Recently I am researching about H ACTIVATION; POLYETHYLENE-GLYCOL; ORGANIC-SYNTHESIS; INTERNAL ALKYNES; DIRECTING GROUP; EFFICIENT SYNTHESIS; IRIDIUM COMPLEXES; O BOND; FUNCTIONALIZATION; RHODIUM, Saw an article supported by the University Grants Commission (UGC), New Delhi, IndiaUniversity Grants Commission, India [F.25-1/2014-15, F.7-227/2009]. Formula: C8H7NO3. Published in GEORG THIEME VERLAG KG in STUTTGART ,Authors: Deshmukh, DS; Bhanage, BM. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone
In this work, N-Cbz hydrazone has been employed as a rarely explored directing group for the synthesis of isoquinolines by annulation with internal alkynes via C-H/ N-N activation using Ru catalyst. Additive as well as external oxidant-free rapid protocol has been established for the synthesis of isoquinolines using microwave strategy. Use of non-volatile and biodegradable PEG as a green solvent with lower catalyst loading makes the proposed protocol environmentally benign. Further, higher functional group tolerance and wide substrate scope has been observed under the stated methodology with higher yields.
About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Deshmukh, DS; Bhanage, BM or concate me.. Formula: C8H7NO3
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem