Tag: M.W=150-200

Formula: C8H7NO3. In 2021.0 J ORG CHEM published article about TRANSITION-METAL-COMPLEXES; N-HETEROCYCLIC CARBENES; COORDINATION CHEMISTRY; CYCLOPENTADIENYL COMPLEXES; YTTRIUM COMPLEXES; ALDEHYDES; AMIDO; ALKYL; BOND; IMIDAZOLIN-2-IMINATO in [Anga, Srinivas; Acharya, Joydev; Chandrasekhar, Vadapalli] Tata Inst Fundamental Res Hyderabad, Hyderabad 500046, India; [Acharya, Joydev; Chandrasekhar, Vadapalli] IIT Kanpur, Dept Chem, Kanpur 208016, Uttar Pradesh, India in 2021.0, Cited 101.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

An imino-phosphanamide ligand, [NHIiPrMe2 P(Ph)NH-2,6-(Pr2C6H3)-Pr-i] (LH), containing two different N-substituents was prepared by the direct reaction of the lithium salt of N-heterocyclic imine (NHI) with phenylchloro-2,6-diisopropylphenyl phosphanamine, PhP(CONH-2,6-Pr-i(2)-C6H3. Reaction of LH with Y(N-(SiMe3)(2))(3) afforded the heteroleptic complex, [{L}Y(N(SiMe3)(2))(2)] (1), by elimination of HN(SiMe3)(2). Compound 1 was characterized by multinuclear NMR and X-ray crystallography. In the complex, the Y(III) center was found to be tetracoordinate in a distorted tetrahedral geometry. The ligand, imino-phosphanamidinate, [L] , functions in a chelating manner, and its coordination to Y(III) results in a distorted 4-membered YPN2 ring. As a proof of principle of its activity, 1 was used as a precatalyst for the hydroboration of various aldehydes and ketones using HBpin as the hydrogen source. The hydroboration reaction was rapid and clean even with low catalyst loadings (0.01-0.1 mol %). In addition, a very good functional group tolerance was observed in these reactions.

Welcome to talk about 100-19-6, If you have any questions, you can contact Anga, S; Acharya, J; Chandrasekhar, V or send Email.. Formula: C8H7NO3

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Recently I am researching about DIHYDROFOLATE-REDUCTASE INHIBITORS; ANTIOPPORTUNISTIC INFECTION AGENTS; DUAL THYMIDYLATE SYNTHASE; DERIVATIVES; ANTITUMOR; POTENT; DISCOVERY; DESIGN, Saw an article supported by the 973 ProjectNational Basic Research Program of China [2013CB911002]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [31761133012, 31530016]; Shenzhen Science and Technology Innovation Commission [JCYJ20170412113009742, JCYJ20180307182213033]. Published in ACADEMIC PRESS INC ELSEVIER SCIENCE in SAN DIEGO ,Authors: Wang, FC; Peng, B; Cao, SL; Li, HY; Yuan, XL; Zhang, TT; Shi, RF; Li, ZQ; Liao, J; Wang, HL; Li, J; Xu, XZ. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone. Recommanded Product: 100-19-6

Many natural or synthetic chalcones have potential anti-tumor activity. Here, we synthesized two series of chalcone analogues containing a thieno [2,3-cflpyrimidin-2-y] group and evaluated for their cytotoxic activity towards cultured human lung cancer A549 and colorectal HCT-116 cells. Among them, compound 8d was the most cytotoxic against HCT-116 cells, with an IC50 value of 2.65 mu M. Analyses of the phenotypic changes induced by this compound found a dose-dependent accumulation of HCT-116 cells in sub-G1 phase, indicating that compound 8d might induce apoptosis. Furthermore, we found that 8d triggered mitochondrial membrane potential depolarization, promoted reactive oxygen species formation in HCT-116 cells, and increased the percentage of early and late apoptotic cells. Finally, immunoblotting indicated that 8d increased PARP-1 and caspases 3, 7 and 9 cleavage. These data suggest that compound 8d induces apoptosis via the mitochondrial death pathway.

Welcome to talk about 100-19-6, If you have any questions, you can contact Wang, FC; Peng, B; Cao, SL; Li, HY; Yuan, XL; Zhang, TT; Shi, RF; Li, ZQ; Liao, J; Wang, HL; Li, J; Xu, XZ or send Email.. Recommanded Product: 100-19-6

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

An article Transition-metal-free selective pyrimidines and pyridines formation from aromatic ketones, aldehydes and ammonium salts WOS:000488459900004 published article about DIELS-ALDER REACTIONS; MULTICOMPONENT REACTIONS; ALPHA,BETA-UNSATURATED KETONES; STEP SYNTHESIS; 3+3 ANNULATION; DERIVATIVES; CYCLOADDITIONS; NITRILES; HETEROCYCLES; DISCOVERY in [Chen, Jinjin; Meng, Huanxin; Zhang, Feng; Xiao, Fuhong; Deng, Guo-Jun] Xiangtan Univ, Key Lab Green Organ Synth & Applicat Hunan Prov, Key Lab Environmentally Friendly Chem & Applicat, Minist Educ,Coll Chem, Xiangtan 411105, Peoples R China; [Zhang, Feng] Hunan Agr Univ, Coll Sci, Changsha 410128, Hunan, Peoples R China in 2019.0, Cited 105.0. Formula: C8H7NO3. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

An efficient synthesis of pyrimidines and pyridines has been developed from readily available aromatic ketones, aldehydes and ammonium salts under transition-metal-free conditions. In this strategy, ammonium salts were used as nitrogen sources and only water was generated as a nontoxic byproduct. A catalytic amount of NaIO4 played an important role in the selectivity control, whereas substituted pyridines were dominantly formed in its absence.

Formula: C8H7NO3. Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Category: benzodioxans. Recently I am researching about NICKEL ALLOY NANOPARTICLES; SODIUM-BOROHYDRIDE; HETEROGENEOUS CATALYST; EFFICIENT CATALYST; CARBON NANOTUBE; DEHYDROGENATION; REDUCTION; POLYMER; NANOSPHERES; BORANE, Saw an article supported by the Dumlupinar University BAP grantDumlupinar University [2014-05]. Published in ELSEVIER in AMSTERDAM ,Authors: Bilgicli, HG; Burhan, H; Diler, F; Cellat, K; Kuyuldar, E; Zengin, M; Sen, F. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone

Herein, the composite of palladium nanoparticles and graphene oxide (CPG) has been synthesized by a facile and very efficient method that provided chemical selectivity and high catalytic activity. The synthesized CPG was characterized by several techniques such as transmission and high-resolution electron microscopy (TEM and HR-TEM), X-ray diffraction (XRD) and Raman spectroscopy, and Photoelectron spectroscopy (XPS). CPG was tested for selective reduction of nitroarenes at room temperature. After the addition of CPG to the reaction media, catalytic performances were depended upon the cooperative effect of hydrogen activation with Pd nanoparticles, where the lack of electrons favors an excellent performance. Nitroarenes can be bound to the energetically preferred adsorption site for the nitro group in electrically enriched graphene oxide. In addition, the Pd nanoparticles transfer electrons to the graphene oxide which increases the functions of metal and carbon support. CPG exhibits both chemoprotective and high catalytic performance for hydrogenation of nitroarenes at room temperature. Aniline derivatives were obtained with high yields under mild conditions and a practical catalytic system was developed by the use of CPG.

Welcome to talk about 100-19-6, If you have any questions, you can contact Bilgicli, HG; Burhan, H; Diler, F; Cellat, K; Kuyuldar, E; Zengin, M; Sen, F or send Email.. Category: benzodioxans

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

SDS of cas: 100-19-6. In 2019.0 POLYHEDRON published article about ASYMMETRIC TRANSFER HYDROGENATION; SCHIFF-BASE LIGAND; EFFECTIVE CORE POTENTIALS; DENSITY-FUNCTIONAL THEORY; MOLECULAR CALCULATIONS; EXCITATION-ENERGIES; CARBON-SULFUR; RUTHENIUM(II); ACTIVATION; SULFINATO in [Roy, Puspendu; Manna, Chandan Kumar; Naskar, Rahul; Mondal, Tapan Kumar] Jadavpur Univ, Dept Chem, Kolkata 700032, India; [Roy, Puspendu] Univ Calcutta, Dept Chem, Netaji Nagar Day Coll, Kolkata 700092, India in 2019.0, Cited 49.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

A new rhodium(III) triphenylphosphine complex having the general formula [Rh(PPh3)(2)(L)Cl] (1) was synthesized by C-S bond cleavage of an ONS donor azo-thioether ligand (L-CH2Ph). The complex was thoroughly characterized by various spectroscopic techniques. Its single crystal X-ray structure exhibits an octahedral geometry around the rhodium(III) center. A cyclic voltammogram of the complex exhibits ligand based quasi-irreversible oxidative and reductive responses. The electronic structure, redox properties and electronic excitations in the complex were interpreted by DFT and TDDFT calculations. The complex effectively catalyzed the transfer hydrogenation reaction of ketones with high yields in i-PrOH in the presence of a base. (C) 2018 Elsevier Ltd. All rights reserved.

SDS of cas: 100-19-6. Welcome to talk about 100-19-6, If you have any questions, you can contact Roy, P; Manna, CK; Naskar, R; Mondal, TK or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Product Details of 100-19-6. In 2019.0 ORG LETT published article about ONE-POT SYNTHESIS; SUBSTITUTED CARBAZOLES; H FUNCTIONALIZATION; INDOLES; CYCLIZATION; ALKYNES; AMINATION; ACCESS; CYCLOISOMERIZATION; HYDROARYLATION in [Ni, Penghui; Tan, Jing; Zhao, Wenqi; Huang, Huawen; Xiao, Fuhong; Deng, Guo-Jun] Xiangtan Univ, Key Lab Environm Friendly Chem & Applicat, Key Lab Green Organ Synth & Applicat Hunan Prov, Minist Educ,Coll Chem, Xiangtan 411105, Peoples R China in 2019.0, Cited 73.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

A metal-free strategy for the synthesis of benzocarbazoles from 2-arylindoles and aryl ketones is developed. Various 2-aryl-3-vinyl-indoles were generated in situ through dehydrative condensation of aryl ketones and indoles. These key intermediates could be selectively converted into the corresponding benzo[a]carbazoles via a direct cyclization process between two Csp(2)-H bonds. Furthermore, terminal alkynes also could be used as the versatile C2 source to afford the corresponding products in good yields.

Welcome to talk about 100-19-6, If you have any questions, you can contact Ni, PH; Tan, J; Zhao, WQ; Huang, HW; Xiao, FH; Deng, GJ or send Email.. Product Details of 100-19-6

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Quality Control of 1-(4-Nitrophenyl)ethanone. I found the field of Biochemistry & Molecular Biology; Chemistry very interesting. Saw the article Synthesis and Bioactivity of Thiosemicarbazones Containing Adamantane Skeletons published in 2020.0, Reprint Addresses Vu, BD (corresponding author), Vietnam Mil Med Univ, Drug R&D Ctr, 160,Phung Hung St,Phuc La Ward, Hanoi 100000, Vietnam.; Phan, DC (corresponding author), Hanoi Univ Sci & Technol, 1,Dai Co Viet St,Bach Khoa Ward, Hanoi 100000, Vietnam.. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone.

Reaction of 4-(1-adamantyl)-3-thiosemicarbazide (1) with numerous substituted acetophenones and benzaldehydes yielded the corresponding thiosemicarbazones containing adamantane skeletons. The synthesized compounds were evaluated for their in vitro activities against some Gram-positive and Gram-negative bacteria, and the fungus Candida albicans, and cytotoxicity against four cancer cell lines (Hep3B, HeLa, A549, and MCF-7). All of them showed good antifungal activity against Candida albicans. Compounds 2c, 2d, 2g, 2j and 3a, 3e, 3g displayed significant inhibitory activity against Enterococcus faecalis. Compounds 2a, 2e, 2h, 2k and 3j had moderate inhibitory potency against Staphylococcus aureus. Compounds 2a, 2e and 2g found so good inhibitory effect on Bacillus cereus. Compounds 2d and 2h, which contain (ortho) hydroxyl groups on the phenyl ring, were shown to be good candidates as potential agents for killing the tested cancer cell lines, i.e., Hep3B, A549, and MCF-7. Compounds 2a-c, 2f, 2g, 2j, 2k, 3g, and 3i were moderate inhibitors against MCF-7.

Quality Control of 1-(4-Nitrophenyl)ethanone. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Pham, VH; Phan, TPD; Phan, DC; Vu, BD or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

In 2020.0 NEW J CHEM published article about AG-AT-AGCL; HIGHLY EFFICIENT; SELECTIVE OXIDATION; PHOTOCATALYTIC ACTIVITY; BENZYL ALCOHOL; AEROBIC OXIDATION; ESCHERICHIA-COLI; STYRENE; EPOXIDATION; DEGRADATION in [Hosseini-Sarvari, Mona; Dehghani, Abdulhamid] Shiraz Univ, Dept Chem, Shiraz 7194684795, Iran in 2020.0, Cited 79.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. SDS of cas: 100-19-6

The Ag/AgBr/TiO2 ternary component nanotube as a heterogeneous photocatalyst was used for the solvent-free oxidation of the benzylic C(sp(3))-H bond to the corresponding carbonyl compound or the solvent-controlled selective oxidative cleavage of the CQC double bond of styrene to benzaldehyde under visible light at room temperature. A wide variety of carbonyl compounds were successfully synthesized through the developed photocatalytic process. Several advantages such as solvent-free conditions, sans additional oxidant, simple reaction, short reaction time, and easy separation of the product promote the reaction to be green. Moreover, the Ag/AgBr/TiO2 nanotubes could be used several times without reduction in their photocatalytic activity.

Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.. SDS of cas: 100-19-6

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Authors Ni, PH; Tan, J; Zhao, WQ; Huang, HW; Deng, GJ in WILEY-V C H VERLAG GMBH published article about COUPLING REACTIONS; CATALYZED SYNTHESIS; DIARYL SELENIDES; CASCADE REACTION; BOND FORMATION; ARYL HALIDES; INDOLES; CHALCOGENATION; DISELENIDES; ALKENES in [Ni, Penghui; Tan, Jing; Zhao, Wenqi; Huang, Huawen; Deng, Guo-Jun] Xiangtan Univ, Key Lab Environm Friendly Chem & Applicat, Key Lab Green Organ Synth & Applicat Hunan Prov, Minist Educ,Coll Chem, Xiangtan 411105, Peoples R China; [Deng, Guo-Jun] Chinese Acad Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China; [Deng, Guo-Jun] Chinese Acad Sci, Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China in 2019.0, Cited 79.0. Recommanded Product: 1-(4-Nitrophenyl)ethanone. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6

A facile metal-free entry to novel selenopheno[2,3-b]indole motif is described. The three-component assembly of indoles, aromatic ketones, and selenium powder is enabled by the IBr-promoted highly selective double C-H selenylation/annulation. This protocol provides a novel access to a diverse variety of selenopheno[2,3-b]indoles with good efficacy and broad functional group compatibility.

Recommanded Product: 1-(4-Nitrophenyl)ethanone. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Ni, PH; Tan, J; Zhao, WQ; Huang, HW; Deng, GJ or concate me.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem

Product Details of 100-19-6. Liu, MY; Zhang, ZR; Liu, HZ; Wu, TB; Han, BX in [Liu, Mingyang; Zhang, Zhanrong; Liu, Huizhen; Wu, Tianbin; Han, Buxing] Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Colloid & Interface & Thermodynam, CAS Res Educ Ctr Excellence Mol Sci,Inst Chem, Beijing 100190, Peoples R China; [Liu, Mingyang; Liu, Huizhen; Wu, Tianbin; Han, Buxing] Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China; [Liu, Mingyang; Zhang, Zhanrong; Liu, Huizhen; Han, Buxing] Huairou Natl Comprehens Sci Ctr, Phys Sci Lab, 5 Yanqi East Second St, Beijing 101400, Peoples R China published Dehydroxyalkylative halogenation of C(aryl)-C bonds of aryl alcohols in 2020.0, Cited 42.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.

We herein report Cu mediated side-directed dehydroxyalkylative halogenation of aryl alcohols. C(aryl)-C bonds of aryl alcohols were effectively cleaved, affording the corresponding aryl chlorides, bromides and iodides in excellent yields. Aryl alcohols could serve as both aromatic electrophilic and radical synthetic equivalents during the reaction.

Product Details of 100-19-6. Welcome to talk about 100-19-6, If you have any questions, you can contact Liu, MY; Zhang, ZR; Liu, HZ; Wu, TB; Han, BX or send Email.

Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem