Heterocyclic Building Blocks-benzodioxan

Authors Shen, HM; Hu, MY; Liu, L; Qi, B; Ye, HL; She, YB in ELSEVIER published article about METAL-ORGANIC FRAMEWORKS; AEROBIC OXIDATION; CARBON NANOTUBES; CYCLOHEXANE OXIDATION; GREEN CHEMISTRY; PORPHYRINS; NITROGEN; CUMENE; PRINCIPLES; MECHANISM in [Shen, Hai-Min; Hu, Meng-Yun; Liu, Lei; Qi, Bei; Ye, Hong-Liang; She, Yuan-Bin] Zhejiang Univ Technol, Coll Chem Engn, State Key Lab Breeding Base Green Chem Synth Tech, Hangzhou 310014, Peoples R China in 2020.0, Cited 65.0. Recommanded Product: 1-(4-Nitrophenyl)ethanone. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

The direct and efficient oxidation of tertiary benzylic C-H bonds to alcohols with O-2 was accomplished in the presence of metalloporphyrins as catalysts under solvent-free and additive-free conditions. Based on effective inhibition on the unselective autoxidation and deep oxidation, systematical investigation on the effects of porphyrin ligands and metal centers, and apparent kinetics study, the oxidation system employing porphyrin manganese(II) (T(2,3,6-triCl)PPMn) with bulkier substituents as catalyst, was regarded as the most promising and efficient one. For the typical substrate, the conversion of cumene could reach up to 57.6% with the selectivity of 70.5% toward alcohol, both of them being higher than the current documents under similar conditions. The superiority of T(2,3,6-triCl)PPMn was mainly attributed to its bulkier substituent groups preventing metalloporphyrins from oxidative degradation, its planar structure favoring the interaction between central metal with reactants, and the high efficiency of Mn(II) in the catalytic transformation of hydroperoxides to alcohols.

Recommanded Product: 1-(4-Nitrophenyl)ethanone. Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Computed Properties of C8H7NO3. In 2019.0 NEW J CHEM published article about ONE-POT SYNTHESIS; 2,4-DISUBSTITUTED THIAZOLES; 3-COMPONENT REACTION; DERIVATIVES; ANTIBACTERIAL; ANTAGONISTS; EFFICIENT in [Saroha, Mohit; Khurana, Jitender M.] Univ Delhi, Dept Chem, Delhi 110007, India in 2019.0, Cited 37.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

Acetic acid mediated regioselective synthesis of novel 2,4,5- trisubstituted thiazole derivatives has been reported by a domino reaction of thiosemicarbazide and aldehydes/ ketones/ isatin, to generate thiosemicarbazones ( in situ) followed by addition of arylglyoxal and active methylene/ activated C- H acids/ pyrazole/ indole in ethanol at 80 1C. The products are obtained in high yields by a simple work up. Metal free, short reaction time and high yields are some merits of this methodology.

Computed Properties of C8H7NO3. Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Safety of 1-(4-Nitrophenyl)ethanone. I found the field of Science & Technology – Other Topics; Materials Science very interesting. Saw the article PdO/CuO Nanoparticles on Zeolite-Y for Nitroarene Reduction and Methanol Oxidation published in 2019.0, Reprint Addresses Bania, KK (corresponding author), Tezpur Univ, Dept Chem Sci, Tezpur 784028, Assam, India.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone.

Selective reduction of various nitroarenes to amines was achieved up to 93% under autoclave condition in isopropanol using catalytic amount of palladium oxide/copper oxide (PdO/CuO) nanoparticles (NPs) supported on mesoporous zeolite-Y, PdO/CuO-Y. The catalyst was also found to be highly effective for one-pot cascade synthesis of the 3,3′-diaminobiphenyl from 3-nitrophenylboronic acid (NPBA). The hybridization of PdO/CuO-Y with multiwalled carbon nanotubes (MVVCNTs) resulted in a highly effective and durable electrocatalyst for the methanol oxidation reaction (MOR). The mass activity of the electrocatalyst was found to be 690 A/g and was stable for 4000 s. The catalytic activity of the PdO/CuO-Y catalyst was found to be superior in terms of productivity and recyclability in comparison to that of the bared PdO/CuO NPs separated by the ultracentrifugation (UC) method. On the other hand, the one modified with the carbon matrix retained the same activity and reduced the reaction time in nitroarene reduction reaction (NAR) under identical conditions. Electrochemical studies and density functional theory (DFT) calculations were performed to understand the mechanism of the NAR process. Both the experimental and theoretical evidence explicitly demonstrated the individual role of both palladium (Pd) and copper (Cu). Pd was found to be the active site for nitroarene interaction, while CuO NPs played an important role in isopropanol oxidation.

Safety of 1-(4-Nitrophenyl)ethanone. Welcome to talk about 100-19-6, If you have any questions, you can contact Sharma, M; Das, B; Hazarika, A; Guha, AK; Bhargava, SK; Bania, KK or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Tamuli, KJ; Bordoloi, M in [Tamuli, Kashyap J.; Bordoloi, Manobjyoti] North East Inst Sci & Technol, CSIR, Chem Sci & Technol Div, Jorhat 785006, Assam, India; [Tamuli, Kashyap J.; Bordoloi, Manobjyoti] Acad Sci & Innovat Res, Jorhat 785006, Assam, India published Recyclable Itaconic Acid with Water as Green Catalytic System: Synthesis of Substituted 1,5-Benzodiazepine Derivatives at Room Temperature in 2020.0, Cited 89.0. Product Details of 100-19-6. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

The construction of new C-N chemical bonds through co-condensation reaction in water media as sole solvent, especially without the use of any metal catalyst has undergoes green protocols. Herein, we describe a water-mediated and metal-free mild protocol for easily accessing of structurally and electronically diverse 1,5-benzodiazepine analogous by using biodegradable naturally occurring itaconic acid (20 mol%) in 30 minutes with excellent yields. The simplicity in reaction operation, reusability of the catalytic system and simple filtration to get the desired product make this reaction as green synthetic pathway upto multi gram scale level.

Product Details of 100-19-6. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Tamuli, KJ; Bordoloi, M or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Formula: C14H11N. I found the field of Social Sciences – Other Topics very interesting. Saw the article Algae colonisation of brick pavement at the University of Venda: A potential slippery hazard published in 2019, Reprint Addresses Gumbo, JR (corresponding author), Univ Venda, Dept Hydrol & Water Resource Management, Thohoyandou, South Africa.. The CAS is 86-29-3. Through research, I have a further understanding and discovery of 2,2-Diphenylacetonitrile.

A brick pavement, tramped by humans, is exposed to atmospheric elements, thus allowing cyanobacteria and algae to colonise. In this article, we report on the factors that contribute to the slipperiness of a brick pavement at the University of Venda in the Limpopo province of the South Africa. Samples were collected from brick surfaces either colonised by green algae (treated) or not (control). The samples were acid-digested and analysed for metals by Inductively Coupled Plasma Mass Spectrometry (ICP MS) in parts per billion (ppb). The treated bricks, with green algae, had average high metal contents (ppb): Al 9456.02, Ti 731.23, V 46.44, Cr 78.85, Mn 862.93, Fe 16295.18, Co 23.57, Ni 59.36, Cu 66.31, Zn 160.57, As 7.92, Se 10.45, Mo 6.74, Cd 5.19, Sn 4.65, Sb 2.31 and Pb 19.51. In contrast, control bricks had a low average of metal content (ppb) as follows: Al 2.99, Ti 0.28, V 4.04, Cr 1.42, Mn 4.29, Fe 20.89, Co 0.36, Ni 2.74, Cu 5.64, Zn 4.21, As 0.56, Se <3.00, Mo 0.88, Cd 0.01, Sn 1.05, Sb 0.04 and Pb 0.04. Other factors that promote algae colonisation include high solar radiation, neutral pH, nutrients, low electrical conductivity and total dissolved solids. The algae colonisation of brick pavement results in an unaesthetic sighting and a slippery surface that is hazardous to humans. Bye, fridends, I hope you can learn more about C14H11N, If you have any questions, you can browse other blog as well. See you lster.. Formula: C14H11N

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Authors Smith, JD; Jamhawi, AM; Jasinski, JB; Gallou, F; Ge, J; Advincula, R; Liu, JJ; Handa, S in NATURE PUBLISHING GROUP published article about INTRINSIC MICROPOROSITY; PHOTOREDOX CATALYSIS; RATIONAL DESIGN; ARYL BROMIDES; HALOGEN BOND; LIGHT; WATER; PHOTOOXIDATION; DERIVATIVES; POLYMER in [Smith, Justin D.; Jamhawi, Abdelqader M.; Liu, Jinjun; Handa, Sachin] Univ Louisville, Dept Chem, 2320 South Brook St, Louisville, KY 40292 USA; [Jasinski, Jacek B.] Univ Louisville, Conn Ctr Renewable Energy Res, Mat Characterizat, Louisville, KY 40292 USA; [Gallou, Fabrice] Novartis Pharma AG, CH-4002 Basel, Switzerland; [Ge, Jin; Advincula, Rigoberto] Case Western Reserve Univ, Dept Macromol Sci & Engn, Cleveland, OH 44106 USA in 2019.0, Cited 62.0. Application In Synthesis of 1-(4-Nitrophenyl)ethanone. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

Photocatalytic polymers offer an alternative to prevailing organometallics and nanomaterials, and they may benefit from polymer-mediated catalytic and material enhancements. MPC-1, a polymer photoredox catalyst reported herein, exhibits enhanced catalytic activity arising from charge transfer states (CTSs) between its two chromophores. Oligomeric and polymeric MPC-1 preparations both promote efficient hydrodehalogenation of a-halocarbonyl compounds while exhibiting different solubility properties. The polymer is readily recovered by filtration. MPC-1-coated vessels enable batch and flow photocatalysis, even with opaque reaction mixtures, via backside irradiation. Ultrafast transient absorption spectroscopy indicates a fast charge-transfer process within 20 ps of photoexcitation. Time-resolved photoluminescence measurements reveal an approximate 10 ns lifetime for bright valence states. Ultrafast measurements suggest a long CTS lifetime. Empirical catalytic activities of small-molecule models of MPC-1 subunits support the CTS hypothesis. Density functional theory (DFT) and time-dependent DFT calculations are in good agreement with experimental spectra, spectral peak assignment, and proposed underlying energetics.

Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.. Application In Synthesis of 1-(4-Nitrophenyl)ethanone

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Recently I am researching about ASYMMETRIC TRANSFER HYDROGENATION; AROMATIC KETONES; DERIVATIVES; REDUCTION; ALCOHOLS; BF2, Saw an article supported by the Chemistry Department of Harran University, Sanliurfa, Turkey. Published in TAYLOR & FRANCIS LTD in ABINGDON ,Authors: Kilic, A; Ozbahceci, O; Durgun, M; Aydemir, M. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone. Formula: C8H7NO3

A family of hemi-salen (L1H-L6H) and hemi-salan (L1aH-L2aH) ligands-based N,O-chelated binuclear boron-fluoride [L-n(BF2)(2)] (n = L-1-L-6 or L-1a-L-2a) complexes have been prepared and characterized by a variety of spectroscopic techniques (H-1, C-13 and F-19 NMR, FT-IR, UV-Vis, LC-MS, and fluorescence spectra) and elemental analysis. All of the binuclear boron-fluoride complexes exhibit strong absorption bands due to S-0 -> S-1 transitions and strong fluorescence properties were observed at room temperature in the solution. The binuclear boron complexes containing two naphthyl groups are significantly red-shifted in comparison with the other binuclear boron-fluoride complexes. After the structures are characterized, these hemi-salen and salan ligand-based N, O-chelated binuclear boron-fluoride complexes were utilized to the transfer hydrogenation of the different acetophenone derivatives conversion to 1-phenylethanol derivatives as catalysts.

Formula: C8H7NO3. Welcome to talk about 100-19-6, If you have any questions, you can contact Kilic, A; Ozbahceci, O; Durgun, M; Aydemir, M or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

I found the field of Chemistry very interesting. Saw the article Scissoring Enaminone C=C Double Bond by Free Radical Process for the Synthesis of alpha-Trifluoromethyl Ketones with CF3SO2Na published in 2021.0. Quality Control of 1-(4-Nitrophenyl)ethanone, Reprint Addresses Wan, JP (corresponding author), Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Jiangxi, Peoples R China.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone

The C=C double bond cleavage on tertiary enaminones, enabling the formation of a new C-CF3 bond, has been realized as a practical method for the synthesis of alpha-trifluoromethyl ketones with only the promotion of TBHP and ambient heating. Control experiments support that the reactions proceed via a featured free radical process. The deuterium labeling experiment employing D2O indicates that water participated in the product formation by donating the hydrogen atom for the newly generated alpha-C-H bond in the product.

Quality Control of 1-(4-Nitrophenyl)ethanone. Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Authors Massolo, E; Pirola, M; Puglisi, A; Rossi, S; Benaglia, M in ROYAL SOC CHEMISTRY published article about BETA-ENAMINO ESTERS; ENANTIOSELECTIVE REDUCTION; ASYMMETRIC HYDROSILYLATION; RATIONAL DESIGN; AMINES; PERSPECTIVE; DERIVATIVES; SELECTIVITY; AMIDATION; LIGANDS in [Massolo, Elisabetta; Pirola, Margherita; Puglisi, Alessandra; Rossi, Sergio; Benaglia, Maurizio] Univ Milan, Dipartimento Chim, Via Golgi 19, I-20133 Milan, Italy in 2020, Cited 42. Quality Control of 1-(4-Nitrophenyl)ethanone. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

A two-step one pot, experimentally simple protocol, based on readily available and inexpensive reagents allowed the conversion of nitro-arenes directly to N-aryl amides. A metal-free reduction of the nitro group, mediated by trichlorosilane, followed by the addition of an anhydride afforded the corresponding N-aryl carboxyamide, that was isolated after a simple aqueous work up in good-excellent yields. When the methodology was applied to the reaction with gamma-butyrolactone, the desired N-aryl butanamide derivative was obtained, featuring a chlorine atom at the gamma-position, a functionalized handle that can be used for further synthetic manipulation of the reaction product. Such an intermediate has already been employed as a key advanced precursor of pharmaceutically active compounds.

Quality Control of 1-(4-Nitrophenyl)ethanone. Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

In 2019.0 SYNTHETIC COMMUN published article about INDOLE MOLECULES; INHIBITORS; DESIGN; INDOLE-3-CARBINOL; SCAFFOLD; ANALOGS; NEDD4-1; POTENT in [Gaikwad, Ruchi; Patel, Tarun; Rathore, Anju; Gayen, Shovanlal] Dr Hari Singh Gour Vishwavidyalaya, Dept Pharmaceut Sci, Lab Drug Design & Discovery, Sagar 470003, Madhya Pradesh, India; [Bobde, Yamini; Ganesh, Routholla; Ghosh, Balaram] BITS Pilani, Dept Pharm, Hyderabad Campus, Hyderabad, India; [Das, Kalpataru] Dr Hari Singh Gour Vishwavidyalaya, Dept Chem, Adv Organ Synth Lab, Sagar 470003, Madhya Pradesh, India in 2019.0, Cited 38.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Safety of 1-(4-Nitrophenyl)ethanone

Indole derivatives have attractive anticancer properties and may be a future hope for better anticancer drug(s) of low toxicity and high potency. In this paper, syntheses of 2-phenylindole derivatives have been described via Fischer indole synthesis through a one-pot solvent-free method. The synthesized compounds were screened for anticancer potential in vitro against murine melanoma (B16F10), human lung cancer (A549), and human breast cancer (MDA-MB-231) cell lines. The results highlighted that 2-phenylindole derivatives are also promising anticancer agents in case of melanoma and lung cancer along with the breast cancer. Molecular docking analyses with possible targets for melanoma (NEDD4-1) and lung cancer (EGFR) were also performed to understand specific interactions of 2-phenylindole derivatives with the amino acid residues of the receptors.

Welcome to talk about 100-19-6, If you have any questions, you can contact Gaikwad, R; Bobde, Y; Ganesh, R; Patel, T; Rathore, A; Ghosh, B; Das, K; Gayen, S or send Email.. Safety of 1-(4-Nitrophenyl)ethanone

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem