Safety of 1-(4-Nitrophenyl)ethanone. Recently I am researching about LAYERED DOUBLE HYDROXIDE; OXIDATIVE MANNICH REACTION; MIXED-METAL OXIDES; TERTIARY-AMINES; HIGHLY EFFICIENT; H FUNCTIONALIZATION; CARBONYL-COMPOUNDS; HYDROGEN-PEROXIDE; AEROBIC OXIDATION; ACTIVE CATALYSTS, Saw an article supported by the Advanced Catalysis and Green Manufacturing Collaborative Innovation Center of Changzhou University; Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD); Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology [BM2012110]; Postgraduate Research &Practice Innovation Program of Jiangsu Province [KYCX19_1746]; Qinglan Project of Jiangsu Province; Natural Science Foundation of Jiangsu Province of ChinaNatural Science Foundation of Jiangsu Province [BK20181461]. Published in ELSEVIER in AMSTERDAM ,Authors: Zhou, WY; Lu, WMZ; Wang, H; Xia, ZZ; Zhai, SY; Zhang, Z; Ma, YJ; He, MY; Chen, Q. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone
CuMgAl layered double hydroxide compounds (CuMgAl-LDHs) have been synthesized, characterized and in-vestigated in the aerobic CDC reactions. The results indicated that NH3 center dot H2O coprecipitated CuMgAl LDH (N-CuMgAl-LDH) was able to efficiently accelerate the CDC reactions between the alpha-Csp(3)-H of N-aryltetrahy-droisoquinolines and nucleophiles. A wide scope of N-aryltetrahydroisoquinoline analogues and nucleophiles with different C-H bonds (C-sp3-H, C-sp2-H and Csp-H) could be tolerated by the N-CuMgAl-LDH system. Compared with the sample using Na2CO3 as the precipitant (C-CuMgAl-LDH), N-CuMgAl-LDH showed higher catalytic activity, which probably was due to its higher surface acidity. Dual function of redox and acidity for the N-CuMgAl-LDH catalyst has been observed in the CDC reaction. According to the obtained catalytic results, kinetic isotope effect experiment and XPS analysis, iminium ion was proposed as the key intermediate, made possible by the cycle of Cu2+ and Cu+ under the aerobic conditions.
Welcome to talk about 100-19-6, If you have any questions, you can contact Zhou, WY; Lu, WMZ; Wang, H; Xia, ZZ; Zhai, SY; Zhang, Z; Ma, YJ; He, MY; Chen, Q or send Email.. Safety of 1-(4-Nitrophenyl)ethanone
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem