Category: 100-19-6

Formula: C8H7NO3. Recently I am researching about GRAPHITIC CARBON NITRIDE; Z-SCHEME PHOTOCATALYST; SELECTIVE REDUCTION; NITROBENZENE; EFFICIENT; BIVO4; NANOCOMPOSITES; ANILINE; NANOPARTICLES; CO2, Saw an article supported by the National Key R&D Program of China [2017YFE0116300]; Key Research Programs of Henan Educational Committee [19A610011]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51878646]; Natural Science Foundation of Henan Province [182300410102]. Published in ELSEVIER SCI LTD in OXFORD ,Authors: Liu, N; Ouyang, DJ; Cai, YL; Li, YY. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone

Nitro-reduction of aromatic nitro compounds into anilines has vast opportunities in synthetic chemistry. The catalytic systems used earlier operated under harsh conditions, which was very expensive to achieve end products. Visible light has advantages over the catalytic system due to the easy availability, low cost, and abundance. The present methodology describes the efficient reduction of a variety of aromatic nitro compounds into the corresponding anilines using a Z-scheme Fe2O3/BiVO4 photocatalyst under visible light illuminance. The photocatalyst demonstrated excellent activity up to 99% conversion of the nitrobenzene into aniline and for a series of nitroarenes as well at room temperature and atmospheric pressure visible light irradiation. The catalytic system has the advantage due to no leaching in the recycling experiments and high stability up to six cycles. The use of low-cost transition and p-block metal enhances the applicability of the catalytic system for aromatic nitro compounds reduction into the corresponding amines.

Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.. Formula: C8H7NO3

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

In 2019.0 ACTA CRYSTALLOGR C published article about SOLVENT-FREE SYNTHESIS; ATOM-ATOM BONDS; HYDROXY PHOSPHONATES; INTERMOLECULAR INTERACTIONS; ORGANOPHOSPHORUS CHEMISTRY; ANTIOXIDANT ACTIVITY; ADDITION-REACTIONS; ACID; CONVENIENT; ESTERS in [Radai, Zita; Kiss, Nora Zsuzsa; Czugler, Matyas; Keglevich, Gyoergy] Budapest Univ Technol & Econ, Dept Organ Chem & Technol, H-1521 Budapest, Hungary; [Czugler, Matyas] Hungarian Acad Sci, Res Ctr Nat Sci, H-1525 Budapest, Hungary; [Karaghiosoff, Konstantin] Ludwig Maximilians Univ Munchen, Dept Chem & Biochem, D-81377 Munich, Germany in 2019.0, Cited 69.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. SDS of cas: 100-19-6

The crystal structures of seven alpha-aryl-alpha-hydroxyphosphonates synthesized by the Pudovik reaction of substituted benzaldehydes and dialkyl phosphites, namely dimethyl [(hydroxy)(phenyl)methyl] phosphonate, C9H13O4P, dimethyl [(3,4-dimethoxyphenyl)(hydroxy)methyl]phosphonate, C11H17O6P, dimethyl (1-hydroxy-1-phenylethyl) phosphonate, C10H15O4P, dimethyl [1-hydroxy-1-(4-nitrophenyl)ethyl]phosphonate, C10H14NO6P, dibenzyl [hydroxy(2-nitrophenyl)methyl]phosphonate, C21H20NO6P, dibenzyl [(3-chlorophenyl)(hydroxy)methyl]phosphonate, C21H20ClO4P, and dibenzyl [hydroxy(4-methylphenyl)methyl]phosphonate, C22H23O4P, were studied to gain a better understanding of the organization in this type of molecule in the solid state. The crystals obtained for this series of compounds show a balance between C-OH center dot center dot center dot O-P chain-linked packing and the dimeric types of hydrogen-bond bridges of intermolecular pairs of such functions. The description is based on primary graph-set descriptors. Using graph-set descriptors one level deeper (i.e. secondary graph sets of the C-H center dot center dot center dot O type) revealed a similarity in the graph-set descriptors, suggesting a fine interplay of substituent- and shape-dependent effects on strong-weak interactions. It seems that the formation of chains or dimers is governed not only by the presence of a tertiary C alpha atom, but also by the nature and crowding of the ortho substituents of the alpha-aryl group.

Welcome to talk about 100-19-6, If you have any questions, you can contact Radai, Z; Kiss, NZ; Czugler, M; Karaghiosoff, K; Keglevich, G or send Email.. SDS of cas: 100-19-6

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article sigma-Bond initiated generation of aryl radicals from aryl diazonium salts WOS:000519216700016 published article about ONE-ELECTRON-TRANSFER; EOSIN Y; C-C; SYNTHETIC APPLICATIONS; ARENEDIAZONIUM IONS; AROMATIC ARYLATION; HANTZSCH ESTERS; METAL-FREE; ONE-STEP; REDUCTION in [Tatunashvili, Elene; Nashar, Philippe E.; McErlean, Christopher S. P.] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia; [Chan, Bun] Nagasaki Univ, Grad Sch Engn, Bunkyo Machi 1-14, Nagasaki, Nagasaki 8528521, Japan in 2020, Cited 75. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Quality Control of 1-(4-Nitrophenyl)ethanone

sigma-Bond nucleophiles and molecular oxygen transform aryl diazonium salts into aryl radicals. Experimental and computational studies show that Hantzsch esters transfer hydride to aryl diazonium species, and that oxygen initiates radical fragmentation of the diazene intermediate to produce aryl radicals. The operational simplicity of this addition-fragmentation process for the generation of aryl radicals, by a polar-radical crossover mechanism, has been illustrated in a variety of bond-forming reactions.

Quality Control of 1-(4-Nitrophenyl)ethanone. Welcome to talk about 100-19-6, If you have any questions, you can contact Tatunashvili, E; Chan, B; Nashar, PE; McErlean, CSP or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Efficient Transfer Hydrogenation of Ketones using Methanol as Liquid Organic Hydrogen Carrier WOS:000533699900001 published article about DEHYDROGENATIVE OXIDATION; TO-HYDROCARBONS; BIPYRIDONATE LIGAND; CATALYTIC-SYSTEM; ALCOHOLS; COMPLEX; PHASE; CONVERSION; REDUCTION; BEARING in [Garg, Nidhi; Paira, Soumen; Sundararaju, Basker] Indian Inst Technol Kanpur, Dept Chem, Kanpur 208016, Uttar Pradesh, India in 2020.0, Cited 48.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. SDS of cas: 100-19-6

Herein, we demonstrate an efficient protocol for transfer hydrogenation of ketones using methanol as practical and useful liquid organic hydrogen carrier (LOHC) under Ir(III) catalysis. Various ketones, including electron-rich/electron-poor aromatic ketones, heteroaromatic and aliphatic ketones, have been efficiently reduced into their corresponding alcohols. Chemoselective reduction of ketones was established in the presence of various other reducible functional groups under mild conditions.

SDS of cas: 100-19-6. Welcome to talk about 100-19-6, If you have any questions, you can contact Garg, N; Paira, S; Sundararaju, B or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Sthalam, VK; Singh, AK; Pabbaraja, S in [Sthalam, Vinay Kumar; Singh, Ajay K.; Pabbaraja, Srihari] Indian Inst Chem Technol, CSIR, Dept Organ Synth & Proc Chem, Hyderabad 500007, Andhra Pradesh, India; [Sthalam, Vinay Kumar; Pabbaraja, Srihari] Acad Sci & Innovat Res AcSIR, CSIR HRDC Campus, Ghaziabad 201002, Uttar Pradesh, India published An Integrated Continuous Flow Micro-Total Ultrafast Process System (mu-TUFPS) for the Synthesis of Celecoxib and Other Cyclooxygenase Inhibitors in 2019.0, Cited 54.0. Computed Properties of C8H7NO3. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

Integrated continuous manufacturing has emerged as a promising device for the rapid manufacturing of active pharmaceutical ingredients (APIs). We herein report a newly designed continuous flow micro-total process system platform for the rapid manufacturing of celecoxib, a selective nonsteroidal anti-inflammatory drug. This approach has been proven generally for the synthesis of several alkyl and aryl substituted pyrazoles. In order to minimize the tedious work-up process of potential reaction intermediates/products, we have developed a continuous flow extraction and separation platform to carry out the entire reaction sequence resulting in a short residence time with good yield. The present process was further extended to gram scale synthesis of the COX-2-related API, viz. celecoxib, in the continuous flow process.

Welcome to talk about 100-19-6, If you have any questions, you can contact Sthalam, VK; Singh, AK; Pabbaraja, S or send Email.. Computed Properties of C8H7NO3

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Formula: C8H7NO3. Authors Li, W; Cui, XJ; Junge, K; Surkus, AE; Kreyenschulte, C; Bartling, S; Beller, M in AMER CHEMICAL SOC published article about in [Li, Wu; Cui, Xinjiang; Junge, Kathrin; Surkus, Annette-Enrica; Kreyenschulte, Carsten; Bartling, Stephan; Beller, Matthias] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany in 2019, Cited 40. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

Copper oxide catalysts have been prepared by pyrolysis of copper acetate on aluminum oxide. The material resulting from pyrolysis at 800 degrees C allows for catalytic hydrogenations at low temperature of a variety of unsaturated compounds such as quinolines, alkynes, ketones, imines, and polycyclic aromatic hydrocarbons as well as nitroarenes with good activity and selectivity.

Formula: C8H7NO3. Welcome to talk about 100-19-6, If you have any questions, you can contact Li, W; Cui, XJ; Junge, K; Surkus, AE; Kreyenschulte, C; Bartling, S; Beller, M or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Vodnala, N; Gujjarappa, R; Hazra, CK; Kaldhi, D; Kabi, AK; Beifuss, U; Malakar, CC in [Vodnala, Nagaraju; Gujjarappa, Raghuram; Kaldhi, Dhananjaya; Kabi, Arup. K.; Malakar, Chandi C.] Natl Inst Technol Manipur, Dept Chem, Imphal 795004, Manipur, India; [Hazra, Chinmoy K.] Korea Adv Inst Sci & Technol, Dept Chem, Daejeon 305701, South Korea; [Beifuss, Uwe] Univ Hohenheim, Inst Chem, Garbenstr 30, D-70599 Stuttgart, Germany published Copper-Catalyzed Site-Selective Oxidative C-C Bond Cleavage of Simple Ketones for the Synthesis of Anilides and Paracetamol in 2019, Cited 70. Product Details of 100-19-6. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

A copper-catalyzed approach for the N-acylation of anilines with acetone and acetophenones via C-C bond cleavage is described. Under the developed conditions both CHCl3 and CH2Cl2 were identified as potential C1-source to promote the transformation. The reaction features a site selective C-C bond cleavage to install the amide moieties with high functional-group compatibility and wide substrate scope. The developed method avoids the use of sensitive and narcotic agents. The method also represents an excellent complement to the previous protocols with lower E-factor (13.91 mg/1 mg) than current industrially used method (E-factor 17.54 mg/1 mg). The developed approach has also been extended for the effective preparation of pyridine derivatives and paracetamol in gram scale. The course of the reaction was monitored by H-1 NMR as a preliminary investigation of the reaction mechanism.

Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.. Product Details of 100-19-6

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Convenient One-Pot Synthesis of Allylsilanes from Enolizable Ketones WOS:000498684900001 published article about GRIGNARD-REAGENTS; OLEFINATION; ALDEHYDES; SALTS in [Kwan, Man Lung D.; Challen, Paul R.; Tran, Quynh D-D] John Carroll Univ, Dept Chem, 1 John Carroll Blvd, University Hts, PA 44118 USA in 2019.0, Cited 33.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Category: benzodioxans

A convenient one-pot synthesis of allylsilanes from enolizable methyl aryl ketones has been developed. The first step involves nucleophilic addition of the trimethylsilylmethyl group to ketones using the alkylation method developed by Ishihara with slight modification to generate the corresponding beta-silylalkoxides. The second step entails addition of diisobutylaluminum chloride and heating at about 130 degrees C overnight to afford allylsilanes in fair yields.

Category: benzodioxans. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Kwan, MLD; Challen, PR; Tran, QDD or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Han, AJ; Zhang, J; Sun, WM; Chen, WX; Zhang, SL; Hang, YH; Feng, QC; Zheng, LR; Gu, L; Chen, C; Peng, Q; Wang, DS; Li, YD in [Han, Aijuan] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China; [Han, Aijuan; Zhang, Jian; Chen, Wenxing; Zhang, Shaolong; Hang, Yunhu; Feng, Quanchen; Chen, Chen; Peng, Qing; Wang, Dingsheng; Li, Yadong] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China; [Sun, Wenming] China Agr Univ, Coll Sci, Beijing 100193, Peoples R China; [Chen, Wenxing] Beijing Inst Technol, Sch Mat Sci & Engn, Beijing Key Lab Construct Tailorable Adv Funct Ma, Beijing 100081, Peoples R China; [Zheng, Lirong] Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100049, Peoples R China; [Gu, Lin] Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China published Isolating contiguous Pt atoms and forming Pt-Zn intermetallic nanoparticles to regulate selectivity in 4-nitrophenylacetylene hydrogenation in 2019.0, Cited 53.0. HPLC of Formula: C8H7NO3. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

Noble metals play a momentous role in heterogeneous catalysis but still face a huge challenge in selectivity control. Herein, we report isolating contiguous Pt atoms and forming Pt-Zn intermetallic nanoparticles as an effective strategy to optimize the selectivity of Pt catalysts. Contiguous Pt atoms are isolated into single atoms and Pt-Zn intermetallic nanoparticles are formed which are supported on hollow nitrogen-doped carbon nanotubes (PtZn/HNCNT), as confirmed by aberration-corrected high-resolution transmission electron microscopy and X-ray absorption spectrometry measurements. Interestingly, this PtZn/HNCNT catalyst promotes the hydrogenation of 4-nitrophenylacetylene to 4-aminophenylacetylene with a much higher conversion (> 99%) and selectivity (99%) than the comparison samples with Pt isolated-single-atomic-sites (Pt/HNCNT) and Pt nanoparticles (Pt/CN). Further density functional theory (DFT) calculations disclose that the positive Zn atoms assist the adsorption of nitro group and Pt-Zn intermetallic nanoparticles facilitate the hydrogenation on nitro group kinetically.

HPLC of Formula: C8H7NO3. Welcome to talk about 100-19-6, If you have any questions, you can contact Han, AJ; Zhang, J; Sun, WM; Chen, WX; Zhang, SL; Hang, YH; Feng, QC; Zheng, LR; Gu, L; Chen, C; Peng, Q; Wang, DS; Li, YD or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

COA of Formula: C8H7NO3. Authors Chen, HJ; Chiu, CC; Wang, T; Lee, DS; Lu, TJ in MDPI published article about in [Chen, Hui-Ju; Chiu, Chien-Cheng; Wang, Tsui; Lee, Dong-Sheng; Lu, Ta-Jung] Natl Chung Hsing Univ, Dept Chem, Taichung 40227, Taiwan in 2021.0, Cited 74.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

The bis-NHC-Ag/Pd(OAc)(2) catalytic system (NHC = N-heterocyclic carbene), a combination of bis-NHC-Ag complex and Pd(OAc)(2), was found to be a smart catalyst in the Pd-catalyzed transfer hydrogenation of various functionalized arenes and internal/terminal alkynes. The catalytic system demonstrated high efficiency for the reduction of a wide range of various functional groups such as carbonyls, alkynes, olefins, and nitro groups in good to excellent yields and high chemoselectivity for the reduction of functional groups. In addition, the protocol was successfully exploited to stereoselectivity for the transformation of alkynes to alkenes in aqueous media under air. This methodology successfully provided an alternative useful protocol for reducing various functional groups and a simple operational protocol for transfer hydrogenation.

Welcome to talk about 100-19-6, If you have any questions, you can contact Chen, HJ; Chiu, CC; Wang, T; Lee, DS; Lu, TJ or send Email.. COA of Formula: C8H7NO3

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem