Application In Synthesis of 1-(4-Nitrophenyl)ethanone. Recently I am researching about NITRO-COMPOUNDS; SELECTIVE HYDROGENATION; REDUCTION; EFFICIENT; GOLD; DEHYDROGENATION; NANOPARTICLES; NITROBENZENE; CARBON; METAL, Saw an article supported by the National Key R&D Program of China [2016YFA0202801, 2017YFA0700101]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21872076, 21573119, 21590792, 21890383, 21866032]; Beijing Natural Science FoundationBeijing Natural Science Foundation [JQ18007]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Cheong, WC; Yang, WJ; Zhang, J; Li, Y; Zhao, D; Liu, SJ; Wu, KL; Liu, QG; Zhang, C; Wang, DS; Peng, Q; Chen, C; Li, YD. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone
Selective hydrogenation of nitroarenes to arylamines is a great challenge because of the complicated mechanism and competitive hydrogenation of reducible functional groups. Isolated single-atomic site catalysts, benefitting from their uniform and well-defined catalytic sites, are promising to achieve high activity and selectivity. Herein, we prepared an isolated iron single-atomic catalyst supported on ordered mesoporous nitrogen-doped carbon (Fe-1/N-C). The as-prepared Fe-1/N-C showed excellent activity and tolerance for functional groups in the transfer hydrogenation of nitroarenes over hydrazine hydrate. Density functional theory calculations revealed that the single atomically dispersed, partially positively charged Fe atoms and the lowered energy barrier collectively contribute to the superior hydrogenation performances for nitroarenes.
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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem