An article Experimental and Computational Insights into the Water-Mediated Decomposition of N-Sulfonylhydrazones: A Catalyst-Free Synthesis of gamma-Keto/Nitrile Sulfones WOS:000510016500001 published article about METAL-FREE CYCLOPROPANATION; CROSS-COUPLING REACTIONS; CONJUGATE ADDITION; CASCADE REACTIONS; MICHAEL ADDITION; DIAZO-COMPOUNDS; TOSYLHYDRAZONES; EFFICIENT; NITRILES; CARBENE in [Goyal, Shagun; Budhiraja, Meenakshi; Mandal, Debasish; Tyagi, Vikas] Thapar Inst Engn & Technol, Sch Chem & Biochem, Patiala 147004, Punjab, India in 2020.0, Cited 67.0. Safety of 1-(4-Nitrophenyl)ethanone. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6
This work is an example of water-mediated decomposition of N-sulfonylhydrazones used as sulfonyl-transferring reagents in the selective sulfa-Michael reaction in the absence of any base or catalyst. A wide range of substituted N-sulfonylhydrazones were tested as sources of sulfonyl anions with enones or acrylonitrile, which in turn provided the gamma- keto/nitrile sulfones in very good yields. Additionally, we have performed a rigorous computational mechanistic study to investigate the role of water which demonstrates the key role of water in the hydrogen abstraction from N-tosylhydrazone to initiate the reaction.
About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Goyal, S; Budhiraja, M; Mandal, D; Tyagi, V or concate me.. Safety of 1-(4-Nitrophenyl)ethanone
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem