Yun, RR; Ma, WJ; Wang, SN; Jia, WG; Zheng, BS in [Yun, Ruirui; Ma, Wanjiao; Jia, Weiguo] Anhui Normal Univ, Key Lab Funct Mol Solids, Minist Educ, Coll Chem & Mat Sci, Wuhu 214001, Peoples R China; [Wang, Suna] Liaocheng Univ, Shandong Prov Key Lab Chem Energy Storage & Novel, Sch Chem & Chem Engn, Liaocheng 252059, Shandong, Peoples R China; [Zheng, Baishu] Hunan Univ Sci & Technol, Key Lab Theoret Chem & Mol Simulat, Minist Educ, Sch Chem & Chem Engn, Xiangtan 411201, Peoples R China published High Selectivity of Hydrogenation Reaction over Co-0.15@C/PC Catalyst at Room Temperature in 2019.0, Cited 35.0. SDS of cas: 100-19-6. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.
In the field of catalysis, material scientists pay much attention to tuning the activity and chemoselectivity of metal nanoparticles. Herein, we design and successfully synthesize a series of Co NPs which show high performance on hydrogenation of nitroarenes with both activity and chemoselectivity. Co-0.15@C/PC preferentially activates the -C=O bond over -NO2 in water with ammonia borane (AB); however, when the hydrogen source is changes to hydrazine hydrate (HH), the results are the opposite. The Co-based catalyst exhibits exceptionally high catalytic activity (with a TOF value of 10512 h(-1), which is approximately 100 times than the akin catalysts) and chemo-selectivity for the hydrogenation of nitro compounds under mild conditions. Additionally, the catalyst can be separated easily by a magnet and shows prominent stabilit, which means that it can be reused for at least 10 cycles.
SDS of cas: 100-19-6. Welcome to talk about 100-19-6, If you have any questions, you can contact Yun, RR; Ma, WJ; Wang, SN; Jia, WG; Zheng, BS or send Email.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem