Category: 86-29-3

In 2019 ORG LETT published article about AMINO-ACIDS; REARRANGEMENT in [Jongwohan, Chanantida; Suzuki, Toshiyasu; Fujinami, Takeshi; Adachi, Kiyohiro; Momiyama, Norie] Inst Mol Sci, Okazaki, Aichi 4448787, Japan; [Jongwohan, Chanantida; Suzuki, Toshiyasu; Momiyama, Norie] SOKENDAI Grad Univ Adv Studies, Okazaki, Aichi 4448787, Japan; [Honda, Yasushi] HPC Syst Inc, West Japan Off, Shimogyo Ku, 646 Nijohanjikicho, Kyoto 6008412, Japan; [Adachi, Kiyohiro] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1118656, Japan in 2019, Cited 18. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3. COA of Formula: C14H11N

The rearrangement of ene-aldimines is a useful reaction for affording homoallylic amines. Despite their utilities in synthetic chemistry, the rearrangement for accessing homoallylic amines substituted at the 2-position remains elusive. In this study, the Bronsted acid-initiated formal [1,3]-rearrangement of ene-aldimines was developed to synthesize 2,4,4-substituted homoallylic amines that were otherwise inaccessible previously. Our study reveals an intermolecular pathway in which the rearrangement proceeds via a protonation-mediated 2-azaallenium cation.

COA of Formula: C14H11N. Welcome to talk about 86-29-3, If you have any questions, you can contact Jongwohan, C; Honda, Y; Suzuki, T; Fujinami, T; Adachi, K; Momiyama, N or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Product Details of 86-29-3. I found the field of Chemistry very interesting. Saw the article Copper-catalyzed transformation of alkyl nitriles to N-arylacetamide using diaryliodonium salts published in 2021, Reprint Addresses Gillaizeau, I (corresponding author), Univ Orleans, Inst Organ & Analyt Chem, ICOA UMR 7311 CNRS, Rue Chartres, F-45100 Orleans, France.; Grimaud, L (corresponding author), PSL Univ, Sorbonne Univ, Dept Chim,CNRS, Lab Biomol,LBM,Ecole Normale Super, F-75005 Paris, France.. The CAS is 86-29-3. Through research, I have a further understanding and discovery of 2,2-Diphenylacetonitrile.

This work reports a simple and efficient method for the copper-catalyzed redox-neutral transformation of alkyl nitriles using eco-friendly diaryliodonium salts and leading to N-arylacetamides. The method features high efficiency, broad substrate scope and good functional group tolerance.

Product Details of 86-29-3. About 2,2-Diphenylacetonitrile, If you have any questions, you can contact Sallio, R; Payard, PA; Pakulski, P; Diachenko, I; Fabre, I; Berteina-Raboin, S; Colas, C; Ciofini, I; Grimaud, L; Gillaizeau, I or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

HPLC of Formula: C14H11N. In 2019 ANGEW CHEM INT EDIT published article about INTRAMOLECULAR CARBOSULFENYLATION; ASYMMETRIC BROMOLACTONIZATION; CHLOROCYCLIZATION; CONSTRUCTION; ALKENES; DIHALOGENATION; HALOFUNCTIONALIZATION; BROMOETHERIFICATION; SULFENOAMINATION; HALOGENATION in [Cao, Qingxiang; Luo, Jie; Zhao, Xiaodan] Sun Yat Sen Univ, Sch Chem, Inst Organ Chem, Guangzhou 510275, Guangdong, Peoples R China; [Cao, Qingxiang; Luo, Jie; Zhao, Xiaodan] Sun Yat Sen Univ, Sch Chem, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China in 2019, Cited 81. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3.

An unprecendented chiral sulfide catalyzed desymmetrizing enantioselective chlorination is disclosed. Various aryl-tethered diolefins and diaryl-tethered olefins afforded teralins and tricyclic hexahydrophenalene derivatives, respectively, bearing multiple stereogenic centers in high yields with excellent enantio- and diastereoselectivities. In contrast, the tertiary amine catalyst (DHQD)(2)PHAL led to a diastereomeric product. The products could be transformed into a variety of compounds, such as spiro-N-heterocycles.

HPLC of Formula: C14H11N. Bye, fridends, I hope you can learn more about C14H11N, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Safety of 2,2-Diphenylacetonitrile. In 2020 ORGANOMETALLICS published article about ORGANOMETALLIC CHEMISTRY; COORDINATION CHEMISTRY; BOND-CLEAVAGE; NITRIC-OXIDE; LIGANDS; PNP; APPROXIMATION; HYDROBORATION; PLATINUM; IRIDIUM in [Pecak, Jan; Eder, Wolfgang; Linert, Wolfgang; Kirchner, Karl] Vienna Univ Technol, Inst Appl Synthet Chem, A-1060 Vienna, Austria; [Stoeger, Berthold] Vienna Univ Technol, Xray Ctr, A-1060 Vienna, Austria; [Realista, Sara] Univ Nova Lisboa, ITQB NOVA, Inst Tecnol Quim & Biol Antonio Xavier, P-2780157 Oeiras, Portugal; [Martinho, Paulo N.; Calhorda, Maria Jose] Univ Lisbon, Fac Ciencias, BioISI Biosyst & Integrat Sci Inst, DQB, P-1749016 Lisbon, Portugal in 2020, Cited 53. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3.

The reaction of coordinatively unsaturated Co(II) PCP pincer complexes with nitric oxide leads to the formation of new, air-stable, diamagnetic mono nitrosyl compounds. The synthesis and characterization of five- and four-coordinate Co(III) and Co(I) nitrosyl pincer complexes based on three different ligand scaffolds is described. Passing NO through a solution of [Co(PCPNMe-iPr)Cl], [Co(PCPO-iPr)Cl] or [Co(PCPCH2-iPr)Br] led to the formation of the low-spin complex [Co(PCP-iPr)(NO)-X] with a strongly bent NO ligand. Treatment of the latter species with (X = CI, Br) AgBF4 led to chloride abstraction and formation of cationic square-planar Co(I) complexes of the type [Co(PCP-iPr)(NO)](+) featuring a linear NO group. This reaction could be viewed as a formal two electron reduction of the metal center by the NO radical from Co(III) to Co(I), if NO is counted as NO+. Hence, these systems can be described as {CoNO}(8) according to the Enemark-Feltham convention. X-ray structures, spectroscopic and electrochemical data of all nitrosyl complexes are presented. Preliminary studies show that [Co(PCPNMe-iPr)(NO)](+) catalyzes efficiently the reductive hydroboration of nitriles with pinacolborane (HBpin) forming an intermediate {CoNO}(8) hydride species.

Safety of 2,2-Diphenylacetonitrile. Welcome to talk about 86-29-3, If you have any questions, you can contact Pecak, J; Eder, W; Stoger, B; Realista, S; Martinho, PN; Calhorda, MJ; Linert, W; Kirchner, K or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Recently I am researching about TRANS-HYDROBORATION; HYDRIDE; ALKENES; REDUCTION; COMPLEXES; EFFICIENT; IMINES, Saw an article supported by the . Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Sarkar, N; Bera, S; Nembenna, S. The CAS is 86-29-3. Through research, I have a further understanding and discovery of 2,2-Diphenylacetonitrile. Formula: C14H11N

The reaction of LH [L = {(ArNH)(ArN)-C=N-C=(NAr)(NHAr)}; Ar =2,6-Et-2-C6H3] with a commercially available alane amine adduct (H3Al center dot NMe2Et) in toluene resulted in the formation of a conjugated bis-guanidinate (CBG)-supported aluminum dihydride complex, i.e., LAIH(2) (1), in good yield. The new complex has been thoroughly characterized by multinuclear magnetic resonance, IR, mass, and elemental analyses, including single-crystal structural studies. Further, we have demonstrated the aluminum-catalyzed hydroboration of a variety of nitriles and alkynes. Moreover, aluminum-catalyzed hydroboration is expanded to more challenging substrates such as alkene, pyridine, imine, carbodiimide, and isocyanides. More importantly, we have shown that the aluminum dihydride catalyzed both intra- and intermolecular chemoselective hydroboration of nitriles and alkynes over other reducible functionalities for the first time.

Formula: C14H11N. Bye, fridends, I hope you can learn more about C14H11N, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Quality Control of 2,2-Diphenylacetonitrile. Kaboudin, B; Esfandiari, H; Moradi, A; Kazemi, F; Aoyama, H in [Kaboudin, Babak; Esfandiari, Hesam; Moradi, Atieh; Kazemi, Foad] IASBS, Dept Chem, Gava Zang 4513766731, Zanjan, Iran; [Aoyama, Hiroshi] Tokyo Univ Pharm & Life Sci, Sch Pharm, 1432-1 Horinouchi, Hachioji, Tokyo 1920392, Japan published ZnCl2-Mediated Double Addition of Dialkylphosphite to Nitriles for the Synthesis of 1-Aminobisphosphonates in 2019, Cited 41. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3.

In this study, the double addition of dialkylphosphite to nitriles in a ZnCl2/Et3N system is described. The reaction was conveniently and directly used for the synthesis of biologically important 1-aminobisphosphonates (ABPs) from nitriles. The one-pot synthesis of 1-aminobisphosphonates from aldehydes via the in situ generation of nitriles is also described.

Quality Control of 2,2-Diphenylacetonitrile. Welcome to talk about 86-29-3, If you have any questions, you can contact Kaboudin, B; Esfandiari, H; Moradi, A; Kazemi, F; Aoyama, H or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Authors Zhou, YL; Xu, XJ; Sun, HW; Tao, GY; Chang, XY; Xing, XY; Chen, B; Xu, C in NATURE RESEARCH published article about in [Zhou, Yali; Xu, Xingjun; Sun, Hongwei; Tao, Guanyu; Chang, Xiao-Yong; Xing, Xiangyou; Xu, Chen] Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen, Guangdong, Peoples R China; [Zhou, Yali; Xu, Xingjun; Sun, Hongwei; Tao, Guanyu; Chang, Xiao-Yong; Xing, Xiangyou; Xu, Chen] Southern Univ Sci & Technol, Dept Chem, Guangdong Prov Key Lab Catalysis, Shenzhen, Guangdong, Peoples R China; [Chen, Bo] Southern Univ Sci & Technol, Acad Adv Interdisciplinary Studies, Shenzhen, Guangdong, Peoples R China in 2021, Cited 66. Recommanded Product: 2,2-Diphenylacetonitrile. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3

Hydrofunctionalization, the direct addition of an X-H (e.g., X=O, N) bond across an alkene, is a desirable strategy to make heterocycles that are important structural components of naturally occurring molecules. Described here is the design and discovery of donor-acceptor-type platinum catalysts that are highly effective in both hydroalkoxylation and hydroamination of unactivated alkenes over a broad range of substrates under mild conditions. A number of alkene substitution patterns are accommodated, including tri-substituted, 1,1-disubstituted, (E)-disubstituted, (Z)-disubstituted and even mono-substituted double bonds. Detailed mechanistic investigations suggest a plausible pathway that includes an unexpected dissociation/re-association of the electron-deficient ligand to form an alkene-bound donor-acceptor-type intermediate. These mechanistic studies help understand the origins of the high reactivity exhibited by the catalytic system, and provide a foundation for the rational design of chiral catalysts towards asymmetric hydrofunctionalization reactions. The direct addition of an O-H (hydroalkoxylation) or an N-H (hydroamination) bond across an alkene is a useful strategy to access biologically relevant heterocycles. Here, the authors report donor-acceptor-type platinum catalysts that are effective for both hydroalkoxylation and hydroamination of unactivated alkenes, with broad substrate scope and use of mild conditions.

Recommanded Product: 2,2-Diphenylacetonitrile. Welcome to talk about 86-29-3, If you have any questions, you can contact Zhou, YL; Xu, XJ; Sun, HW; Tao, GY; Chang, XY; Xing, XY; Chen, B; Xu, C or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

COA of Formula: C14H11N. Recently I am researching about ASYMMETRIC ALPHA-ALLYLATION; ANION PHASE-TRANSFER; TSUJI-TROST REACTION; C-O BOND; TRANSITION-METAL; BRONSTED ACID; DUAL CATALYSIS; NONCOVALENT INTERACTIONS; TRANSFER HYDROGENATION; OXIDATIVE ADDITION, Saw an article supported by the National Institutes of HealthUnited States Department of Health & Human ServicesNational Institutes of Health (NIH) – USA [GM121383, R35 GM118190]; Ministry of Science and Technology, TaiwanMinistry of Science and Technology, Taiwan [106-2917-I-564-056]; EUEuropean Commission [789399]; NSFNational Science Foundation (NSF) [ACI-1548562]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Tsai, CC; Sandford, C; Wu, T; Chen, BY; Sigman, MS; Toste, FD. The CAS is 86-29-3. Through research, I have a further understanding and discovery of 2,2-Diphenylacetonitrile

The mode of asymmetric induction in an enantioselective intramolecular allylic substitution reaction catalyzed by a combination of palladium and a chiral phosphoric acid was investigated by a combined experimental and statistical modeling approach. Experiments to probe nonlinear effects, the reactivity of deuterium-labeled substrates, and control experiments revealed that nucleophilic attack to the pi-allylpalladium intermediate is the enantio-determining step, in which the chiral phosphate anion is involved in stereoinduction. Using multivariable linear regression analysis, we determined that multiple noncovalent interactions with the chiral environment of the phosphate anion are integral to enantiocontrol in the transition state. The synthetic protocol to form chiral pyrrolidines was further applied to the asymmetric construction of C-O bonds at fully substituted carbon centers in the synthesis of chiral 2,2-disubstituted benzomorpholines.

COA of Formula: C14H11N. About 2,2-Diphenylacetonitrile, If you have any questions, you can contact Tsai, CC; Sandford, C; Wu, T; Chen, BY; Sigman, MS; Toste, FD or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Name: 2,2-Diphenylacetonitrile. Recently I am researching about FREE SONOGASHIRA COUPLINGS; C-H ARYLATION; CATALYSIS; COMPLEXES, Saw an article supported by the Takeda PharmaceuticalsTakeda Pharmaceutical Company Ltd; Arno Spatola Endowment Graduate Research Fellowship. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Bihani, M; Ansari, TN; Finck, L; Bora, PP; Jasinski, JB; Pavuluri, B; Leahy, DK; Handa, S. The CAS is 86-29-3. Through research, I have a further understanding and discovery of 2,2-Diphenylacetonitrile

A scalable synthetic method is described for both the preparation of ultrasmall palladium nanoparticles and their subsequent use in catalyzing an alpha-arylation reaction of nitriles in aqueous micelles. This method involves the intermediacy of carbanions or keteniminates, which are presumably stabilized by the micellar environment rather than being quenched with water. These Pd nanoparticles are thoroughly characterized. Mechanistic studies using P-31 NMR spectroscopy revealed the binding of phosphine ligand with the Pd surface and control experiment confirmed the zero-oxidation state of palladium. The scope of the transformation is demonstrated over 35 examples, including one at 50 g scale.

Name: 2,2-Diphenylacetonitrile. Welcome to talk about 86-29-3, If you have any questions, you can contact Bihani, M; Ansari, TN; Finck, L; Bora, PP; Jasinski, JB; Pavuluri, B; Leahy, DK; Handa, S or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Chiral BrOnsted Acid Catalyzed Dynamic Kinetic Asymmetric Hydroamination of Racemic Allenes and Asymmetric Hydroamination of Dienes WOS:000476423300046 published article about ENANTIOSELECTIVE HYDROAMINATION; METAL CATALYSIS; STEREOCONVERGENT; TRANSFORMATIONS; CLASSIFICATION; ISOMERIZATION; RACEMIZATION; ACTIVATION; S(N)1 in [Lin, Jin-Shun] Tsinghua Univ, Key Lab Chem Biol, State Key Lab Chem Oncogen, Grad Sch Shenzhen, Shenzhen 518055, Peoples R China; [Lin, Jin-Shun] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China; [Lin, Jin-Shun; Li, Tao-Tao; Jiao, Guan-Yuan; Gu, Qiang-Shuai; Cheng, Jiang-Tao; Lv, Ling; Liu, Xin-Yuan] Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China; [Lin, Jin-Shun; Li, Tao-Tao; Jiao, Guan-Yuan; Cheng, Jiang-Tao; Lv, Ling; Liu, Xin-Yuan] Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China; [Gu, Qiang-Shuai] Southern Univ Sci & Technol, Acad Adv Interdisciplinary Studies, Shenzhen 518055, Peoples R China in 2019, Cited 71. HPLC of Formula: C14H11N. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3

The first highly efficient and practical chiral BrOnsted acid catalyzed dynamic kinetic asymmetric hydroamination (DyKAH) of racemic allenes and asymmetric hydroamination of unactivated dienes with both high E/Z selectivity and enantioselectivity are described herein. The transformation proceeds through a new catalytic asymmetric model involving a highly reactive pi-allylic carbocationic intermediate, generated from racemic allenes or dienes through a proton transfer mediated by an activating/directing thiourea group. This method affords expedient access to structurally diverse enantioenriched, potentially bioactive alkenyl-containing aza-heterocycles and bicyclic aza-heterocycles.

About 2,2-Diphenylacetonitrile, If you have any questions, you can contact Lin, JS; Li, TT; Jiao, GY; Gu, QS; Cheng, JT; Lv, L; Liu, XY or concate me.. HPLC of Formula: C14H11N

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem