6H6)(2)Cl-2](PF6)(2) (1) (L = 5-phenyl-2,8-di-2-pyridinylanthyridine), was prepared and characterized. This diruthenium complex 1 was found to be an efficient catalyst for the reduction of aromatic nitro compounds leading to the corresponding aniline derivatives with the use of hydrazine as the reducing agent at 80 degrees C in an ethanol solution. Catalytic activity of 1 towards various possible intermediates leading to anilines was investigated to understand the reaction pathway. These studies indicate that this reduction proceeds via a direct route as evidenced by hydroxylamines being observed as the major intermediate followed by the appearance of aniline under the catalytic conditions. Thus, the reaction pathway of this catalytic system is discussed.
Application In Synthesis of 1-(4-Nitrophenyl)ethanone. Welcome to talk about 100-19-6, If you have any questions, you can contact Lin, SCA; Liu, YH; Peng, SM; Liu, ST or send Email.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem