Fernandes, RA; Ramakrishna, GV; Bethi, V in [Fernandes, Rodney A.; Ramakrishna, Gujjula, V; Bethi, Venkati] Indian Inst Technol, Dept Chem, Mumbai 400076, Maharashtra, India published MnO(2)as a terminal oxidant in Wacker oxidation of homoallyl alcohols and terminal olefins in 2020.0, Cited 80.0. Quality Control of 1-(4-Nitrophenyl)ethanone. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6.
Efficient and mild reaction conditions for Wacker-type oxidation of terminal olefins of less explored homoallyl alcohols to beta-hydroxy-methyl ketones have been developed by using a Pd(ii) catalyst and MnO(2)as a co-oxidant. The method involves mild reaction conditions and shows good functional group compatibility along with high regio- and chemoselectivity. While our earlier system of PdCl2/CrO3/HCl produced alpha,beta-unsaturated ketones from homoallyl alcohols, the present method provided orthogonally the beta-hydroxy-methyl ketones. No overoxidation or elimination of benzylic and/or beta-hydroxy groups was observed. The method could be extended to the oxidation of simple terminal olefins as well, to methyl ketones, displaying its versatility. An application to the regioselective synthesis of gingerol is demonstrated.
Quality Control of 1-(4-Nitrophenyl)ethanone. About 1-(4-Nitrophenyl)ethanone, If you have any questions, you can contact Fernandes, RA; Ramakrishna, GV; Bethi, V or concate me.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem