An article A Highly Practical Copper(II)/TEMPO-SO4H Catalyst System for Aerobic Oxidations of Primary Benzylic and Allylic Alcohols on Gram-Scale in Water WOS:000477382000001 published article about ACTIVATED DIMETHYL-SULFOXIDE; SELECTIVE OXIDATION; ALDEHYDES; TEMPO; GREEN; EFFICIENT; REAGENTS in [Chen, Tianyou; Wang, Zihao; Xiao, Juncong; Yi, Changfeng; Xu, Zushun] Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Minist Educ, Key Lab Green Preparat & Applicat Funct Mat,Sch M, Wuhan 430062, Hubei, Peoples R China; [Cao, Zheng] Changzhou Univ, Jiangsu Key Lab Environm Friendly Polymer Mat, Sch Mat Sci & Engn, Jiangsu Collaborat Innovat Ctr Photovolta Sci & E, Changzhou 213164, Peoples R China in 2019.0, Cited 47.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. SDS of cas: 100-19-6
We report a highly practical copper(II)/TEMPO-SO4H catalyst system for aerobic oxidations of primary benzylic and allylic alcohols. A higher activity was achieved when TEMPO-SO4H, an economically feasible 2,2,6,6-tetramethylpiperidinyl-1-oxyl (TEMPO) derivative containing a sulfonic acid group, was used to replace TEMPO. The use of such Cu-II/TEMPO-SO4H catalysts can significantly simplify the removal of catalysts and dramatically reduce the amount of organic solvents used. The aerobic oxidation of primary benzylic and allylic alcohols was conducted in water on gram scale using air as the oxidant, and in the absence of surfactant, leading to green catalysis.
SDS of cas: 100-19-6. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Chen, TY; Wang, ZH; Xiao, JC; Cao, Z; Yi, CF; Xu, ZS or concate me.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem