Category: 100-19-6

Authors Hafliger, J; Livingstone, K; Daniliuc, CG; Gilmour, R in ROYAL SOC CHEMISTRY published article about in [Haefliger, Joel; Livingstone, Keith; Daniliuc, Constantin G.; Gilmour, Ryan] Westfalische Wilhelms Univ Munster, Organ Chem Inst, D-48149 Munster, Germany in 2021.0, Cited 17.0. Product Details of 100-19-6. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

Simple alpha-(bromomethyl)styrenes can be processed to a variety of 1,1-difluorinated electrophilic building blocks via I(I)/I(III) catalysis. This inexpensive main group catalysis strategy employs p-TolI as an effective organocatalyst when combined with Selectfluor (R) and simple amine center dot HF complexes. Modulating Bronsted acidity enables simultaneous geminal and vicinal difluorination to occur, thereby providing a platform to generate multiply fluorinated scaffolds for further downstream derivatization. The method facilitates access to a tetrafluorinated API candidate for the treatment of amyotrophic lateral sclerosis. Preliminary validation of an enantioselective process is disclosed to access alpha-phenyl-beta-difluoro-gamma-bromo/chloro esters.

Product Details of 100-19-6. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Hafliger, J; Livingstone, K; Daniliuc, CG; Gilmour, R or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Heshmat, M in [Heshmat, Mojgan] Univ Amsterdam, Vant Hoff Inst Mol Sci, Sci Pk 904, NL-1098 XH Amsterdam, Netherlands; [Heshmat, Mojgan] Rhein Westfal TH Aachen, CAT Catalyt Ctr, ITMC, Worringerweg 2, D-52074 Aachen, Germany published Lewis Acidity of Carbon in Activated Carbonyl Group vs. B(C6F5)(3) for Metal-Free Catalysis of Hydrogenation of Carbonyl Compounds in 2021.0, Cited 60.0. SDS of cas: 100-19-6. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

In this work, using DFT calculations, we investigated Lewis acidities of carbon (in activated carbonyl group) in comparison to the B(C6F5)(3) in combination with dioxane as the Lewis base (LB) for metal-free catalysis of heterolytic H-2 splitting and hydrogenation of carbonyl compounds. We found that in case of carbon as the Lewis acid (LA) the reaction is controlled by frontier molecular orbital interactions between the H-2 and LA-LB fragments at shorter distances. The steric effects can be reduced by electrophilic substitutions on the carbonyl carbon. Synergic combination between stronger orbital interactions and reduced steric effects can lower the barrier of the H-2 splitting below 10 kcal/mol. With the B(C6F5)(3), the H-2 splitting is controlled by electrostatic interactions, which cause to form an early transition state. An advantage of employing Lewis acidity of the activated carbonyl carbon for hydrogenation is that the hydride-type attack and hydrogenation of the C=O bond occur in a single step throughout H-2 splitting. Hence, stronger Lewis acidity of the C(C=O) reinforces hydrogenation without prohibition of the hydride delivery.

SDS of cas: 100-19-6. Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

I found the field of Biochemistry & Molecular Biology; Pharmacology & Pharmacy very interesting. Saw the article Quinolone-isoniazid hybrids: synthesis and preliminary in vitro cytotoxicity and anti-tuberculosis evaluation published in 2019.0. Product Details of 100-19-6, Reprint Addresses Khanye, SD (corresponding author), Rhodes Univ, Dept Chem, Fac Sci, ZA-6140 Grahamstown, South Africa.; Khanye, SD (corresponding author), Rhodes Univ, Ctr Chem & Biomed Res, ZA-6140 Grahamstown, South Africa.; Khanye, SD (corresponding author), Rhodes Univ, Fac Pharm, ZA-6140 Grahamstown, South Africa.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone

Herein, we propose novel quinolones incorporating an INH moiety as potential drug templates against TB. The quinolone-based compounds bearing an INH moiety attached via a hydrazide-hydrazone bond were synthesised and evaluated against Mycobacterium tuberculosis H37Rv (MTB). The compounds were also evaluated for cytotoxicity against HeLa cell lines. These compounds showed significant activity (MIC90) against MTB in the range of 0.2-8 mu M without any cytotoxic effects. Compounds 10 (MIC90; 0.9 mu M), 11 (MIC90; 0.2 mu M), 12 (MIC90; 0.8 mu M) and compound 15 (MIC90; 0.8 mu M), the most active compounds in this series, demonstrate activities on par with INH and superior to those reported for the fluoroquinolones. The SAR analysis suggests that the nature of substituents at positions -1 and -3 of the quinolone nucleus influences anti-MTB activity. Aqueous solubility evaluation and in vitro metabolic stability of compound 12 highlights favourable drug-like properties for this compound class.

Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.. Product Details of 100-19-6

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Authors Yakantham, T; Sreenivasulu, R; Alluraiah, G; Tej, MB; Raju, RR in MAIK NAUKA/INTERPERIODICA/SPRINGER published article about INHIBITORY-ACTIVITY; CALCIUM INFLUX; SAR in [Yakantham, T.; Ramesh Raju, R.] Acharya Nagarjuna Univ, Dept Chem, Nagarjuna Nagar 522510, Andhra Pradesh, India; [Sreenivasulu, R.] Jawaharlal Nehru Technol Univ, Univ Coll Engn Autonomous, Dept Chem, Kakinada 533003, Andhra Pradesh, India; [Alluraiah, G.] SV Arts & Sci Coll, Dept Chem, Giddalur 523357, Andhra Pradesh, India; [Tej, M. B.] Sri Ramachandra Inst Higher Educ & Res, Dept Pharm, Chennai 600116, Tamil Nadu, India in 2019.0, Cited 12.0. Recommanded Product: 100-19-6. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

A series of novel 1,2,3-triazole linked thiazole-1,2-isoxazole derivatives has been designed, synthesized and characterized by H-1 and C-13 NMR, and mass spectral analysis. The compounds have been tested for their anticancer activity towards MCF-7 (breast cancer), A549 (lung cancer), Colo-205 (colon cancer), and A2780 (ovarian cancer) by using the MTT method using etoposide as the reference. Most of the tested compounds demonstrate good to moderate activity against all cell lines. The compounds 14b, 14e, 14g, and 14h are characterized by inhibitory activity stronger than that of etoposide.

Welcome to talk about 100-19-6, If you have any questions, you can contact Yakantham, T; Sreenivasulu, R; Alluraiah, G; Tej, MB; Raju, RR or send Email.. Recommanded Product: 100-19-6

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

HPLC of Formula: C8H7NO3. Shao, JL; Liu, MM; Wang, ZZ; Li, KJ; Bao, B; Zhao, SL; Zhou, SH in [Liu, Miaomiao; Zhao, Shuangliang] East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China; East China Univ Sci & Technol, Sch Chem Engn, Shanghai 200237, Peoples R China published Controllable Synthesis of Surface Pt-Rich Bimetallic AuPt Nanocatalysts for Selective Hydrogenation Reactions in 2019.0, Cited 49.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

Bimetallic nanocatalysts, with efficient and controllable catalytic performance, have a promising application in chemical production. In this study, surface Pt-rich bimetallic AuPt nanoparticles with different Pt/Au ratios were prepared and tested in selective hydrogenation reactions of substituted nitroaromatics. Au nanoparticles were first prepared with n-butyllithium as a rapid reducer, which were further used as seeds in the slow growth process of Pt atoms. Because of the employed sequential reduction method and the following atom diffusion, surface Pt-rich bimetallic AuPt nanoparticles were obtained. Compared with the uniform AuPt alloy nanocatalysts synthesized by the co-reduction method with n-butyllithium as the reducer and monometallic Pt nanocatalysts, the obtained surface Pt-rich AuPt bimetallic nanocatalysts presented an enhanced catalytic selectivity or activity. The performance enhancement is assigned to the optimized Au/Pt interaction in the surface Pt-rich bimetallic nanostructures. This work demonstrates that the optimization of the stoichiometry and construction of bimetallic materials is a feasible method to synthesize controllable and efficient nanocatalysts.

Welcome to talk about 100-19-6, If you have any questions, you can contact Shao, JL; Liu, MM; Wang, ZZ; Li, KJ; Bao, B; Zhao, SL; Zhou, SH or send Email.. HPLC of Formula: C8H7NO3

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Prabhu, SR; Parol, V; Upadhyaya, V; Jayarama, A; Maidur, SR; Patil, PS in [Prabhu, Shobha R.] NMAM Inst Technol, Dept Phys, Karkala 574110, Karnataka, India; [Parol, Vinay; Upadhyaya, V.] Manipal Acad Higher Educ, Manipal Inst Technol, Dept Phys, Manipal 576104, India; [Jayarama, A.] Alvas Inst Engn & Technol, Dept Phys, Moodbidri 574225, India; [Jayarama, A.] Alvas Coll, Dept PG Phys, Moodbidri 574227, India; [Maidur, Shivaraj R.; Patil, Parutagouda Shankaragouda] KLE Inst Technol, Dept Engn Phys, Hubballi 580027, Karnataka, India published Novel nitro based chalcone derivative single crystals: characterization on structural, linear optical, thermal, and third-order nonlinear optical properties in 2020.0, Cited 56.0. SDS of cas: 100-19-6. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

Crystals of (2E)-1-(4-nitrophenyl)-3-(2,3,4-trimethoxyphenyl)prop-2-en-1-one (NPTMP) are grown by slow solvent evaporation technique. The compound purity and presence of functional group elements in the material were identified from the spectroscopic techniques (FT-IR and ?H-NMR). The single-phase formation in the bulk powder crystalline sample has been confirmed from powder XRD analysis. The intermolecular interaction and structure-related parameters were obtained and analyzed by utilizing single-crystal XRD data. Using single-crystal XRD data (CIF file), display of the intermolecular interactions and contribution of H center dot center dot center dot H and H center dot center dot center dot O/O center dot center dot center dot H interaction have been obtained. The molecule is mapped over dnorm, de, di, curvedness, shape index, and electrostatic potential by generating the Hirshfeld’s surface of NPTMP molecule. The linear optical absorbance and optical bandgap of the material have been confirmed by UV-VIS-NIR spectroscopic technique. The thermal stability of the crystal NPTMP is obtained from TGA/DTA/DSC techniques. The surface morphology of the crystal is collected from scanning electron microscopy (SEM) and the electronic contribution of hyperpolarizability parameters is obtained from MOPAC 2016 software. The third-order nonlinear optical properties were studied by the Z-scan technique using CW DPSS laser operating at 532 nm wavelength. The molecule exhibits a comparatively moderate optical limiting response due to reverse saturable absorption (RSA).

SDS of cas: 100-19-6. Welcome to talk about 100-19-6, If you have any questions, you can contact Prabhu, SR; Parol, V; Upadhyaya, V; Jayarama, A; Maidur, SR; Patil, PS or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Palladium nanoparticles supported on nitrogen doped porous carbon material derived from cyclodextrin, glucose and melamine based polymer: promising catalysts for hydrogenation reactions WOS:000552035500003 published article about NITROBENZENE HYDROGENATION; PD NANOPARTICLES; GRAPHENE OXIDE; NANOSHEETS; ELECTROCATALYSTS; GENERATION; STABILITY; CHEMISTRY; NANOTUBE; NETWORK in [Sadjadi, Samahe] Iran Polymer & Petrochem Inst, Fac Petrochem, Gas Convers Dept, POB 14975-112, Tehran, Iran; [Leger, Bastien; Monflier, Eric] Univ Lille, Univ Artois, Cent Lille, CNRS,ENSCL,UMR 8181,UCCS, F-62300 Lens, France; [Malmir, Masoumeh; Heravi, Majid M.] Alzahra Univ, Sch Sci, Dept Chem, POB 1993891176, Tehran, Iran in 2020.0, Cited 42.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Computed Properties of C8H7NO3

Melamine based polymer (MT) was prepared and then reacted with a mixture of glucose (Glu) and beta-cyclodextrin (CD) under hydrothermal conditions to afford, MT/Glu-CD. Then, the adsorption of Pd salt was realized on MT/Glu-CD. The resulting compound was subsequently carbonized to furnish Pd/MT/C that exhibited high catalytic activity for the hydrogenation of nitroarenes in aqueous media. To elucidate the roles of CD, Glu, the molar ratio of Glu:CD and the carbonization in the catalytic activity, several control catalysts have been prepared and their performances for a model hydrogenation reaction were compared with that of Pd/MT/C. The results confirmed the importance of the carbonization as well as the presence of CD for achieving high catalytic activity. Moreover, it was found that the molar ratio of Glu:CD could affect the catalytic activity of the final catalyst and the optimum molar ratio of Glu:CD was 30:70. The recycling test as well as measurement of Pd leaching demonstrated high recyclability and low Pd leaching of Pd/MT/C.

About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Sadjadi, S; Malmir, M; Leger, B; Monflier, E; Heravi, MM or concate me.. Computed Properties of C8H7NO3

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Category: benzodioxans. Authors Rahman, T; Borah, G; Gogoi, PK in INDIAN ACAD SCIENCES published article about in [Rahman, Taskia; Borah, Geetika; Gogoi, Pradip K.] Dibrugarh Univ, Dept Chem, Dibrugarh, Assam, India in 2021.0, Cited 50.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

The iron oxide was successfully supported on activated clay/carbon through an experimentally viable protocol for both hydrations of nitrile to amide and reduction of nitro compounds to amines. The as-prepared catalyst has been extensively characterised by XPS, SEM-EDX, TEM, TGA, BET surface area measurements and powdered X-ray diffraction (PXRD). A wide variety of substrates could be converted to the desired products with good to excellent yields by using water as a green solvent for both the reactions. The catalyst was recyclable and reusable up to six consecutive cycles without compromising its catalytic proficiency.

Category: benzodioxans. Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Arene-Ruthenium(II) Complexes Containing 11H-Indeno[1,2-b]quinoxalin-11-one Derivatives and Tryptanthrin-6-oxime: Synthesis, Characterization, Cytotoxicity, and Catalytic Transfer Hydrogenation of Aryl Ketones WOS:000537145000060 published article about ARENE-RUTHENIUM COMPLEXES; MOLECULAR-ORBITAL METHODS; HIGHLY-ACTIVE CATALYSTS; RUTHENIUM(II)-ARENE COMPLEXES; ANTITUMOR-ACTIVITY; BIOLOGICAL EVALUATION; DENSITY FUNCTIONALS; HUMAN OVARIAN; BASIS-SETS; IN-VITRO in [Benassi, Enrico] Shihezi Univ, Dept Chem, Shihezi 832000, Xinjiang, Peoples R China; [Sukhikh, Taisiya S.; Gushchin, Artem L.; Potapov, Andrei S.] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia; [Sukhikh, Taisiya S.; Gushchin, Artem L.; Potapov, Andrei S.] Novosibirsk State Univ, Dept Nat Sci, Novosibirsk 630090, Russia; [Matveevskaya, Vladislava V.; Pavlov, Dmitry, I] Natl Res Tomsk Polytech Univ, Kizhner Res Ctr, Tomsk 634050, Russia; [Ivanov, Alexander Yu] St Petersburg State Univ, Ctr Magnet Resonance, Peterhof 198504, Russia; [Tennikova, Tatiana B.; Sharoyko, Vladimir V.; Baykov, Sergey, V] St Petersburg State Univ, Inst Chem, Peterhof 198504, Russia in 2020.0, Cited 86.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Quality Control of 1-(4-Nitrophenyl)ethanone

A series of novel mono- and binuclear arene-ruthenium(H) complexes [(p-cym)Ru(L)Cl] containing 11H-indeno [1,2-b]quinoxalin-11-one derivatives or tryptanthrin-6-oxime were synthesized and characterized by X-ray crystallography, IR, NMR spectroscopy, cyclic voltammetry, and elemental analysis. Theoretical calculations invoking singlet state geometry optimiza-tion, solvation effects, and noncovalent interactions were done using density functional theory (DFT). DFT calculations were also applied to evaluate the electronic properties, and time-dependent DFT was applied to clarify experimental UV-vis results. Cytotoxicity for cancerous and noncancerous human cell lines was evaluated with cell viability MTT assay. Complexes demonstrated a moderate cytotoxic effect toward cancerous human cell line PANC-1. The catalytic activity of the complexes was evaluated in transfer hydrogenation of aryl ketones. All complexes exhibited good catalytic activity and functional group tolerance.

Welcome to talk about 100-19-6, If you have any questions, you can contact Matveevskaya, VV; Pavlov, DI; Sukhikh, TS; Gushchin, AL; Ivanov, AY; Tennikova, TB; Sharoyko, VV; Baykov, SV; Benassi, E; Potapov, AS or send Email.. Quality Control of 1-(4-Nitrophenyl)ethanone

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

COA of Formula: C8H7NO3. Authors Li, MJ; Zheng, ZB; Zhang, ZG; Li, NW; Liu, SW; Chi, ZG; Xu, JR; Zhang, Y in MDPI published article about in [Li, Maijun; Zheng, Zhibo; Liu, Siwei; Chi, Zhenguo; Xu, Jiarui; Zhang, Yi] Sun Yat Sen Univ, Guangdong Engn Technol Res Ctr High Performance O, State Key Lab Optoelect Mat & Technol, PCFM Lab,GD HPPC Lab,Sch Chem, Guangzhou 510275, Peoples R China; [Zhang, Zhiguang; Li, Nanwen] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China in 2021.0, Cited 64.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

To improve the interfacial compatibility of mixed matrix membranes (MMMs) for gas separation, microporous polyimide particle (AP) was designed, synthesized, and introduced into intrinsic microporous polyimide matrix (6FDA-Durene) to form all polyimide MMMs. The AP fillers showed the feature of thermal stability, similar density with polyimide matrix, high porosity, high fractional free volume, large microporous dimension, and interpenetrating network architecture. As expected, the excellent interfacial compatibility between 6FDA-Durene and AP without obvious agglomeration even at a high AP loading of 10 wt.% was observed. As a result, the CO2 permeability coefficient of MMM with AP loading as low as 5 wt.% reaches up to 1291.13 Barrer, which is 2.58 times that of the pristine 6FDA-Durene membrane without the significant sacrificing of ideal selectivity of CO2/CH4. The improvement of permeability properties is much better than that of the previously reported MMMs, where high filler content is required to achieve a high permeability increase but usually leads to significant agglomeration or phase separation of fillers. It is believed that the excellent interfacial compatibility between the PI fillers and the PI matrix induce the effective utilization of porosity and free volume of AP fillers during gas transport. Thus, a higher diffusion coefficient of MMMs has been observed than that of the pristine PI membrane. Furthermore, the rigid polyimide fillers also result in the excellent anti-plasticization ability for CO2. The MMMs with a 10 wt.% AP loading shows a CO2 plasticization pressure of 300 psi.

COA of Formula: C8H7NO3. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Li, MJ; Zheng, ZB; Zhang, ZG; Li, NW; Liu, SW; Chi, ZG; Xu, JR; Zhang, Y or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem