Safety of 2,2-Diphenylacetonitrile. I found the field of Chemistry very interesting. Saw the article Olefin Oxyamination with Unfunctionalized N-Alkylanilines published in 2019, Reprint Addresses Niggeman, M (corresponding author), Rhein Westfal TH Aachen, Inst Organ Chem, Landoltweg 1, D-52074 Aachen, Germany.. The CAS is 86-29-3. Through research, I have a further understanding and discovery of 2,2-Diphenylacetonitrile.
N-Alkylanilines have rarely been used in oxyamination reactions, due to the normally necessary pre-functionalization of the N-atom. Also, the formation of aminium radical cations (ARCs) of anilines bearing alkyl substituents is plagued by the ARC’s tendency to instantaneously convert to alpha-amino radicals or iminium ions. We present a readily available reagent combination that addresses both challenges, and thus allows for an oxyamination with N-alkylanilines via ARCs as the crucial reactive intermediates and excellent diastereoselectivity.
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Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem