Category: 86-29-3

Name: 2,2-Diphenylacetonitrile. Xiang, KR; Tong, P; Yan, BR; Long, LL; Zhao, CB; Zhang, Y; Li, Y in [Xiang, Kuirong; Tong, Pei; Yan, Baorun; Long, Lingling; Zhao, Chunbo; Zhang, Yuan; Li, Ying] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China published Synthesis of Benzannulated [6,6]-Spiroketals by a One-Pot Carbonylative Sonogashira Coupling/Double Annulation Reaction in 2019, Cited 86. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3.

A one-pot Pd-catalyzed carbonylative Sonogashira coupling in tandem with double annulation reaction to synthesize benzannulated [6,6]-spiroketals from o-iodophenols and terminal alkynols or alkynyl phenols was achieved. The protocol provides straightforward and facile access to benzannulated [6,6]-spiroketals in moderate to good yields and excellent diastereoselectivities under balloon pressure of CO at room temperature.

Name: 2,2-Diphenylacetonitrile. Bye, fridends, I hope you can learn more about C14H11N, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Authors Pecak, J; Eder, W; Stoger, B; Realista, S; Martinho, PN; Calhorda, MJ; Linert, W; Kirchner, K in AMER CHEMICAL SOC published article about ORGANOMETALLIC CHEMISTRY; COORDINATION CHEMISTRY; BOND-CLEAVAGE; NITRIC-OXIDE; LIGANDS; PNP; APPROXIMATION; HYDROBORATION; PLATINUM; IRIDIUM in [Pecak, Jan; Eder, Wolfgang; Linert, Wolfgang; Kirchner, Karl] Vienna Univ Technol, Inst Appl Synthet Chem, A-1060 Vienna, Austria; [Stoeger, Berthold] Vienna Univ Technol, Xray Ctr, A-1060 Vienna, Austria; [Realista, Sara] Univ Nova Lisboa, ITQB NOVA, Inst Tecnol Quim & Biol Antonio Xavier, P-2780157 Oeiras, Portugal; [Martinho, Paulo N.; Calhorda, Maria Jose] Univ Lisbon, Fac Ciencias, BioISI Biosyst & Integrat Sci Inst, DQB, P-1749016 Lisbon, Portugal in 2020, Cited 53. HPLC of Formula: C14H11N. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3

The reaction of coordinatively unsaturated Co(II) PCP pincer complexes with nitric oxide leads to the formation of new, air-stable, diamagnetic mono nitrosyl compounds. The synthesis and characterization of five- and four-coordinate Co(III) and Co(I) nitrosyl pincer complexes based on three different ligand scaffolds is described. Passing NO through a solution of [Co(PCPNMe-iPr)Cl], [Co(PCPO-iPr)Cl] or [Co(PCPCH2-iPr)Br] led to the formation of the low-spin complex [Co(PCP-iPr)(NO)-X] with a strongly bent NO ligand. Treatment of the latter species with (X = CI, Br) AgBF4 led to chloride abstraction and formation of cationic square-planar Co(I) complexes of the type [Co(PCP-iPr)(NO)](+) featuring a linear NO group. This reaction could be viewed as a formal two electron reduction of the metal center by the NO radical from Co(III) to Co(I), if NO is counted as NO+. Hence, these systems can be described as {CoNO}(8) according to the Enemark-Feltham convention. X-ray structures, spectroscopic and electrochemical data of all nitrosyl complexes are presented. Preliminary studies show that [Co(PCPNMe-iPr)(NO)](+) catalyzes efficiently the reductive hydroboration of nitriles with pinacolborane (HBpin) forming an intermediate {CoNO}(8) hydride species.

About 2,2-Diphenylacetonitrile, If you have any questions, you can contact Pecak, J; Eder, W; Stoger, B; Realista, S; Martinho, PN; Calhorda, MJ; Linert, W; Kirchner, K or concate me.. HPLC of Formula: C14H11N

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

I found the field of Chemistry very interesting. Saw the article Olefin Oxyamination with Unfunctionalized N-Alkylanilines published in 2019. Recommanded Product: 2,2-Diphenylacetonitrile, Reprint Addresses Niggeman, M (corresponding author), Rhein Westfal TH Aachen, Inst Organ Chem, Landoltweg 1, D-52074 Aachen, Germany.. The CAS is 86-29-3. Through research, I have a further understanding and discovery of 2,2-Diphenylacetonitrile

N-Alkylanilines have rarely been used in oxyamination reactions, due to the normally necessary pre-functionalization of the N-atom. Also, the formation of aminium radical cations (ARCs) of anilines bearing alkyl substituents is plagued by the ARC’s tendency to instantaneously convert to alpha-amino radicals or iminium ions. We present a readily available reagent combination that addresses both challenges, and thus allows for an oxyamination with N-alkylanilines via ARCs as the crucial reactive intermediates and excellent diastereoselectivity.

Welcome to talk about 86-29-3, If you have any questions, you can contact Gao, S; Niggeman, M or send Email.. Recommanded Product: 2,2-Diphenylacetonitrile

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

I found the field of Chemistry very interesting. Saw the article Copper-catalyzed transformation of alkyl nitriles to N-arylacetamide using diaryliodonium salts published in 2021. SDS of cas: 86-29-3, Reprint Addresses Gillaizeau, I (corresponding author), Univ Orleans, Inst Organ & Analyt Chem, ICOA UMR 7311 CNRS, Rue Chartres, F-45100 Orleans, France.; Grimaud, L (corresponding author), PSL Univ, Sorbonne Univ, Dept Chim,CNRS, Lab Biomol,LBM,Ecole Normale Super, F-75005 Paris, France.. The CAS is 86-29-3. Through research, I have a further understanding and discovery of 2,2-Diphenylacetonitrile

This work reports a simple and efficient method for the copper-catalyzed redox-neutral transformation of alkyl nitriles using eco-friendly diaryliodonium salts and leading to N-arylacetamides. The method features high efficiency, broad substrate scope and good functional group tolerance.

SDS of cas: 86-29-3. Welcome to talk about 86-29-3, If you have any questions, you can contact Sallio, R; Payard, PA; Pakulski, P; Diachenko, I; Fabre, I; Berteina-Raboin, S; Colas, C; Ciofini, I; Grimaud, L; Gillaizeau, I or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Recommanded Product: 2,2-Diphenylacetonitrile. Authors Foster, D; Gao, PC; Zhang, ZY; Sipos, G; Sobolev, AN; Nealon, G; Falivene, L; Cavallo, L; Dorta, R in ROYAL SOC CHEMISTRY published article about in [Foster, Daven; Gao, Pengchao; Sipos, Gellert; Dorta, Reto] Univ Western Australia, Sch Mol Sci, Dept Chem, M310,35 Stirling Highway, Perth, WA 6009, Australia; [Zhang, Ziyun; Falivene, Laura; Cavallo, Luigi] King Abdullah Univ Sci & Technol, Chem & Life Sci & Engn, Kaust Catalysis Ctr, Thuwal 239556900, Saudi Arabia; [Sobolev, Alexandre N.; Nealon, Gareth] Univ Western Australia, Ctr Microscopy Characterisat & Anal, 35 Stirling Highway, Perth, WA 6009, Australia; [Sipos, Gellert] ComInnex Inc, Zahony Utca 7, H-1031 Budapest, Hungary; [Falivene, Laura] Univ Salerno, Dipartimento Chim, Via Giovanni Paolo II, I-84084 Fisciano, Italy in 2021, Cited 102. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3

Chiral, cationic NHC-iridium complexes are introduced as catalysts for the intramolecular hydroamination reaction of unactivated aminoalkenes. The catalysts show high activity in the construction of a range of 5- and 6-membered N-heterocycles, which are accessed in excellent optical purity, with various functional groups being tolerated with this system. A major deactivation pathway is presented and eliminated by using alternative reaction conditions. A detailed experimental and computational study on the reaction mechanism is performed providing valuable insights into the mode of action of the catalytic system and pointing to future modifications to be made for this catalytic platform.

Recommanded Product: 2,2-Diphenylacetonitrile. Bye, fridends, I hope you can learn more about C14H11N, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

SDS of cas: 86-29-3. Authors Foster, D; Gao, PC; Zhang, ZY; Sipos, G; Sobolev, AN; Nealon, G; Falivene, L; Cavallo, L; Dorta, R in ROYAL SOC CHEMISTRY published article about in [Foster, Daven; Gao, Pengchao; Sipos, Gellert; Dorta, Reto] Univ Western Australia, Sch Mol Sci, Dept Chem, M310,35 Stirling Highway, Perth, WA 6009, Australia; [Zhang, Ziyun; Falivene, Laura; Cavallo, Luigi] King Abdullah Univ Sci & Technol, Chem & Life Sci & Engn, Kaust Catalysis Ctr, Thuwal 239556900, Saudi Arabia; [Sobolev, Alexandre N.; Nealon, Gareth] Univ Western Australia, Ctr Microscopy Characterisat & Anal, 35 Stirling Highway, Perth, WA 6009, Australia; [Sipos, Gellert] ComInnex Inc, Zahony Utca 7, H-1031 Budapest, Hungary; [Falivene, Laura] Univ Salerno, Dipartimento Chim, Via Giovanni Paolo II, I-84084 Fisciano, Italy in 2021, Cited 102. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3

Chiral, cationic NHC-iridium complexes are introduced as catalysts for the intramolecular hydroamination reaction of unactivated aminoalkenes. The catalysts show high activity in the construction of a range of 5- and 6-membered N-heterocycles, which are accessed in excellent optical purity, with various functional groups being tolerated with this system. A major deactivation pathway is presented and eliminated by using alternative reaction conditions. A detailed experimental and computational study on the reaction mechanism is performed providing valuable insights into the mode of action of the catalytic system and pointing to future modifications to be made for this catalytic platform.

About 2,2-Diphenylacetonitrile, If you have any questions, you can contact Foster, D; Gao, PC; Zhang, ZY; Sipos, G; Sobolev, AN; Nealon, G; Falivene, L; Cavallo, L; Dorta, R or concate me.. SDS of cas: 86-29-3

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Recommanded Product: 2,2-Diphenylacetonitrile. Recently I am researching about MASS-SPECTROMETRY; TRANSFORMATION PRODUCTS; RETENTION TIMES; WASTE-WATER; QUANTIFICATION; PREDICTION, Saw an article supported by the Biotechnology and Biological Sciences Research Council under the London Interdisciplinary Doctoral Training Programme (LIDO) programme [BB/M009513/1]; Agilent Technologies UK Limited as iCASE partners. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Richardson, AK; Chadha, M; Rapp-Wright, H; Mills, GA; Fones, GR; Gravell, A; Sturzenbaum, S; Cowan, DA; Neep, DJ; Barron, LP. The CAS is 86-29-3. Through research, I have a further understanding and discovery of 2,2-Diphenylacetonitrile

A novel and rapid approach to characterise the occurrence of contaminants of emerging concern (CECs) in river water is presented using multi-residue targeted analysis and machine learning-assisted in silico suspect screening of passive sampler extracts. Passive samplers (Chemcatcher (R)) configured with hydrophilic-lipophilic balanced (HLB) sorbents were deployed in the Central London region of the tidal River Thames (UK) catchment in winter and summer campaigns in 2018 and 2019. Extracts were analysed by; (a) a rapid 5.5 min direct injection targeted liquid chromatography-tandem mass spectrometry (LC-MS/MS) method for 164 CECs and (b) a full-scan LC coupled to quadrupole time of flight mass spectrometry (QTOF-MS) method using data-independent acquisition over 15 min. From targeted analysis of grab water samples, a total of 33 pharmaceuticals, illicit drugs, drug metabolites, personal care products and pesticides (including several EU Watch-List chemicals) were identified, and mean concentrations determined at 40 +/- 37 ng L-1. For targeted analysis of passive sampler extracts, 65 unique compounds were detected with differences observed between summer and winter campaigns. For suspect screening, 59 additional compounds were shortlisted based on mass spectral database matching, followed by machine learning-assisted retention time prediction. Many of these included additional pharmaceuticals and pesticides, but also new metabolites and industrial chemicals. The novelty in this approach lies in the convenience of using passive samplers together with machine learning-assisted chemical analysis methods for rapid, time-integrated catchment monitoring of CECs.

Welcome to talk about 86-29-3, If you have any questions, you can contact Richardson, AK; Chadha, M; Rapp-Wright, H; Mills, GA; Fones, GR; Gravell, A; Sturzenbaum, S; Cowan, DA; Neep, DJ; Barron, LP or send Email.. Recommanded Product: 2,2-Diphenylacetonitrile

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Recommanded Product: 2,2-Diphenylacetonitrile. Authors Foster, D; Gao, PC; Zhang, ZY; Sipos, G; Sobolev, AN; Nealon, G; Falivene, L; Cavallo, L; Dorta, R in ROYAL SOC CHEMISTRY published article about in [Foster, Daven; Gao, Pengchao; Sipos, Gellert; Dorta, Reto] Univ Western Australia, Sch Mol Sci, Dept Chem, M310,35 Stirling Highway, Perth, WA 6009, Australia; [Zhang, Ziyun; Falivene, Laura; Cavallo, Luigi] King Abdullah Univ Sci & Technol, Chem & Life Sci & Engn, Kaust Catalysis Ctr, Thuwal 239556900, Saudi Arabia; [Sobolev, Alexandre N.; Nealon, Gareth] Univ Western Australia, Ctr Microscopy Characterisat & Anal, 35 Stirling Highway, Perth, WA 6009, Australia; [Sipos, Gellert] ComInnex Inc, Zahony Utca 7, H-1031 Budapest, Hungary; [Falivene, Laura] Univ Salerno, Dipartimento Chim, Via Giovanni Paolo II, I-84084 Fisciano, Italy in 2021, Cited 102. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3

Chiral, cationic NHC-iridium complexes are introduced as catalysts for the intramolecular hydroamination reaction of unactivated aminoalkenes. The catalysts show high activity in the construction of a range of 5- and 6-membered N-heterocycles, which are accessed in excellent optical purity, with various functional groups being tolerated with this system. A major deactivation pathway is presented and eliminated by using alternative reaction conditions. A detailed experimental and computational study on the reaction mechanism is performed providing valuable insights into the mode of action of the catalytic system and pointing to future modifications to be made for this catalytic platform.

Recommanded Product: 2,2-Diphenylacetonitrile. Welcome to talk about 86-29-3, If you have any questions, you can contact Foster, D; Gao, PC; Zhang, ZY; Sipos, G; Sobolev, AN; Nealon, G; Falivene, L; Cavallo, L; Dorta, R or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Authors Zhou, YL; Xu, XJ; Sun, HW; Tao, GY; Chang, XY; Xing, XY; Chen, B; Xu, C in NATURE RESEARCH published article about in [Zhou, Yali; Xu, Xingjun; Sun, Hongwei; Tao, Guanyu; Chang, Xiao-Yong; Xing, Xiangyou; Xu, Chen] Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen, Guangdong, Peoples R China; [Zhou, Yali; Xu, Xingjun; Sun, Hongwei; Tao, Guanyu; Chang, Xiao-Yong; Xing, Xiangyou; Xu, Chen] Southern Univ Sci & Technol, Dept Chem, Guangdong Prov Key Lab Catalysis, Shenzhen, Guangdong, Peoples R China; [Chen, Bo] Southern Univ Sci & Technol, Acad Adv Interdisciplinary Studies, Shenzhen, Guangdong, Peoples R China in 2021, Cited 66. Name: 2,2-Diphenylacetonitrile. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3

Hydrofunctionalization, the direct addition of an X-H (e.g., X=O, N) bond across an alkene, is a desirable strategy to make heterocycles that are important structural components of naturally occurring molecules. Described here is the design and discovery of donor-acceptor-type platinum catalysts that are highly effective in both hydroalkoxylation and hydroamination of unactivated alkenes over a broad range of substrates under mild conditions. A number of alkene substitution patterns are accommodated, including tri-substituted, 1,1-disubstituted, (E)-disubstituted, (Z)-disubstituted and even mono-substituted double bonds. Detailed mechanistic investigations suggest a plausible pathway that includes an unexpected dissociation/re-association of the electron-deficient ligand to form an alkene-bound donor-acceptor-type intermediate. These mechanistic studies help understand the origins of the high reactivity exhibited by the catalytic system, and provide a foundation for the rational design of chiral catalysts towards asymmetric hydrofunctionalization reactions. The direct addition of an O-H (hydroalkoxylation) or an N-H (hydroamination) bond across an alkene is a useful strategy to access biologically relevant heterocycles. Here, the authors report donor-acceptor-type platinum catalysts that are effective for both hydroalkoxylation and hydroamination of unactivated alkenes, with broad substrate scope and use of mild conditions.

Name: 2,2-Diphenylacetonitrile. Bye, fridends, I hope you can learn more about C14H11N, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Authors Foster, D; Gao, PC; Zhang, ZY; Sipos, G; Sobolev, AN; Nealon, G; Falivene, L; Cavallo, L; Dorta, R in ROYAL SOC CHEMISTRY published article about in [Foster, Daven; Gao, Pengchao; Sipos, Gellert; Dorta, Reto] Univ Western Australia, Sch Mol Sci, Dept Chem, M310,35 Stirling Highway, Perth, WA 6009, Australia; [Zhang, Ziyun; Falivene, Laura; Cavallo, Luigi] King Abdullah Univ Sci & Technol, Chem & Life Sci & Engn, Kaust Catalysis Ctr, Thuwal 239556900, Saudi Arabia; [Sobolev, Alexandre N.; Nealon, Gareth] Univ Western Australia, Ctr Microscopy Characterisat & Anal, 35 Stirling Highway, Perth, WA 6009, Australia; [Sipos, Gellert] ComInnex Inc, Zahony Utca 7, H-1031 Budapest, Hungary; [Falivene, Laura] Univ Salerno, Dipartimento Chim, Via Giovanni Paolo II, I-84084 Fisciano, Italy in 2021, Cited 102. Quality Control of 2,2-Diphenylacetonitrile. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3

Chiral, cationic NHC-iridium complexes are introduced as catalysts for the intramolecular hydroamination reaction of unactivated aminoalkenes. The catalysts show high activity in the construction of a range of 5- and 6-membered N-heterocycles, which are accessed in excellent optical purity, with various functional groups being tolerated with this system. A major deactivation pathway is presented and eliminated by using alternative reaction conditions. A detailed experimental and computational study on the reaction mechanism is performed providing valuable insights into the mode of action of the catalytic system and pointing to future modifications to be made for this catalytic platform.

Quality Control of 2,2-Diphenylacetonitrile. Welcome to talk about 86-29-3, If you have any questions, you can contact Foster, D; Gao, PC; Zhang, ZY; Sipos, G; Sobolev, AN; Nealon, G; Falivene, L; Cavallo, L; Dorta, R or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem