Category: 100-19-6

An article N,S-Codoped Carbon Shells Embedded with Ultrafine Co NPs for Reductive Amination with Formic Acid WOS:000467351200092 published article about COVALENT ORGANIC FRAMEWORK; N-DOPED CARBON; OXYGEN REDUCTION; TRANSFER HYDROGENATION; NITRO-COMPOUNDS; COBALT NANOPARTICLES; GRAPHENE; METAL; CATALYST; ELECTROCATALYSTS in [Guo, Haotian; Wang, Bowei; Qiu, Pengzhi; Gao, Ruixiao; Sun, Mingming; Chen, Ligong] Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300350, Peoples R China; [Wang, Bowei; Chen, Ligong] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China; [Wang, Bowei; Chen, Ligong] Tianjin Engn Res Ctr Funct Fine Chem, Tianjin, Peoples R China; [Guo, Haotian] Emory Univ, Dept Chem, 1515 Pierce Dr, Atlanta, GA 30322 USA in 2019.0, Cited 67.0. Formula: C8H7NO3. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

Herein, N,S-codoped carbon materials embedded with ultrafine and well-distributed Co nanoparticles (1.14 wt % Co) were prepared through pyrolysis of the hybrids of SNW-1 and Co(Ac)(2) coated with glucose. It was observed by TEM and XRD that Co nanoparticles (NPs) were entrapped in doped carbon shells uniformly. The glucose coating presented a significant impact on the size distribution of Co NPs and doped modes of heteroatoms, especially the S species. The catalyst displayed outstanding activity for catalytic transfer hydrogenation (CTH) with formic acid under the base-free system. Encouragingly, diverse secondary amines were produced in excellent yields through the domino reaction of hydrogenation and reductive amination. Remarkably, the catalyst with ultrafine Co NPs showed good durability under harsh reaction conditions and displayed no significant loss in both activity and selectivity in 5 runs. This was attributed to the protection of constructed N,S dual-doped carbon shells. Hence, we offer an alternative strategy for the construction of dual-doped carbon materials trapped with ultrafine transition metal, which can be further applied in various catalytic processes.

Formula: C8H7NO3. Welcome to talk about 100-19-6, If you have any questions, you can contact Guo, HT; Wang, BW; Qiu, PZ; Gao, RX; Sun, MM; Chen, LG or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Authors Biswal, P; Samser, S; Nayak, P; Chandrasekhar, V; Venkatasubbaiah, K in AMER CHEMICAL SOC published article about ONE-POT SYNTHESIS; CONJUGATE ADDITION; ALPHA-METHYLATION; KETONES; ALCOHOLS; AMINES; SESQUITERPENOIDS; ALKYLATION; REACTIVITY; EFFICIENT in [Biswal, Priyabrata; Samser, Shaikh; Nayak, Prakash; Venkatasubbaiah, Krishnan] Natl Inst Sci Educ & Res NISER, Sch Chem Sci, Bhubaneswar 752050, Odisha, India; [Chandrasekhar, Vadapalli] Tata Inst Fundamental Res Hyderabad, Hyderabad 500046, Telangana, India; [Chandrasekhar, Vadapalli] Indian Inst Technol Kanpur, Dept Chem, Kanpur 208016, Uttar Pradesh, India in 2021.0, Cited 67.0. Quality Control of 1-(4-Nitrophenyl)ethanone. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

A novel cobalt(II)porphyrin-mediated acceptorless dehydrogenation of methanol is reported for the first time. This methodology has been applied for the coupling of a variety of ketones with methanol to produce 1,5-diketones along with H-2 and H2O as the environment friendly byproducts. This paradigm was also demonstrated for a one-pot synthesis of substituted pyridines using a sequential addition protocol where the 1,5-diketones were generated in situ. From many experiments including those involving deuterium labeling, it is proposed that protonated cobalt(II)-porphyrin methoxide complex acts as an intermediate to generate formaldehyde along with a metal hydride.

Quality Control of 1-(4-Nitrophenyl)ethanone. Welcome to talk about 100-19-6, If you have any questions, you can contact Biswal, P; Samser, S; Nayak, P; Chandrasekhar, V; Venkatasubbaiah, K or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

I found the field of Pharmacology & Pharmacy; Chemistry very interesting. Saw the article Novel thiazole-pyrazolone hybrids as potent ACE inhibitors and their cardioprotective effect on isoproterenol-induced myocardial infarction published in 2020.0. Category: benzodioxans, Reprint Addresses Su, GY (corresponding author), Shandong Univ, Jinan Cent Hosp, Cheeloo Coll Med, Dept Cardiol, Jinan 250013, Shandong, Peoples R China.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone

A facile synthesis of a group of novel thiazole-pyrazolone hybrids and their investigation for angiotensin-converting enzyme (ACE) inhibition are reported in this study. These compounds were synthesized using a well-known approach, based on the condensation of ethyl acetoacetate with thiazolylhydrazines, and characterized by various spectroscopic and analytical techniques. The entire set of compounds displayed a moderate-to-excellent inhibitory activity against ACE. In particular, compound4iwas found to be the most potent ACE inhibitor and was further studied for cardioprotective effects against isoproterenol (ISO)-induced myocardial infarction (MI) in rats. Compound4iimproved the cardiac function and prevented cardiac injury induced by ISO in Sprague Dawley rats. The levels of oxidative stress and proinflammatory cytokines were also restored to near normal by4ias compared with the ISO group. In the Western blot analysis, compound4iprevented mitochondrial apoptosis after MI by downregulating the expression of cleaved caspase-3 and Bax, with the upregulation of Bcl-2, as compared with the ISO group.

Category: benzodioxans. Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

SDS of cas: 100-19-6. Recently I am researching about C-H-FUNCTIONALIZATION; DEHYDROGENATIVE COUPLING APPROACH; METAL-FREE; OLEFIN SYNTHESIS; BOND ACTIVATION; METHYL KETONES; OXIDATIVE AMINATION; MICHAEL ADDITION; IODINE; AMINES, Saw an article supported by the Science and Engineering Research Board (SERB), India [SB/FT/CS-073/2014]; MHRD, Govt of India under the TEQIP-III Project. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Rastogi, GK; Deka, B; Deb, ML; Baruah, PK. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone

We have developed an efficient metal-free route for the synthesis of 1,4-enedione derivatives under microwave irradiation by reacting easily available arylmethylketones with DMSO or diphenyl sulfoxide in the presence of TBAI and persulfate. The reaction is very clean and completes within very short time. All the reagents and catalysts are cheap and environmentally benign. In addition, the E-isomer of the products can easily be transformed into the Z-isomer by using eosin Y photocatalyst under the irradiation of white CFL.

About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Rastogi, GK; Deka, B; Deb, ML; Baruah, PK or concate me.. SDS of cas: 100-19-6

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

SDS of cas: 100-19-6. In 2019.0 J ORGANOMET CHEM published article about BASE COMPLEXES APPLICATION; ONE-POT SYNTHESIS; CRYSTAL X-RAY; ARYL HALIDES; BOND FORMATION; RECYCLABLE CATALYST; REUSABLE CATALYST; 3+2 CYCLOADDITION; COUPLING REACTION; COPPER-COMPLEXES in [Layek, Samaresh; Agrahari, Bhumika; Pathak, Devendra D.] Indian Inst Technol ISM, Dept Appl Chem, Dhanbad 826004, Bihar, India; [Dey, Shuvankar] Gujarat Univ, Sch Sci, Dept Chem, Ahmadabad 380009, Gujarat, India; [Ganguly, Rakesh] Nanyang Technol Univ, Div Chem & Biol Chem, Singapore 639798, Singapore in 2019.0, Cited 103.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

Benzoylhydrazine based Schiff base-ligated two new copper(II) complexes, [Cu(L-1)(2)] (1) and [Cu(L-2)(2)] (2) were synthesized by the reaction of Cu(CH3COO)(2)center dot H2O with respective Schiff base ligand 1-[(4-nitrophenyl) ethylidene] benzohydrazide (HL1) or 1-[(4-methoxyphenyl)ethylidene]benzohydrazide (HL2). Both complexes were isolated as greenish solid and fully characterized by elemental analysis, FT-IR, EPR, thermo-gravimetric (TG) analysis and Cyclic Voltammetry. The molecular structures of both complexes have also been determined by single crystal X-ray crystallography, which confirmed the co-ordination of Schiff base ligands through N, O donor atoms and distorted square planar geometry around the Cu(II) ion. Both complexes were found to be good homogeneous catalysts for the synthesis of a wide range of substituted thioethers and 5-substituted 1H-tetrazoles in 92% and 93% yield, respectively, at a low catalyst loading (0.5 mol%). The bond angles and distances, as discerned from the DFT calculations, commusurated with the experimental findings. The energy difference between the HOMO and the LUMO, calculated from DFT studies, was found to be 5.645 eV and 6.459 eV for complex 1 and complex 2, respectively. These results are in harmony with the observed higher catalytic activity of complex 1. (c) 2019 Elsevier B.V. All rights reserved.

SDS of cas: 100-19-6. Welcome to talk about 100-19-6, If you have any questions, you can contact Layek, S; Agrahari, B; Dey, S; Ganguly, R; Pathak, DD or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

In 2019.0 BIOORG CHEM published article about ALZHEIMERS-DISEASE; DONEPEZIL; TACRINE; HYBRIDS; DESIGN; E2020 in [Kuzu, Burak; Tan, Meltem; Menges, Nurettin] Van Yuzuncu Yil Univ, Pharmaceut Chem Sect, TR-65080 Van, Turkey; [Kuzu, Burak; Tan, Meltem; Menges, Nurettin] YYU TEKNOKENT, SAFF Chem Reagent R&D Lab, TR-65080 Van, Turkey; [Taslimi, Parham; Gulcin, Ilhami] Ataturk Univ, Dept Chem, TR-25240 Erzurum, Turkey; [Taspinar, Mehmet] Van Yuzuncu Yil Univ, Dept Med Biol, TR-65080 Van, Turkey in 2019.0, Cited 32.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Quality Control of 1-(4-Nitrophenyl)ethanone

Mono- or di-substituted imidazole derivatives were synthesized using a one-pot, two-step strategy. All imidazole derivatives were tested for AChE and BChE inhibition and showed nanomolar activity similar to that of the test compound donepezil and higher than that of tacrine. Structure activity relationship studies, docking studies to on X-ray crystal structure of AChE with PDB code 1B41, and adsorption, distribution, metabolism, and excretion (ADME) predictions were performed. The synthesized core skeleton was bound to important regions of the active site of AChE such as the peripheral anionic site (PAS), oxyanion hole (OH), and anionic subsite (AS). Selectivity of the reported test compounds was calculated and enzyme kinetic studies revealed that they behave as competitive inhibitors, while two of the test compounds showed noncompetitive inhibitory behavior. ADME predictions revealed that the synthesized molecules might pass through the blood brain barrier and intestinal epithelial barrier and circulate freely in the blood stream without binding to human serum albumin. While the toxicity of one compound on the WS1 (skin fibroblast) cell line was 1790 mu M, its toxicity on the SH-SY5Y (neuroblastoma) cell line was 950 mu M.

Quality Control of 1-(4-Nitrophenyl)ethanone. Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

SDS of cas: 100-19-6. Authors Song, T; Zhou, X; Wang, XX; Xiao, JL; Yang, Y in ROYAL SOC CHEMISTRY published article about in [Song, Tao; Zhou, Xin; Wang, Xiaoxue; Yang, Yong] Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, 189 Songling Rd, Qingdao 266101, Peoples R China; [Xiao, Jianliang] Univ Liverpool, Dept Chem, Crown St, Liverpool L69 7ZD, Merseyside, England; [Song, Tao; Zhou, Xin; Wang, Xiaoxue; Yang, Yong] Shandong Energy Inst, Qingdao 266101, Peoples R China in 2021.0, Cited 66.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

A new methodology for the synthesis of alpha-diketones was reported via a one-pot cascade process from aldehydes and ketones catalyzed by a bifunctional iron nanocomposite using H2O2 as a green oxidant in water. The one-pot strategy showed excellent catalytic stability, comprehensive suitability of substrates and important practical utility for directly synthesizing biologically active and medicinally valuable N-heterocycles via an intermittent process.

Welcome to talk about 100-19-6, If you have any questions, you can contact Song, T; Zhou, X; Wang, XX; Xiao, JL; Yang, Y or send Email.. SDS of cas: 100-19-6

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Category: benzodioxans. In 2020.0 ORG LETT published article about GOLD NANOPARTICLES; PHOTOCATALYTIC HYDROGENATION; COPPER; PHOTOCHEMISTRY; NITROAROMATICS; EFFICIENT; NITROSOBENZENE; DEHALOGENATION; PHOTOREDUCTION; NITROBENZENE in [Kallitsakis, Michael G.; Ioannou, Dimitris I.; Lykakis, Ioannis N.] Aristotle Univ Thessaloniki, Dept Chem, Thessaloniki 54124, Greece; [Terzidis, Michael A.] Int Hellen Univ, Dept Nutr Sci & Dietet, Thessaloniki 57400, Greece; [Kostakis, George E.] Univ Sussex, Sch Life Sci, Dept Chem, Brighton BN1 9QJ, E Sussex, England in 2020.0, Cited 63.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

We report the selective photoinduced reduction of nitroarenes to N-arylhydroxylamines. The present methodology facilitates this transformation in the absence of catalyst or additives and uses only light and methylhydrazine. This noncatalytic photoinduced transformation proceeds with a broad scope, excellent functional-group tolerance, and high yields. The potential of this protocol reflects on the selective and straightforward conversion of two general antibiotics, azomycin and chloramphenicol, to the bioactive hydroxylamine species.

Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.. Category: benzodioxans

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Metal-Free Synthesis and Photophysical Properties of 1,2,4-Triarylpyrroles WOS:000606840200009 published article about AGGREGATION-INDUCED EMISSION; PYRROLE-DERIVED ALKALOIDS; INDUCED ENHANCED-EMISSION; SUBSTITUTED PYRROLES; REAL-TIME; CONSTRUCTION; QUINOLINE; COMPOUND; AMINE in [Chang, Dan; Chen, Jinjin; Huang, Huawen; Deng, Guo-Jun] Xiangtan Univ, Coll Chem, Key Lab Green Organ Synth & Applicat Hunan Prov, Minist Educ,Key Lab Environm Friendly Chem & Appl, Xiangtan 411105, Peoples R China; [Liu, Yong; Qin, Anjun; Deng, Guo-Jun] South China Univ Technol, Guangdong Prov Key Lab Luminescence Mol Aggregate, Guangzhou 510640, Peoples R China in 2021, Cited 79. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Recommanded Product: 100-19-6

A three-component reaction has been developed for the construction of multiaryl-substituted pyrrole derivatives from arylketones, amines, and nitrovinylarenes under metal- free conditions. Hence, homologous 1,2,4-triaryl-substituted pyrrole products were obtained in good to high yields. Furthermore, 2,3,5-triaryl-substituted pyrroles were selectively formed in the absence of nitrovinylarenes. The photophysical properties of some pyrrole products have been investigated to show good aggregation-induced emission (AIE) activity.

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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Muthukrishnan, I; Karuppasamy, M; Vachan, BS; Rajput, D; Subbiah, N; Maheswari, CU; Sridharan, V in [Muthukrishnan, Isravel; Karuppasamy, Muthu; Vachan, B. S.; Maheswari, C. Uma; Sridharan, Vellaisamy] SASTRA Deemed Univ, Sch Chem & Biotechnol, Dept Chem, Thanjavur 613401, Tamil Nadu, India; [Rajput, Diksha; Sridharan, Vellaisamy] Cent Univ Jammu, Dept Chem & Chem Sci, Jammu 181143, Jammu & Kashmir, India; [Subbiah, Nagarajan] Natl Inst Technol, Dept Chem, Warangal 506004, Telangana, India published Chemodivergent synthesis of functionalized methanodibenzo[b,f][1,5]diazocin-13-ylmethanones and tetrahydroquinolinesviasolvent-dependent AB(2)and A(2)B(2)multicomponent annulation reactions in 2020.0, Cited 66.0. Product Details of 100-19-6. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

A solvent-dependent chemodivergent approach was established for the synthesis of 6,12-methanodibenzo[b,f][1,5]diazocin-13-ylmethanones and 2,3,4-trisubstituted 1,2,3,4-tetrahydroquinolines involving two distinct multicomponent processes under basic conditions. The AB(2)three-component and A(2)B(2)four-component reactions between 2-aminoarylaldehydes and aryl methyl ketones under basic conditions afforded 6,12-methanodibenzo[b,f][1,5]diazocin-13-ylmethanones (up to 95% yield) and trisubstituted tetrahydroquinolines (up to 84% yield), respectively, based on the nature of the solvent employed. The skeletal diversity and complexity were attained in these high atom- and step-economical processes by creating four new bonds in a single synthetic operation from readily available simple starting materials.

Product Details of 100-19-6. Welcome to talk about 100-19-6, If you have any questions, you can contact Muthukrishnan, I; Karuppasamy, M; Vachan, BS; Rajput, D; Subbiah, N; Maheswari, CU; Sridharan, V or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem