Category: 100-19-6

An article Lead-Halide Perovskites for Photocatalytic alpha-Alkylation of Aldehydes WOS:000456350300003 published article about PHOTOREDOX CATALYSIS; OPTICAL-PROPERTIES; TRANSITION-METAL; ANION-EXCHANGE; NANOCRYSTALS; BR; CL; CH3NH3PBBR3; LUMINESCENT; TRIHALIDE in [Zhu, Xiaolin; Lin, Yixiong; Sun, Yue; Yan, Yong] San Diego State Univ, Dept Chem & Biochem, San Diego, CA 92182 USA; [Zhu, Xiaolin; Lin, Yixiong; Sun, Yue; Yan, Yong] New Jersey Inst Technol, Dept Chem & Environm Sci, Newark, NJ 07102 USA; [Beard, Matthew C.] Natl Renewable Energy Lab, Chem & Nanosci Ctr, Golden, CO 80401 USA in 2019.0, Cited 44.0. Application In Synthesis of 1-(4-Nitrophenyl)ethanone. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

Cost-effective and efficient photocatalysis are highly desirable in chemical synthesis. Here we demonstrate that readily prepared suspensions of APbBr(3) (A = Cs or methylammonium (MA)) type perovskite colloids (ca. 2-100 nm) can selectively photocatalyze carbon-carbon bond formation reactions, i.e., alpha-alkylations. Specifically, we demonstrate alpha-alkylation of aldehydes with a turnover number (TON) of over 52,000 under visible light illumination. Hybrid organic/inorganic perovskites are revolutionizing photovoltaic research and are now impacting other research fields, but their exploration in organic synthesis is rare. Our low-cost, easy-to-process, highly efficient and bandedge-tunable perovskite photocatalyst is expected to bring new insights in chemical synthesis.

Welcome to talk about 100-19-6, If you have any questions, you can contact Zhu, XL; Lin, YX; Sun, Y; Beard, MC; Yan, Y or send Email.. Application In Synthesis of 1-(4-Nitrophenyl)ethanone

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Application In Synthesis of 1-(4-Nitrophenyl)ethanone. In 2020.0 J ORG CHEM published article about ONE-POT SYNTHESIS; TRISODIUM CITRATE DIHYDRATE; MULTICOMPONENT REACTION; PHARMACEUTICAL-INDUSTRY; GABA(A) RECEPTOR; GREEN CHEMISTRY; EASY ACCESS; DERIVATIVES; EFFICIENT; ZOLPIDEM in [Brahmachari, Goutam; Nayek, Nayana; Karmakar, Indrajit; Nurjamal, Khondekar; Bhowmick, Anindita] Visva Bharati, Dept Chem, Lab Nat Prod & Organ Synth, Santini Ketan 731235, W Bengal, India; [Chandra, Swapan K.] Visva Bharati, Dept Chem, Santini Ketan 731235, W Bengal, India in 2020.0, Cited 61.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

A water-mediated and catalyst-free practical method for the synthesis of a new series of pharmaceutically interesting functionalized 5-(2-arylimidazo[1,2-a]pyridin-3-yl)pyrimidine-2,4-(1H,3H)-diones has been accomplished based on a one-pot multicomponent reaction between arylglyoxal monohydrates, 2-aminopyridines/2-aminopyrimidine, and barbituric/N,N-dimethylbarbituric acids under reflux conditions. The salient features of this protocol are avoidance of any additive/catalyst and toxic organic solvents, use of water as reaction medium, clean reaction profiles, operational simplicity, ease of product isolation/purification without the aid of tedious column chromatography, good to excellent yields, and high atom-economy and low E-factor.

About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Brahmachari, G; Nayek, N; Karmakar, I; Nurjamal, K; Chandra, SK; Bhowmick, A or concate me.. Application In Synthesis of 1-(4-Nitrophenyl)ethanone

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

I found the field of Chemistry very interesting. Saw the article Iridium Complex-Catalyzed Transfer Hydrogenation of N-Heteroarenes and Tentative Asymmetric Synthesis published in 2021.0. SDS of cas: 100-19-6, Reprint Addresses Luo, RS (corresponding author), Gannan Med Univ, Sch Pharm, Ganzhou 341000, Jiangxi, Peoples R China.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone

An iridium-catalyzed transfer hydrogenation of N-heteroarenes to access a series of substituted 1,2,3,4-tetrahydroquinoline derivatives in excellent yields is disclosed. This transformation is distinguished with water-soluble and air-stable iridium complexes as the catalyst, formic acid as the hydrogen source, mild reaction conditions, and broad functional group compatibility. Most importantly, a tentative chiral N,N-chelated Cp*Ir(III) complex-catalyzed enantioselective transfer hydrogenation is also presented, affording chiral products in excellent yields and good enantioselectivities.

About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Ouyang, L; Xia, YP; Liao, JH; Miao, R; Yang, X; Luo, RS or concate me.. SDS of cas: 100-19-6

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Electrochemical reduction of functionalized carbonyl compounds: enhanced reactivity over tailored nanoporous gold WOS:000531408100008 published article about HYDROSILYLATION; CATALYST; HYDROGENATION; SELECTIVITY in [Xiao, Zihui; Yang, Hui; Yin, Shuai; Zhang, Jian; Yang, Zhenhua; Yuan, Kedong; Ding, Yi] Tianjin Univ Technol, Tianjin Key Lab Adv Funct Porous Mat, Inst New Energy Mat & Low Carbon Technol, Sch Mat Sci & Engn, 391 Bin Shui Xi Dao Rd, Tianjin 300384, Peoples R China in 2020.0, Cited 29.0. Computed Properties of C8H7NO3. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

The effect of the pore size of nanoporous gold on electrochemical reduction of functionalized carbonyl compounds was investigated. NPG with a pore size of similar to 30 nm significantly enhanced the reactivity with high chemo-selectivity at a low-potential. Typically, p-nitrobenzaldehyde reduction demonstrates a high turnover frequency (TOF) up to 232 000 h(-1).

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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Category: benzodioxans. Sun, LP; Wang, PP; Xu, LL; Gao, LX; Li, J; Piao, HR in [Sun, Liangpeng] Yanbian Univ, Coll Med, Yanji 133000, Peoples R China; [Wang, Peipei; Gao, Lixin; Li, Jia] Chinese Acad Sci, Natl Ctr Drug Screening, Shanghai Inst Mat Med, Shanghai Inst Biol Sci, Shanghai 201203, Peoples R China; [Xu, Lili; Piao, Huri] Yanbian Univ, Key Lab Nat Resources Changbai Mt & Funct Mol, Minist Educ, Coll Pharm, Yanji 133000, Peoples R China published Discovery of 1,3-diphenyl-1H-pyrazole derivatives containing rhodanine-3-alkanoic acid groups as potential PTP1B inhibitors in 2019.0, Cited 29.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

Two series of 1,3-diphenyl-1H-pyrazole derivatives containing rhodanine-3-alkanoic acid groups were identified as competitive protein tyrosine phosphatase 1B (PTP1B) inhibitors. Among the compounds studied, IIIv was found to have the best in vitro inhibition activity against PTP1B (IC50 = 0.67 +/- 0.09 mu M) and the best selectivity (9-fold) between PTP1B and T-cell protein tyrosine phosphatase (TCPTP). Molecular docking studies demonstrated that compounds IIIm, IIIv and IVg could occupy simultaneously at both the catalytic site and the adjacent pTyr binding site. These results provide novel lead compounds for the design of inhibitors of PTP1B as well as other PTPs.

Category: benzodioxans. Welcome to talk about 100-19-6, If you have any questions, you can contact Sun, LP; Wang, PP; Xu, LL; Gao, LX; Li, J; Piao, HR or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Gavande, NS; VanderVere-Carozza, PS; Pawelczak, KS; Vernon, TL; Jordan, MR; Turchi, JJ in [Gavande, Navnath S.; VanderVere-Carozza, Pamela S.; Vernon, Tyler L.; Jordan, Matthew R.; Turchi, John J.] Indiana Univ Sch Med, Indianapolis, IN 46202 USA; [Gavande, Navnath S.] Wayne State Univ, Coll Pharm & Hlth Sci, Detroit, MI 48202 USA; [Pawelczak, Katherine S.; Turchi, John J.] NERx Biosci, Indianapolis, IN 46202 USA published Structure-Guided Optimization of Replication Protein A (RPA)-DNA Interaction Inhibitors in 2020, Cited 32. SDS of cas: 100-19-6. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

Replication protein A (RPA) is the major human single stranded DNA (ssDNA)-binding protein, playing essential roles in DNA replication, repair, recombination, and DNA-damage response (DDR). Inhibition of RPA-DNA interactions represents a therapeutic strategy for cancer drug discovery and has great potential to provide single agent anticancer activity and to synergize with both common DNA damaging chemotherapeutics and newer targeted anticancer agents. In this letter, a new series of analogues based on our previously reported TDRL-551 (4) compound were designed to improve potency and physicochemical properties. Molecular docking studies guided molecular insights, and further SAR exploration led to the identification of a series of novel compounds with low micromolar RPA inhibitory activity, increased solubility, and excellent cellular up-take. Among a series of analogues, compounds 43, 44, 45, and 46 hold promise for further development of novel anticancer agents.

SDS of cas: 100-19-6. Welcome to talk about 100-19-6, If you have any questions, you can contact Gavande, NS; VanderVere-Carozza, PS; Pawelczak, KS; Vernon, TL; Jordan, MR; Turchi, JJ or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Copper-Catalyzed Three-Component Domino Cyclization for the Synthesis of 4-Aryl-5-(arythio)-2-(trifluoromethyl)oxazoles WOS:000494553300006 published article about C-H FUNCTIONALIZATION; OXIME ACETATES; METAL-FREE; EFFICIENT SYNTHESIS; POLYSUBSTITUTED PYRIDINES; ACCESS; DERIVATIVES; OXAZOLES; CLEAVAGE; INDOLES in [Xiao, Fuhong; Yuan, Shanshan; Huang, Huawen; Deng, Guo-Jun] Xiangtan Univ, Coll Chem, Key Lab Environm Friendly Chem & Applicat, Minist Educ,Key Lab Green Organ Synth & Applicat, Xiangtan 411105, Peoples R China; [Zhang, Feng] Hunan Agr Univ, Coll Sci, Changsha 410128, Hunan, Peoples R China in 2019.0, Cited 59.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Quality Control of 1-(4-Nitrophenyl)ethanone

A copper-catalyzed oxidative cyclization of oxime, arylthiol, and trifluoroacetic anhydride for the construction of trisubstituted oxazoles has been developed. This transformation combines N-O bond cleavage, C-H functionalization, and intramolecular annulation, providing a practical protocol for the introduction of a trifluoromethyl (-CF3) group at oxazole rings.

Quality Control of 1-(4-Nitrophenyl)ethanone. Welcome to talk about 100-19-6, If you have any questions, you can contact Xiao, FH; Yuan, SS; Huang, HW; Zhang, F; Deng, GJ or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

In 2019.0 SYNTHESIS-STUTTGART published article about ONE-POT SYNTHESIS; ACTIVE METHYLENE ISOCYANIDES; SOLID-PHASE SYNTHESIS; AEROBIC OXIDATION; QUINOXALINE DERIVATIVES; REGIOSPECIFIC SYNTHESIS; EFFICIENT PROTOCOL; TERMINAL ALKYNES; FACILE SYNTHESIS; AMIDE HYDROLASE in [Kiran, Kuppalli R.; Sukrutha, Kodipura P.; Shruthi, Jeegundipattana B.; Anil, Seegehally M.; Rangappa, Kanchugarakoppal S.; Sadashiva, Maralinganadoddi P.] Univ Mysore, Dept Studies Chem, Mysuru 570006, Karnataka, India; [Swaroop, Toreshettahally R.] Univ Mysore, Dept Studies Organ Chem, Mysuru 570006, Karnataka, India in 2019.0, Cited 96.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. SDS of cas: 100-19-6

o-Phenylenediammines ando-aminophenols were reacted with alpha-oxodithioesters in a highly regioselective fashion to give 2-methylthio-3-aryl/heteroarylquinoxalines and 2-acylbenzoxazoles in 55-94% and 45-86%, respectively, in the presence ofp-toluene sulfonic acid catalyst. Control experiments involving reaction of aniline with a alpha-oxodithioester indicated that the thiocarbonyl group is more reactive than the carbonyl group. Based on this, probable mechanisms for the formation of quinoxalines and benzoxazoles are given. Biological targets of the quinoxalines and benzoxazoles were identified by bioinformatics. It was found that quinoxalines have good binding affinity with human dual-specificity tyrosine-phosphorylation-regulated kinase 1A and benzoxazoles with human carboxylesterase.

SDS of cas: 100-19-6. Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Product Details of 100-19-6. Recently I am researching about HETEROGENEOUS CATALYST; NITROBENZENE HYDROGENATION; FUNCTIONALIZED HALLOYSITE; PLATINUM CATALYST; PD NANOPARTICLES; CLAY NANOTUBES; SUPPORTS; RAMAN; NANOCATALYSTS; PRECURSOR, Saw an article supported by the Iran Polymer and Petrochemical Institute; Alzahra University; Iran National Science Foundation (INSF)Iran National Science Foundation (INSF) [97009384]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Sadjadi, S; Akbari, M; Heravi, MM. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone

A novel nitrile-/cyano-free ionic liquid was synthesized and carbonized under two different carbonization methods in the presence of ZnCl2 as a catalyst to afford N-doped carbon materials. It was found that the carbonization condition could affect the nature and textural properties of the resulting carbon. In the following, ionic liquid-derived carbon was hybridized with naturally occurring halloysite nanotubes via two procedures, that is, hydrothermal treatment of halloysite and as-prepared carbon and carbonization of ionic liquid in the presence of halloysite. The two novel nanocomposites were then used for stabilizing Pd nanoparticles. Examining the structures and catalytic activities of the resulting catalysts for the hydrogenation of nitroarenes in aqueous media showed that the carbonization procedure and hybridization method could affect the structure and the catalytic activity of the catalysts and hydrothermal approach, in which the structure of halloysite is preserved, leading to the catalyst with superior catalytic activity.

Welcome to talk about 100-19-6, If you have any questions, you can contact Sadjadi, S; Akbari, M; Heravi, MM or send Email.. Product Details of 100-19-6

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Authors Anga, S; Acharya, J; Chandrasekhar, V in AMER CHEMICAL SOC published article about TRANSITION-METAL-COMPLEXES; N-HETEROCYCLIC CARBENES; COORDINATION CHEMISTRY; CYCLOPENTADIENYL COMPLEXES; YTTRIUM COMPLEXES; ALDEHYDES; AMIDO; ALKYL; BOND; IMIDAZOLIN-2-IMINATO in [Anga, Srinivas; Acharya, Joydev; Chandrasekhar, Vadapalli] Tata Inst Fundamental Res Hyderabad, Hyderabad 500046, India; [Acharya, Joydev; Chandrasekhar, Vadapalli] IIT Kanpur, Dept Chem, Kanpur 208016, Uttar Pradesh, India in 2021.0, Cited 101.0. Product Details of 100-19-6. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

An imino-phosphanamide ligand, [NHIiPrMe2 P(Ph)NH-2,6-(Pr2C6H3)-Pr-i] (LH), containing two different N-substituents was prepared by the direct reaction of the lithium salt of N-heterocyclic imine (NHI) with phenylchloro-2,6-diisopropylphenyl phosphanamine, PhP(CONH-2,6-Pr-i(2)-C6H3. Reaction of LH with Y(N-(SiMe3)(2))(3) afforded the heteroleptic complex, [{L}Y(N(SiMe3)(2))(2)] (1), by elimination of HN(SiMe3)(2). Compound 1 was characterized by multinuclear NMR and X-ray crystallography. In the complex, the Y(III) center was found to be tetracoordinate in a distorted tetrahedral geometry. The ligand, imino-phosphanamidinate, [L] , functions in a chelating manner, and its coordination to Y(III) results in a distorted 4-membered YPN2 ring. As a proof of principle of its activity, 1 was used as a precatalyst for the hydroboration of various aldehydes and ketones using HBpin as the hydrogen source. The hydroboration reaction was rapid and clean even with low catalyst loadings (0.01-0.1 mol %). In addition, a very good functional group tolerance was observed in these reactions.

Product Details of 100-19-6. Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem