Category: 86-29-3

Authors Ashraf, MA; Liu, ZL; Li, C; Zhang, DQ in WILEY published article about CATALYZED SYNTHESIS; 3-COMPONENT SYNTHESIS; EFFICIENT SYNTHESIS; ACID CATALYST; TETRAZOLES; NITRILES; NANOPARTICLES; 5-SUBSTITUTED-1H-TETRAZOLES; DERIVATIVES; CONVERSION in [Ashraf, Muhammad Aqeel; Li, Cheng; Zhang, Dangquan] Henan Agr Univ, Sch Forestry, Zhengzhou 450002, Peoples R China; [Ashraf, Muhammad Aqeel] China Univ Geosci, Sch Environm Studies, Wuhan 430074, Peoples R China; [Liu, Zhenling] Henan Univ Technol, Sch Management, Zhengzhou 450001, Peoples R China in 2021, Cited 46. Category: benzodioxans. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3

An efficient and sustainable synthetic protocol has been presented to synthesis and 5-substituted 1H-tetrazole privileged heterocyclic substructures. The synthetic protocol involves two-component reaction between aryl nitriles and NaN3 in water using complex of L-lysine-palladium nanoparticles (NPs) modified Fe3O4 nanoparticles as magnetically separable, recyclable, and reusable heterogeneous catalyst. Magnetically retrievable L-lysine-Pd(0) modified Fe3O4 nanoparticles were applied in [2 + 3] cycloaddition synthesis of 5-substituted 1H-tetrazoles. The advantages of this strategy include easy recovery and efficient reusability of the expensive Pd NPs, obtaining high yields of [2 + 3] cycloaddition, short reaction times, and all of the reported synthetic strategies are being performed in water as green solvent for a wide range of substrates.

Category: benzodioxans. Bye, fridends, I hope you can learn more about C14H11N, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

In 2021 RSC ADV published article about ONE-POT SYNTHESIS; ARYL HALIDES; ARYLATION; CHEMISTRY; COMPLEX; PERSPECTIVE; AMIDATION; EFFICIENT; REAGENTS; SYSTEM in [Sallio, Romain; Pakulski, Pawel; Diachenko, Iryna; Berteina-Raboin, Sabine; Colas, Cyril; Gillaizeau, Isabelle] Univ Orleans, Inst Organ & Analyt Chem, ICOA UMR 7311 CNRS, Rue Chartres, F-45100 Orleans, France; [Payard, Pierre-Adrien; Fabre, Indira; Grimaud, Laurence] PSL Univ, Sorbonne Univ, Dept Chim,CNRS, Lab Biomol,LBM,Ecole Normale Super, F-75005 Paris, France; [Ciofini, Ilaria] PSL Univ, Inst Chem Hlth & Life Sci, CNRS, Chim ParisTech,I CLeHS, F-75005 Paris, France in 2021, Cited 38. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3. Name: 2,2-Diphenylacetonitrile

This work reports a simple and efficient method for the copper-catalyzed redox-neutral transformation of alkyl nitriles using eco-friendly diaryliodonium salts and leading to N-arylacetamides. The method features high efficiency, broad substrate scope and good functional group tolerance.

About 2,2-Diphenylacetonitrile, If you have any questions, you can contact Sallio, R; Payard, PA; Pakulski, P; Diachenko, I; Fabre, I; Berteina-Raboin, S; Colas, C; Ciofini, I; Grimaud, L; Gillaizeau, I or concate me.. Name: 2,2-Diphenylacetonitrile

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article A general asymmetric copper-catalysed Sonogashira C(sp(3))-C(sp) coupling WOS:000498875700019 published article about CROSS-COUPLINGS; ALKYL BROMIDES; ACETYLENE; NICKEL; ARYL; METHODOLOGY; DERIVATIVES; ALDEHYDES; HYDROGEN; IODIDES in [Dong, Xiao-Yang; Zhang, Yu-Feng; Ma, Can-Liang; Wang, Fu-Li; Jiang, Sheng-Peng; Liu, Xin-Yuan] Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen, Guangdong, Peoples R China; [Dong, Xiao-Yang; Zhang, Yu-Feng; Ma, Can-Liang; Gu, Qiang-Shuai; Wang, Fu-Li; Li, Zhong-Liang; Jiang, Sheng-Peng; Liu, Xin-Yuan] Southern Univ Sci & Technol, Dept Chem, Shenzhen, Guangdong, Peoples R China; [Gu, Qiang-Shuai; Li, Zhong-Liang] Southern Univ Sci & Technol, Acad Adv Interdisciplinary Studies, Shenzhen, Guangdong, Peoples R China in 2019, Cited 54. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3. Formula: C14H11N

Continued development of the Sonogashira coupling has made it a well established and versatile reaction for the straightforward formation of C-C bonds, forging the carbon skeletons of broadly useful functionalized molecules. However, asymmetric Sonogashira coupling, particularly for C(sp(3))-C(sp) bond formation, has remained largely unexplored. Here we demonstrate a general stereoconvergent Sonogashira C(sp(3))-C(sp) cross-coupling of a broad range of terminal alkynes and racemic alkyl halides (>120 examples) that are enabled by copper-catalysed radical-involved alkynylation using a chiral cinchona alkaloid-based P,N-ligand. Industrially relevant acetylene and propyne are successfully incorporated, laying the foundation for scalable and economic synthetic applications. The potential utility of this method is demonstrated in the facile synthesis of stereoenriched bioactive or functional molecule derivatives, medicinal compounds and natural products that feature a range of chiral C(sp(3))-C(sp/sp(2)/sp(3)) bonds. This work emphasizes the importance of radical species for developing enantioconvergent transformations.

Formula: C14H11N. About 2,2-Diphenylacetonitrile, If you have any questions, you can contact Dong, XY; Zhang, YF; Ma, CL; Gu, QS; Wang, FL; Li, ZL; Jiang, SP; Liu, XY or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Name: 2,2-Diphenylacetonitrile. Authors Babon, JC; Esteruelas, MA; Fernandez, I; Lopez, AM; Onate, E in AMER CHEMICAL SOC published article about in [Babon, Juan C.; Esteruelas, Miguel A.; Lopez, Ana M.; Onate, Enrique] Univ Zaragoza, Ctr Innovac Quim Avanzada ORFEO CINQA, Inst Sintesis Quim & Catalisis Homogenea ISQCH, Dept Quim Inorgan,CSIC, Zaragoza 50009, Spain; [Fernandez, Israel] Univ Complutense Madrid, Ctr Innovac Quim Avanzada ORFEO CINQA, Fac Ciencias Quim, Dept Quim Organ 1, Madrid 28040, Spain in 2020, Cited 69. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3

Complex OsH6((PPr3)-Pr-i)(2) is an efficient catalyst precursor for the addition of pinacolborane and catecholborane to the C-N triple bond of alkyl nitrites. In this way, a variety of N,N-diborylamines have been isolated and fully characterized, including 13 derivatives not described so far. The range of nitrites used is wide and comprises substrates having unfunctionalized linear and branched chains, and functionalized chains with methoxide, trifluoromethyl, aryl, pyridyl, benzoyl, or cyanide groups. Kinetic studies demonstrate that the overall process consists of two consecutive irreversible reactions: the catalytic metal-promoted monohydroboration of the nitrile to afford the borylimine and the metal-free stoichiometric hydroboration of the latter to give the diborylamine. The mechanism of the hydroboration has been established by combining the kinetic analysis of the catalysis, stoichiometric reactions, and DFT calculations. The rate-determining step of the catalysis is the insertion of the C-N triple bond of the nitrite into the Os-B bond of an osmium-sigma-borane intermediate and is regiodirected by the nucleophilicity of the nitrogen atom and the electrophilicity of the carbon atom of the nitrite.

Name: 2,2-Diphenylacetonitrile. About 2,2-Diphenylacetonitrile, If you have any questions, you can contact Babon, JC; Esteruelas, MA; Fernandez, I; Lopez, AM; Onate, E or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

I found the field of Chemistry very interesting. Saw the article Old Concepts, New Application – Additive-Free Hydrogenation of Nitriles Catalyzed by an Air Stable Alkyl Mn(I) Complex published in 2019. Category: benzodioxans, Reprint Addresses Kirchner, K (corresponding author), Vienna Univ Technol, Inst Appl Synthet Chem, Getreidemarkt 9-163-AC, A-1060 Vienna, Austria.. The CAS is 86-29-3. Through research, I have a further understanding and discovery of 2,2-Diphenylacetonitrile

An efficient additive-free manganese-catalyzed hydrogenation of nitriles to primary amines with molecular hydrogen is described. The pre-catalyst, a well-defined bench-stable alkyl bisphosphine Mn(I) complex fac-[Mn(dpre)(CO)(3)(CH3)] (dpre=1,2-bis(di-n-propylphosphino)ethane), undergoes CO migratory insertion into the manganese-alkyl bond to form acyl complexes which upon hydrogenolysis yields the active coordinatively unsaturated Mn(I) hydride catalyst [Mn(dpre)(CO)(2)(H)]. A range of aromatic and aliphatic nitriles were efficiently and selectively converted into primary amines in good to excellent yields. The hydrogenation of nitriles proceeds at 100 degrees C with a catalyst loading of 2 mol % and a hydrogen pressure of 50 bar. Mechanistic insights are provided by means of DFT calculations.

Category: benzodioxans. Welcome to talk about 86-29-3, If you have any questions, you can contact Weber, S; Veiros, LF; Kirchner, K or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Authors Xiang, KR; Tong, P; Yan, BR; Long, LL; Zhao, CB; Zhang, Y; Li, Y in AMER CHEMICAL SOC published article about PALLADIUM-CATALYZED CARBONYLATION; ARYL IODIDES; EXPEDITIOUS SYNTHESIS; AROMATIC SPIROKETALS; ASYMMETRIC-SYNTHESIS; NATURAL-PRODUCTS; ALKYNYL KETONES; O-IODOPHENOLS; FORMIC-ACID; CHROMONES in [Xiang, Kuirong; Tong, Pei; Yan, Baorun; Long, Lingling; Zhao, Chunbo; Zhang, Yuan; Li, Ying] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China in 2019, Cited 86. COA of Formula: C14H11N. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3

A one-pot Pd-catalyzed carbonylative Sonogashira coupling in tandem with double annulation reaction to synthesize benzannulated [6,6]-spiroketals from o-iodophenols and terminal alkynols or alkynyl phenols was achieved. The protocol provides straightforward and facile access to benzannulated [6,6]-spiroketals in moderate to good yields and excellent diastereoselectivities under balloon pressure of CO at room temperature.

COA of Formula: C14H11N. Welcome to talk about 86-29-3, If you have any questions, you can contact Xiang, KR; Tong, P; Yan, BR; Long, LL; Zhao, CB; Zhang, Y; Li, Y or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Recommanded Product: 2,2-Diphenylacetonitrile. Babon, JC; Esteruelas, MA; Lopez, AM; Onate, E in [Babon, Juan C.; Esteruelas, Miguel A.; Lopez, Ana M.; Onate, Enrique] Univ Zaragoza CSIC, Dept Quim Inorgan, Inst Sintesis Quim & Catalisis Homogenea ISQCH, Ctr Innovac Quim Avanzada ORFEO CINQA, Zaragoza 50009, Spain published Osmium-Promoted Transformation of Alkyl Nitriles to Secondary Aliphatic Amines: Scope and Mechanism in 2020, Cited 116. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3.

The transformation of alkyl nitriles to symmetrical and asymmetrical secondary aliphatic amines promoted by the hexahydride complex OsH6 ((PPr3)-Pr-i)(2) (1) is described, and the mechanisms of the reactions involved are established. Complex 1 catalyzes the aforementioned transformations of aryl-, pyridyl-, and alkoxy-functionalized alkyl nitriles with linear or branched chains. The formation of the secondary amines involves primary imines, primary amines, and secondary imines as organic intermediates. The reactions take place under mild conditions (toluene, 100 degrees C, and 4 bar of H-2). Stoichiometric reactions of 1 with pivalonitrile and 2-methoxyacetonitrile have allowed us to isolate the trihydride azavinylidene derivatives OsH3{=N=CHR}((PPr3)-Pr-i)(2) (R = Bu-t (3), CH2OMe (4)). Their formation involves the insertion of the N-C triple bond of the substrates into an Os-H bond of the unsaturated tetrahydride OsH4 ((PPr3)-Pr-i)(2) (A), which is generated by reductive elimination of H-2 from the hexahydride precursor. The reaction of these trihydride azavinylidene species with H-2 is the key step for the reduction of the N-C triple bond of the nitriles. In the absence of H-2, the attack of A to the azavinylidene ligand produces the rupture of its C(sp(2))-C(sp(3)) bond. As a consequence of this attack and the presence of primary imines and amines in the reaction media, the binuclear complexes ((PPr3)-Pr-i)(2) H4Os(mu-CN)OsH3{kappa(1)-N-(NH= CHCH2OMe)}((PPr3)-Pr-i)(2) (5) and ((PPr3)-Pr-i)(2)H4Os(mu-CN)OsH3{kappa(1)-N-(NH2CH2CH2OMe)}((PPr3)-Pr-i)(2) (6) have been isolated and characterized by X-ray diffraction analysis, for 2-methoxyacetonitrile. DFT calculations reveal noticeable similarities between the hydrogenations of nitriles to primary imines and those of primary imines to primary amines.

Recommanded Product: 2,2-Diphenylacetonitrile. Bye, fridends, I hope you can learn more about C14H11N, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

HPLC of Formula: C14H11N. Recently I am researching about REDUCTIVE ELIMINATION; CARBON-CARBON; NITRILES; CYANOACETATE; HALIDES; LIGAND; HETEROARYL; COMPLEXES; EFFICIENT; ACETONE, Saw an article supported by the . Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Yuen, OY; Chen, XM; Wu, JY; So, CM. The CAS is 86-29-3. Through research, I have a further understanding and discovery of 2,2-Diphenylacetonitrile

The first general palladium-catalyzed alpha-arylation of arylacetonitriles with aryl and heteroaryl sulfonates are reported. Pd(OAc)(2) associated with XPhos serves as the effective catalyst to facilitate this reaction. A broad range of electron-rich, -neutral, -deficient, and sterically hindered aryl/heteroaryl tosylates and mesylates are coupled with arylacetonitriles bearing different substituents to give the corresponding products in good to excellent yields. Catalyst loading down to 0.1 mol-% Pd was achieved, and 22 unprecedented compounds were synthesized from 43 demonstrated examples using this method. Its applicability with the modification of biological phenolic compounds was successfully demonstrated. The Pd/XPhos system catalyzed the alpha-arylation and followed by alkylation in one-pot sequential conditions, resulting in the direct synthesis of compounds containing quaternary center- and deuterium-containing compounds in good to excellent yields.

Welcome to talk about 86-29-3, If you have any questions, you can contact Yuen, OY; Chen, XM; Wu, JY; So, CM or send Email.. HPLC of Formula: C14H11N

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Authors Hu, LZ; Hussain, MI; Deng, QF; Liu, Q; Feng, YY; Zhang, XH; Xiong, Y in PERGAMON-ELSEVIER SCIENCE LTD published article about IODINE-CATALYZED ALLYLATION; TERTIARY ALLYLIC ALCOHOLS; ENANTIOSELECTIVE CYANOSILYLATION; EFFICIENT CYANOSILYLATION; STEREOSELECTIVE-SYNTHESIS; OXIDATIVE REARRANGEMENT; ANTIVIRAL ACTIVITY; NITRILES; KETONES; AMINES in [Hu, Liangzhen; Hussain, Muhammad Ijaz; Deng, Qingfu; Liu, Qing; Feng, Yangyang; Zhang, Xiaohui; Xiong, Yan] Chongqing Univ, Sch Chem & Chem Engn, Chongqing 401331, Peoples R China; [Xiong, Yan] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China in 2019, Cited 59. HPLC of Formula: C14H11N. The Name is 2,2-Diphenylacetonitrile. Through research, I have a further understanding and discovery of 86-29-3

One-step base promoted strategy for cyanation of alpha,alpha-diaryl alcohols has been developed under mild and transition metal-free conditions. This method provides a straightforward and facile way towards the synthesis of beta,gamma-unsaturated nitriles and alpha-phenylnitiriles from alpha-vinyl carbinols and alpha,alpha-diaryl methanols, respectively, up to 99% yield. Moreover, various azides and ethers could also be accessed from their respective nucleophiles under standard reaction conditions. (C) 2018 Elsevier Ltd. All rights reserved.

Welcome to talk about 86-29-3, If you have any questions, you can contact Hu, LZ; Hussain, MI; Deng, QF; Liu, Q; Feng, YY; Zhang, XH; Xiong, Y or send Email.. HPLC of Formula: C14H11N

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

HPLC of Formula: C14H11N. I found the field of Chemistry very interesting. Saw the article Uranium versus Thorium: Synthesis and Reactivity of [eta(5)-1,2,4-(Me3C)(3)C5H2](2)U[eta(2)-C2Ph2] published in 2021, Reprint Addresses Zi, GF (corresponding author), Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China.; Walter, MD (corresponding author), Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, Hagenring 30, D-38106 Braunschweig, Germany.. The CAS is 86-29-3. Through research, I have a further understanding and discovery of 2,2-Diphenylacetonitrile.

The synthesis, electronic structure, and reactivity of a uranium metallacyclopropene were comprehensively studied. Addition of diphenylacetylene (PhC equivalent to CPh) to the uranium phosphinidene metallocene [eta(5)-1,2,4-(Me3C)(3)C5H2](2)U=P-2,4,6-tBu(3)C(6)H(2) (1) yields the stable uranium metallacyclopropene, [eta(5)-1,2,4-(Me3C)(3)C5H2](2)U[eta(2)-C2Ph2] (2). Based on density functional theory (DFT) results the 5f orbital contributions to the bonding within the metallacyclopropene U-(eta(2)-C=C) moiety increases significantly compared to the related Th-IV compound [eta(5)-1,2,4-(Me3C)(3)C5H2](2)Th[eta(2)-C2Ph2], which also results in more covalent bonds between the [eta(5)-1,2,4-(Me3C)(3)C5H2](2)U2+ and [eta(2)-C2Ph2](2-) fragments. Although the thorium and uranium complexes are structurally closely related, different reaction patterns are therefore observed. For example, 2 reacts as a masked synthon for the low-valent uranium(II) metallocene [eta(5)-1,2,4-(Me3C)(3)C5H2](2)U-II when reacted with Ph2E2 (E=S, Se), alkynes and a variety of hetero-unsaturated molecules such as imines, ketazine, bipy, nitriles, organic azides, and azo derivatives. In contrast, five-membered metallaheterocycles are accessible when 2 is treated with isothiocyanate, aldehydes, and ketones.

Bye, fridends, I hope you can learn more about C14H11N, If you have any questions, you can browse other blog as well. See you lster.. HPLC of Formula: C14H11N

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem