Category: 100-19-6

Application In Synthesis of 1-(4-Nitrophenyl)ethanone. In 2019 J CATAL published article about COPPER(II)-CATALYZED AEROBIC OXIDATION; ORGANIC-SOLVENT-FREE; ROOM-TEMPERATURE; DIOXOMOLYBDENUM(VI) COMPLEXES; OXOPEROXO MOLYBDENUM(VI); SULFOXIDATION REACTIONS; SELECTIVE OXIDATION; SECONDARY ALCOHOLS; HYDROGEN-PEROXIDE; MOLECULAR-OXYGEN in [Thiruvengetam, Prabaharan; Chakravarthy, Rajan Deepan; Chand, Dillip Kumar] Indian Inst Technol Madras, Dept Chem, Chennai 600036, Tamil Nadu, India in 2019, Cited 81. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

A surfactant based oxodiperoxo molybdenum complex, which could activate molecular oxygen, has been employed as a catalyst for controlled oxidation of benzylic alcohols to corresponding carbonyls. The oxidation reactions were carried out under aqueous environment, however, in the absence of any extraneous base or co-catalyst. Sensitive/oxidizable functional groups like cyano, sulfide, hydroxyl, aryl-hydroxyl, alkene (internal/terminal), alkyne (internal/terminal), and acetal were tolerated during the transformations. Such selectivity is attributed to the mild nature of the catalyst. The methodology could also be scaled-up for multi-gram synthesis and the protocol is likely to find practical use since it requires an inexpensive recyclable-catalyst and easily available oxidant (under green conditions). A plausible mechanism is proposed with the help of preliminary computational study. (C) 2019 Elsevier Inc. All rights reserved.

Welcome to talk about 100-19-6, If you have any questions, you can contact Thiruvengetam, P; Chakravarthy, RD; Chand, DK or send Email.. Application In Synthesis of 1-(4-Nitrophenyl)ethanone

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Synthesis of bis(indolyl)methanes under dry grinding conditions, promoted by a Lewis acid-surfactant-SiO2-combined nanocatalyst WOS:000474622600003 published article about ORGANIC-SYNTHESIS; HIGHLY EFFICIENT; ACID; CATALYST; WATER; DERIVATIVES; COCATALYST; COMPOSITE; CHEMISTRY in [Wu, Zhiqiang; Wang, Gang; Yuan, Shuo; Wu, Dan; Liu, Wanyi; Ma, Baojun; Bi, Shuxian; Zhan, Haijuan; Chen, Xiaoyan] Ningxia Univ, Coll Chem & Chem Engn, Natl Demonstrat Ctr Expt Chem Educ, State Key Lab High Efficiency Utilizat Coal & Gre, Yinchuan 750021, Peoples R China in 2019.0, Cited 40.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Formula: C8H7NO3

An in situ developed Lewis acid-surfactant-SiO2-combined (LASSC) nanocatalyst was used, for the first time, as a green and effective promoting medium for the electrophilic activation of aldehydes under solvent-free and dry grinding conditions. The advantages of using the LASSC nanocatalyst include avoiding the generation of wastewater containing sodium dodecyl sulfate and the use of toxic reagents, excellent reusability of the catalyst, and obtaining a high yield of bis(indolyl)methanes.

Formula: C8H7NO3. Welcome to talk about 100-19-6, If you have any questions, you can contact Wu, ZQ; Wang, G; Yuan, S; Wu, D; Liu, WY; Ma, BJ; Bi, SX; Zhan, HJ; Chen, XY or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Recommanded Product: 1-(4-Nitrophenyl)ethanone. Recently I am researching about ARENE-RUTHENIUM COMPLEXES; MOLECULAR-ORBITAL METHODS; HIGHLY-ACTIVE CATALYSTS; RUTHENIUM(II)-ARENE COMPLEXES; ANTITUMOR-ACTIVITY; BIOLOGICAL EVALUATION; DENSITY FUNCTIONALS; HUMAN OVARIAN; BASIS-SETS; IN-VITRO, Saw an article supported by the RFBRRussian Foundation for Basic Research (RFBR) [18-33-00676]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Matveevskaya, VV; Pavlov, DI; Sukhikh, TS; Gushchin, AL; Ivanov, AY; Tennikova, TB; Sharoyko, VV; Baykov, SV; Benassi, E; Potapov, AS. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone

A series of novel mono- and binuclear arene-ruthenium(H) complexes [(p-cym)Ru(L)Cl] containing 11H-indeno [1,2-b]quinoxalin-11-one derivatives or tryptanthrin-6-oxime were synthesized and characterized by X-ray crystallography, IR, NMR spectroscopy, cyclic voltammetry, and elemental analysis. Theoretical calculations invoking singlet state geometry optimiza-tion, solvation effects, and noncovalent interactions were done using density functional theory (DFT). DFT calculations were also applied to evaluate the electronic properties, and time-dependent DFT was applied to clarify experimental UV-vis results. Cytotoxicity for cancerous and noncancerous human cell lines was evaluated with cell viability MTT assay. Complexes demonstrated a moderate cytotoxic effect toward cancerous human cell line PANC-1. The catalytic activity of the complexes was evaluated in transfer hydrogenation of aryl ketones. All complexes exhibited good catalytic activity and functional group tolerance.

Welcome to talk about 100-19-6, If you have any questions, you can contact Matveevskaya, VV; Pavlov, DI; Sukhikh, TS; Gushchin, AL; Ivanov, AY; Tennikova, TB; Sharoyko, VV; Baykov, SV; Benassi, E; Potapov, AS or send Email.. Recommanded Product: 1-(4-Nitrophenyl)ethanone

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Iridium Complex-Catalyzed Transfer Hydrogenation of N-Heteroarenes and Tentative Asymmetric Synthesis WOS:000643537100043 published article about FORMIC-ACID; IRON CATALYST; QUINOLINES; HETEROCYCLES; DEHYDROGENATION; REDUCTION; MECHANISM; OXAMNIQUINE; CHEMISTRY; ALDEHYDES in [Ouyang, Lu; Xia, Yanping; Liao, Jianhua; Miao, Rui; Yang, Xiao; Luo, Renshi] Gannan Med Univ, Sch Pharm, Ganzhou 341000, Jiangxi, Peoples R China in 2021.0, Cited 86.0. Category: benzodioxans. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

An iridium-catalyzed transfer hydrogenation of N-heteroarenes to access a series of substituted 1,2,3,4-tetrahydroquinoline derivatives in excellent yields is disclosed. This transformation is distinguished with water-soluble and air-stable iridium complexes as the catalyst, formic acid as the hydrogen source, mild reaction conditions, and broad functional group compatibility. Most importantly, a tentative chiral N,N-chelated Cp*Ir(III) complex-catalyzed enantioselective transfer hydrogenation is also presented, affording chiral products in excellent yields and good enantioselectivities.

Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.. Category: benzodioxans

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

In 2019.0 ACS APPL MATER INTER published article about CORE-SHELL NANOPARTICLES; NI; REDUCTION; PD; HYDROGENATION; NITROBENZENE; NANOTUBES; NITROGEN; FABRICATION; NANOSHEETS in [Zhao, Xue; Xiang, Changjun; Zhang, Fulin; Yao, Fengze; Sheng, Ruiqing; Ding, Qiong; Zhang, Haibo; Zhou, Xiaohai] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China; [Ding, Qiong; Zhang, Haibo] Wuhan Univ, Natl Demonstrat Ctr Expt Chem, Wuhan 430072, Peoples R China; [Liu, Wenjing] Nanjing Tech Univ NanjingTech, KLOFE, Nanjing 211800, Jiangsu, Peoples R China; [Liu, Wenjing] Nanjing Tech Univ NanjingTech, IAM, Nanjing 211800, Jiangsu, Peoples R China; [Zhang, Haibo; Zhou, Xiaohai] Minist Educ, Engn Res Ctr Organosilicon Cpds & Mat, Wuhan 430072, Peoples R China in 2019.0, Cited 38.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. COA of Formula: C8H7NO3

The increasing global demands for eco-friendly and low-cost catalysts have propelled the advent of nanosized non-noble-metal catalysts to replace traditional noble metals. In this work, ultrafine NiO nanoparticles were prepared rapidly in situ by the strategy of transforming three-dimensional (3D) metal boron organic polymers (BOPs@Ni2+) to one-dimensional (1D) boron organic polymers (BOPs@Ni) nanorod arrays at room temperature. The 3D BOPs@Ni2+ can be quickly obtained by the interaction of 4,4′-bipyridine with Ni2+ and dodecaborate (B12H122-) in an aqueous solution. When Ni2+ is converted into NiO in situ, 1D BOPs@Ni nanostructure transformation from the 3D BOPs@Ni2+ framework was achieved due to the B-H center dot center dot center dot pi interaction between B12H122- and 4,4′-bipyridine. Furthermore, BOPs@Ni exhibits high catalytic activity and rapid kinetics in the conversion of 4-nitrophenol to 4-aminophenol, and the high stability of 1D nanorod arrays guarantees the catalytic activity of BOP@Ni to barely change under recycling for at least 10 times. BOPs@Ni also exhibits good catalytic performance and high selectivity characteristics in the catalytic reduction of a series of nitrobenzene derivatives. This strategy of using BOPs@Ni2+ for loading self-supporting nanometal not only exhibits a highly efficient catalytic hydrogenation of nitrobenzene and its derivative but also provides an effective technical route for designing self-supported nanometal materials.

Welcome to talk about 100-19-6, If you have any questions, you can contact Zhao, X; Xiang, CJ; Zhang, FL; Yao, FZ; Sheng, RQ; Ding, Q; Liu, WJ; Zhang, HB; Zhou, XH or send Email.. COA of Formula: C8H7NO3

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

In 2020.0 RSC ADV published article about REDOX CONDENSATION REACTION; O-HALONITROBENZENES; BENZOTHIAZOLES; BOND; INHIBITORS; THIAZOLES; ACYLATION; ACCESS in [Huynh, Tien, V; Doan, Khang, V; Luong, Ngoc T. K.; Nguyen, Duyen T. P.; Doan, Son H.; Nguyen, Tung T.; Phan, Nam T. S.] Ho Chi Minh City Univ Technol HCMUT, Fac Chem Engn, 268 Ly Thuong Kiet,Dist 10, Ho Chi Minh City, Vietnam; [Huynh, Tien, V; Doan, Khang, V; Luong, Ngoc T. K.; Nguyen, Duyen T. P.; Doan, Son H.; Nguyen, Tung T.; Phan, Nam T. S.] Vietnam Natl Univ Ho Chi Minh City, Linh Trung Ward, Ho Chi Minh City, Vietnam; [Huynh, Tien, V; Luong, Ngoc T. K.; Nguyen, Duyen T. P.] Ho Chi Minh City Univ Food Ind HUFI, Fac Chem Technol, 140 Le Trang Tan, Ho Chi Minh City, Vietnam in 2020.0, Cited 43.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Recommanded Product: 100-19-6

A new synthesis of 2-aroylbenzothiazoles via iodine-promoted domino transformations of anilines, acetophenones, and elemental sulfur was demonstrated. The highlights of this tandem synthesis are (1) easily available anilines and acetophenones as feedstock; (2) transition metal-free conditions; (3) inexpensive, nontoxic, easy handling, and abundant elemental sulfur as a building block. This synthetic strategy would complement the existing methods in the synthesis of this important heterocyclic scaffold. To our best knowledge, the formation of 2-aroylbenzothiazoles from simple anilines, acetophenones, and elemental sulfur was not previously reported in the literature.

Recommanded Product: 100-19-6. Welcome to talk about 100-19-6, If you have any questions, you can contact Huynh, TV; Doan, KV; Luong, NTK; Nguyen, DTP; Doan, SH; Nguyen, TT; Phan, NTS or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Recommanded Product: 100-19-6. Recently I am researching about ONE-POT SYNTHESIS; ACTIVE METHYLENE ISOCYANIDES; SOLID-PHASE SYNTHESIS; AEROBIC OXIDATION; QUINOXALINE DERIVATIVES; REGIOSPECIFIC SYNTHESIS; EFFICIENT PROTOCOL; TERMINAL ALKYNES; FACILE SYNTHESIS; AMIDE HYDROLASE, Saw an article supported by the University Grants Commission-Special Assistance Programme, Departmental Research Support (UGC-SAP DRS III). Published in GEORG THIEME VERLAG KG in STUTTGART ,Authors: Kiran, KR; Swaroop, TR; Sukrutha, KP; Shruthi, JB; Anil, SM; Rangappa, KS; Sadashiva, MP. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone

o-Phenylenediammines ando-aminophenols were reacted with alpha-oxodithioesters in a highly regioselective fashion to give 2-methylthio-3-aryl/heteroarylquinoxalines and 2-acylbenzoxazoles in 55-94% and 45-86%, respectively, in the presence ofp-toluene sulfonic acid catalyst. Control experiments involving reaction of aniline with a alpha-oxodithioester indicated that the thiocarbonyl group is more reactive than the carbonyl group. Based on this, probable mechanisms for the formation of quinoxalines and benzoxazoles are given. Biological targets of the quinoxalines and benzoxazoles were identified by bioinformatics. It was found that quinoxalines have good binding affinity with human dual-specificity tyrosine-phosphorylation-regulated kinase 1A and benzoxazoles with human carboxylesterase.

Recommanded Product: 100-19-6. Welcome to talk about 100-19-6, If you have any questions, you can contact Kiran, KR; Swaroop, TR; Sukrutha, KP; Shruthi, JB; Anil, SM; Rangappa, KS; Sadashiva, MP or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Recently I am researching about CROSS-COUPLING REACTIONS; CASCADE REACTION; SUBSTITUTED CARBAZOLES; ARYL HALIDES; INDOLES; SULFUR; SELENYLATION; ISOCYANIDES; ACCESS; 1-BENZOMETALLOLES, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21871226, 21572194]; Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization; China Postdoctoral Science FoundationChina Postdoctoral Science Foundation [2018M632976]; Hunan Provincial Innovative Foundation for Postgraduate [CX2018B362]. Name: 1-(4-Nitrophenyl)ethanone. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Ni, PH; Tan, J; Zhao, WQ; Huang, HW; Xiao, FH; Deng, GJ. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone

An efficient three-component benzoselenophenes formation has been developed from substituted indoles, acetophenones, and selenium powder under metalfree conditions. 2-Aryl indoles played an important role to promote benzoselenophene formation from acetophenone derivatives and selenium powder. One C-C and two C-Se bonds were selectively formed to provide 40 new benzoselenophenes in good yields.

Welcome to talk about 100-19-6, If you have any questions, you can contact Ni, PH; Tan, J; Zhao, WQ; Huang, HW; Xiao, FH; Deng, GJ or send Email.. Name: 1-(4-Nitrophenyl)ethanone

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Recommanded Product: 1-(4-Nitrophenyl)ethanone. Shtukenberg, AG; Zhu, XL; Yang, YF; Kahr, B in [Shtukenberg, Alexander G.; Zhu, Xiaolong; Yang, Yongfan; Kahr, Bart] NYU, Dept Chem, New York, NY 10003 USA; [Shtukenberg, Alexander G.; Zhu, Xiaolong; Yang, Yongfan; Kahr, Bart] NYU, Mol Design Inst, New York, NY 10003 USA published Common Occurrence of Twisted Molecular Crystal Morphologies from the Melt in 2020, Cited 49. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

Two books that describe the forms of thin films of many molecular crystals grown from the melt in polarized light, Gedrillte Kristalle (1929) by Ferdinand Bernauer and Thermomicroscopy in the Analysis of Pharmaceuticals (1971) by Maria Kuhnert-Brandstatter, are analyzed. Their descriptions, especially of curious morphologies consistent with helicoidal twisting of crystalline fibrils or narrow lamellae, are compared in the aggregate with observations from our laboratory collected during the past 10 years. According to Bernauer, 27% of molecular crystals from the melt adopt helicoidal crystal forms under some growth conditions even though helicoids are not compatible with long-range translational symmetry, a feature that is commonly thought to be an a priori condition for crystallinity. Bernauer’s figure of 27% is often met with surprise if not outright skepticism. Kuhnert-Brandstatter was aware of the tell-tale polarimetric signature of twisting (rhythmic interference colors) but observed this characteristic morphology in less than 0.5% of the crystals described. Here, the experience of the authors with 101 arbitrarily selected compounds-many of which are polymorphous-representing 155 total crystal structures, shows an even higher percentage (ca. 31%) of twisted crystals than the value reported by Bernauer. These observations, both positive (twisting) and negative (no twisting), are tabulated. It is concluded that twisting is not associated with molecular structure or crystal structure/symmetry. Rather, these nonclassical morphologies are associated with certain habits with exaggerated aspect ratios, and their appearance is strongly controlled by the growth conditions. Comments are offered in an attempt to reconcile the observations here, and those of Bernauer, the work of seekers of twisted crystals, with those of Kuhnert-Brandstatter, whose foremost consideration was the characterization of polymorphs of compounds of medicinal interest.

Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.. Recommanded Product: 1-(4-Nitrophenyl)ethanone

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

In 2021 DALTON T published article about ASYMMETRIC TRANSFER HYDROGENATION; CARBONYL-COMPOUNDS; CRYSTAL-STRUCTURES; KETONES; REDUCTION; ALCOHOLS; METAL; ACID; CONSTANTS; ALDEHYDES in [Yadav, Samanta; Vijayan, Paranthaman; Yadav, Sunil; Gupta, Rajeev] Univ Delhi, Dept Chem, Delhi 110007, India in 2021, Cited 90. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Name: 1-(4-Nitrophenyl)ethanone

This work presents three mononuclear Ru(ii) complexes of tridentate phosphine-carboxamide based ligands providing a NNP coordination environment. The octahedral Ru(ii) ion shows additional coordination with co-ligands; CO, Cl and CH3OH. All three Ru(ii) complexes were thoroughly characterized including their crystal structures. These Ru(ii) complexes were utilized as catalysts for the transfer hydrogenation of assorted carbonyl compounds, including some challenging biologically relevant substrates, using isopropanol as the hydrogen source. The binding studies illustrated the coordination of the isopropoxide ion by replacing a Ru-ligated chloride ion followed by the generation of the Ru-H intermediate that was isolated and characterized and was found to be involved in the catalysis.

Name: 1-(4-Nitrophenyl)ethanone. Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem