Tag: M.W=150-200

An article Catalytic application of sulfamic acid-functionalized magnetic Fe3O4 nanoparticles (SA-MNPs) for protection of aromatic carbonyl compounds and alcohols: experimental and theoretical studies WOS:000601124900038 published article about EFFICIENT CATALYST; SULFONIC-ACID; GAMMA-FE2O3 NANOPARTICLES; SULFURIC-ACID; ACETALIZATION; ACETALS; METHOXYMETHYLATION; ALDEHYDES; DITHIOACETALIZATION; HYDROLYSIS in [Khaef, Sepideh; Zolfigol, Mohammad Ali; Yarie, Meysam] Bu Ali Sina Univ, Dept Organ Chem, Fac Chem, Hamadan, Hamadan, Iran; [Khaef, Sepideh; Taherpour, Avat Arman] Razi Univ, Dept Organ Chem, Fac Chem, Kermanshah, Iran in 2020.0, Cited 92.0. Recommanded Product: 100-19-6. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

Protection techniques of functional groups within the structure of organic compounds are important synthetic methods against unwanted attacks from various reagents during synthetic sequences. Acetal and thioacetal groups are well known as protective functional groups in organic reactions. In this study, acetalization of carbonyl compounds with diols and dithiols and methoxymethylation of alcohols with formaldehyde dimethyl acetal (FDMA) have been carried out using sulfamic acid-functionalized magnetic Fe3O4 nanoparticles (SA-MNPs) as a heterogeneous solid acid catalyst. Products were characterized by FT-IR and NMR spectroscopies. The structural and electronic properties of some products were computed by quantum mechanical (QM) methods. Depending on the stereochemistry and electronic properties that were obtained by computational results, we have suggested that hyperconjugation plays a key role in the structural properties of 2-phenyl-1,3-dioxolane derivatives, and also the electron transfer between pi-electrons of the aromatic ring with the 3d orbital of S-atoms influences the 2-phenyl-1,3-dithiane derivatives’ structure.

Recommanded Product: 100-19-6. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Khaef, S; Zolfigol, MA; Taherpour, AA; Yarie, M or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Direct Oxygenation of C-H Bonds through Photoredox and Palladium Catalysis WOS:000518875700051 published article about METAL-FREE; COUPLING REACTIONS; ARYL; ACETOXYLATION; FUNCTIONALIZATION; HYDROXYLATION; OXIDATION; ACTIVATION; DERIVATIVES; ARENES in [Shah, Sk. Sheriff; Shee, Maniklal; Singh, Amit Kumar; Paul, Amrita; Singh, N. D. Pradeep] Indian Inst Technol Kharagpur, Dept Chem, Kharagpur 721302, W Bengal, India in 2020.0, Cited 97.0. Name: 1-(4-Nitrophenyl)ethanone. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

This report presents the oxygenation of C-H bonds via the merger of photocatalysis and Pd catalysis. Herein, we describe the utilization of a photocatalyst to oxidize an organopalladium(II) intermediate to high-valent Pd-III or Pd-IV intermediates, which promotes the formation of C-O bonds. The demonstrated method works efficiently with various directing groups, such as oxime ether and benzothiazole. The applicability of this direct C-O bond formation method is shown by synthesizing several metal complexes of 2-(benzo[d]thiazol-2-yl)phenol that can be used in organic light-emitting diodes and pharmaceuticals.

Name: 1-(4-Nitrophenyl)ethanone. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Shah, SS; Shee, M; Singh, AK; Paul, A; Singh, NDP or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Lipase-oxovanadium heterogeneous catalysis system: a robust protocol for the dynamic kinetic resolution of sec-alcohols WOS:000523208900001 published article about MESOPOROUS-SILICA; ENANTIOSELECTIVITY; RACEMIZATION; TRANSESTERIFICATION; PERFORMANCE; RUTHENIUM; VANADIUM; ROUTE in [De Almeida, Laiza A.; Marcondes, Thayna H.; Milagre, Cintia D. F.; Milagre, Humberto M. S.] Sao Paulo State Univ, UNESP, Inst Chem, BR-14800060 Araraquara, SP, Brazil in 2020.0, Cited 41.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Computed Properties of C8H7NO3

Herein, we present a robust and eco-friendly dynamic kinetic resolution (DKR) protocol for secondary alcohols using a combined heterogeneous catalytic CAL-B/VOSO4 system at 50 degrees C in the relatively green solvent heptane. This catalytic system is active and chemo- and enantioselective for up to 5 cycles. A set of 13 aromatic and heteroaromatic secondary alcohols were evaluated to determine the substrate scope. The performance of the combined CAL-B/VOSO4 system was improved by employing a low-cost, homemade Teflon tube to compartmentalize the catalysts in one-pot conditions, making this system for up to 8 reaction cycles.

Computed Properties of C8H7NO3. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact De Almeida, LA; Marcondes, TH; Milagre, CDF; Milagre, HMS or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Category: benzodioxans. Recently I am researching about BETA-ENAMINO ESTERS; ENANTIOSELECTIVE REDUCTION; ASYMMETRIC HYDROSILYLATION; RATIONAL DESIGN; AMINES; PERSPECTIVE; DERIVATIVES; SELECTIVITY; AMIDATION; LIGANDS, Saw an article supported by the Regione LombardiaRegione Lombardia; Universita degli Studi di Milano (grant PSR 2017); Universita degli Studi di Milano. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Massolo, E; Pirola, M; Puglisi, A; Rossi, S; Benaglia, M. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone

A two-step one pot, experimentally simple protocol, based on readily available and inexpensive reagents allowed the conversion of nitro-arenes directly to N-aryl amides. A metal-free reduction of the nitro group, mediated by trichlorosilane, followed by the addition of an anhydride afforded the corresponding N-aryl carboxyamide, that was isolated after a simple aqueous work up in good-excellent yields. When the methodology was applied to the reaction with gamma-butyrolactone, the desired N-aryl butanamide derivative was obtained, featuring a chlorine atom at the gamma-position, a functionalized handle that can be used for further synthetic manipulation of the reaction product. Such an intermediate has already been employed as a key advanced precursor of pharmaceutically active compounds.

About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Massolo, E; Pirola, M; Puglisi, A; Rossi, S; Benaglia, M or concate me.. Category: benzodioxans

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Computed Properties of C8H7NO3. I found the field of Pharmacology & Pharmacy; Chemistry very interesting. Saw the article Anti-cancer potential of novel glycosylated 1,4-substituted triazolylchalcone derivatives published in 2019.0, Reprint Addresses Jana, K; Misra, AK (corresponding author), Bose Inst, Div Mol Med, P-1-12,CIT Scheme 7 M, Kolkata 700054, India.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone.

A series of glycosylated 1,4-substituted triazolyl chalcone derivatives (8a-f and 14a-r) were synthesized in high yield using 1,3-cycloaddition (Click chemistry) of D-glucosyl azides with a variety of propargylated chalcone derivatives followed by de-O-acetylation. The synthesized compounds were evaluated for their cytotoxic potential against the human breast carcinoma cell lines and non-cancerous cells. The MTT assay identified three promising cytotoxic compounds (14c, 14i and 14l) and further biochemical and microscopic studies were carried out with the best compound 14i among the active compounds.

Computed Properties of C8H7NO3. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Manna, T; Pal, K; Jana, K; Misra, AK or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Recently I am researching about PHOSPHONATE DERIVATIVES; INHIBITORS; ANTIBACTERIAL, Saw an article supported by the National Research, Development and Innovation Office (NKFIH project) [TET_16-1-2016-0111]. Published in TAYLOR & FRANCIS LTD in ABINGDON ,Authors: Kiss, NZ; Radai, Z; Keglevich, G. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone. Recommanded Product: 100-19-6

alpha-Hydroxyphosphonates have been in the focus of interest for many years due to their potential in biological activity. Not only alpha-hydroxyphosphonates are of general importance, but also their derivatives. alpha-Aminophosphonates and alpha-hydroxyphosphonic acids have already been recognized for their biological effects, while phosphoryloxyphosphonates represent a new family of compounds. In this paper we present alternative syntheses towards alpha-hydroxyphosphonates and their derivatives.

Recommanded Product: 100-19-6. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Kiss, NZ; Radai, Z; Keglevich, G or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Recently I am researching about CYCLODEXTRIN-BASED NANOSPONGES; GOLD NANOPARTICLES; NANOMATERIALS; MICROSPHERES; OXIDATION; COMPOSITE; CHEMISTRY; CLUSTERS; ENERGY; SUZUKI, Saw an article supported by the Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities [2042016HF1054]. Quality Control of 1-(4-Nitrophenyl)ethanone. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Qi, B; Wu, CC; Liu, Y; Liu, J; Zhang, HB. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone

Self-assembled nanotechnology has been used widely in various well-defined microstructures fabrication. Herein, this synthetic protocol was successfully utilized to in situ or hierarchically prepare magnetic Pt nanocomposites Fe3O4@Pt via a distinguishing two-step process. The distinction of these two pathways is due to the different synthetic processes. In the case of in situ preparation (Path I), it involves a supramolecular self-assembly of boron clusters with gamma-CD on Fe3O4 substrate and then followed by in situ formation of Pt nanoparticles (NPs). But in the case of hierarchical preparation (Path II), the first step is preparing Pt NPs colloids reduced by boron clusters Cs-2[closo-B12H12], and subsequent step is immobilizing the as-prepared [closo-B12H12](2-)-capped Pt NPs on the Fe3O4@gamma-CD. The success of these two fabrication strategies lies in the use of trifunctional boron clusters (reductant, stabilizer, and superchaotropic anchor). Both of the as-prepared Fe3O4@Pt nanocomposites showed good catalytic performance in the selective nitro-group reduction of nitroaromatics. A control test further indicated that the in situ prepared Fe3O4@Pt nanocomposites, with smaller size and higher loading of Pt NPs, exhibited a better catalytic performance and recyclability.

Quality Control of 1-(4-Nitrophenyl)ethanone. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Qi, B; Wu, CC; Liu, Y; Liu, J; Zhang, HB or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Biocompatibility, in Vitro Antiproliferative, and in Silico EGFR/VEGFR2 Studies of Heteroleptic Metal(II) Complexes of Thiosemicarbazones and Naproxen WOS:000482173200010 published article about MIXED-LIGAND COMPLEXES; DNA INTERACTION; ANTICANCER ACTIVITY; ZINC(II) COMPLEXES; MOLECULAR DOCKING; GROWTH-INHIBITION; CANCER-CELLS; COPPER(II); NICKEL(II); BINDING in [Bharathi, Sundaram; Mahendiran, Dharmasivam; Rahiman, Aziz Kahlur] Univ Madras, New Coll Autonomous, Postgrad & Res Dept Chem, Chennai 600014, Tamil Nadu, India; [Mahendiran, Dharmasivam] Univ Sydney, Bosch Inst, Dept Pathol, Mol Pharmacol & Pathol Program, Sydney, NSW 2006, Australia; [Kumar, Raju Senthil] Swamy Vivekanandha Coll Pharm, Dept Pharmaceut Chem, Elayampalayam 637205, Tiruchengodu, India; [Kim, Young Guk; Gajendiran, Mani; Kim, Kyobum] Incheon Natl Univ, Sch Life Sci & Bioengn, Div Bioengn, Incheon 22012, South Korea in 2019.0, Cited 48.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. Computed Properties of C8H7NO3

Eight heteroleptic nickel(II) and copper(II) complexes of the type [M(L1-4)(nap)(2)] (1-8), where L1-4 = 2-(1-(4-substitutedphenyl)ethylidene)-hydrazinecarbothioamide, nap = naproxen, and M = Ni(II) or Cu(II), have been synthesized and characterized. UV-vis and EPR spectral studies showed distorted octahedral geometry around metal(II) ions. The cyclic voltammogram of complexes 1-8 displayed an irreversible one-electron transfer process in the cathodic region (E-pc = -0.66 to -1.43 V), and nickel(II) complexes 1-4 displayed an irreversible one-electron oxidation process in the anodic region (E-pa = 0.75 to 1.10 V). The obtained magnetic moment values (1.82-1.93 mu(B)) for copper(II) complexes 5-8 indicate distortion from octahedral geometry, which is further supported by EPR studies. The geometry of the complexes is retained in both solid and solution phases as evidenced from UV-vis and EPR studies. All the complexes showed stability for almost 72 h in biologically relevant solutions. The reducing ability of the copper(II) complexes in the presence of ascorbic acid was analyzed by UV-vis and cyclic voltammetry techniques, which indicates the reduction of the copper(II) to a copper(I) center, and possible interaction within the cells. An in vitro antiproliferative study revealed the nontoxic nature of complexes to normal human dermal fibroblast (NHDF) up to a concentration of 100 ng/mL. The antiproliferative activity of the complexes was tested against three cancerous (human breast adenocarcinoma (MCF-7), hepatoma (HepG2), and lung (A549)) cell lines using MTT reduction assay, which showed enhanced activity for complexes 4 and 8 containing the hydrophobic substituent. Apoptotic and cellular uptake studies showed that complex 8 is readily taken up by HepG2 cell lines and induces ROS-mediated mitochondrial and caspase-dependent apoptosis. In silico studies indicated hydrogen bonding, hydrophobic, and pi-pair (pi-pi, pi-sigma, and pi-cation) interactions between the complexes and EGFR/VEGFR2 kinase receptors.

Computed Properties of C8H7NO3. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Bharathi, S; Mahendiran, D; Kumar, RS; Kim, YG; Gajendiran, M; Kim, K; Rahiman, AK or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Authors Bao, ZP; Miao, RG; Qi, XX; Wu, XF in ROYAL SOC CHEMISTRY published article about in [Bao, Zhi-Peng; Miao, Ren-Guan; Qi, Xinxin] Zhejiang Sci Tech Univ, Dept Chem, Hangzhou 310018, Zhejiang, Peoples R China; [Wu, Xiao-Feng] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China; [Wu, Xiao-Feng] Inst Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany in 2021, Cited 36. Name: 1-(4-Nitrophenyl)ethanone. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

Dimethyl carbonate (DMC), an environment-friendly compound prepared from CO2, shows diverse reactivities. In this communication, an efficient procedure using DMC as both a C1 building block and solvent in the aminocarbonylation reaction with nitro compounds has been developed. W(CO)(6) acts both a CO source and a reductant here.

Name: 1-(4-Nitrophenyl)ethanone. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Bao, ZP; Miao, RG; Qi, XX; Wu, XF or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Ding, YX; Ma, RC; Hider, RC; Ma, YM in [Ding, Yuxin; Ma, Renchao; Ma, Yongmin] Taizhou Univ, Sch Pharmaceut & Chem Engn, Taizhou 318000, Peoples R China; [Ding, Yuxin; Ma, Yongmin] Zhejiang Chinese Med Univ, Sch Pharmaceut Sci, Hangzhou 310053, Peoples R China; [Hider, Robert C.] Kings Coll London, Inst Pharmaceut Sci, Franklin Wilkins Bldg,Stamford St, London SE1 9NH, England published Acid-Catalyzed Pseudo Five-Component Annulation for a General One-Pot Synthesis of 2,4,6-Triaryl Pyrimidines in 2020.0, Cited 65.0. SDS of cas: 100-19-6. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

A facile and general synthesis of 2,4,6-triaryl pyrimidines has been developed. It involves a one-pot [2+1+1+1+1] pseudo five-component annulation of one methyl ketone, two aldehydes and two NH4OAc catalyzed by TfOH. One C-C and four C-N bonds are formed during the oxidative annulation process. The reaction shows good tolerance of many important functional groups in air and produces only water as the coproduct, making this methodology a highly versatile alternative to the existing methods for structuring pyrimidine framework.

About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Ding, YX; Ma, RC; Hider, RC; Ma, YM or concate me.. SDS of cas: 100-19-6

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem