In 2019.0 INORG CHIM ACTA published article about H BOND ACTIVATION; RU SINGLE BOND; AMIDO COMPLEXES; TITANIUM IMIDO; BASE-FREE; REACTIVITY; H-2; 2-(2-PYRIDYL)-1,8-NAPHTHYRIDINE; CYCLOADDITION; GENERATION in [Gajardo, Juana] Univ San Sebastian, Fac Ciencias, Dept Ciencias Biol & Quim, Santiago, Chile; [Araya, Juan C.] Univ Cent, Fac Ciencias Salud, Ctr Ciencias Basicas, Santiago, Chile; [Ibanez, Andres] Univ Chile, Fac Ciencias Fis & Matemat, Santiago, Chile; [Guerchais, Veronique; Le Bozec, Hubert] Univ Rennes 1, UMR 6226 CNRS, Sci Chim Rennes, Campus Beaulieu, F-35042 Rennes, France; [Moya, Sergio A.] Univ Santiago Chile, Fac Quim & Biol, Avda Libertador Bernardo OHiggins 3363,Casilla 40, Santiago, Chile; [Aguirre, Pedro] Univ Chile, Fac Ciencias Quim & Farmaceut, Santiago, Chile in 2019.0, Cited 62.0. The Name is 1-(4-Nitrophenyl)ethanone. Through research, I have a further understanding and discovery of 100-19-6. SDS of cas: 100-19-6
A new series of novel complexes of type cis-[Ru(CO)(2)Cl-2(L)(2)], L = 2-phenyl-1,8-naphthyridine, 2-(4′-nitrophenyl)-1,8-naphthyridine, 2-(4′-bromophenyl)-1,8-naphthyridine, 2-(4′-methylphenyl)-1,8-naphthyridine, 2-(3′-methoxyphenyl)-1,8-naphthyridine, 2-(2′-methoxyphenyl)-1,8-naphthyridine and 2-(4′-methoxyphenyl)-1,8-naphthyridine have been successfully synthesized and characterized. We found that the complexes can be directly synthesized from [RuCl2(CO)(2)](2) with high yield. The crystallographic structures of complex cis-[RuCl2(CO)(2)(2-(4′-methoxyphenyl)-1,8-naphthyridine-kappa N8)(2)] and cis-[RuCl2(CO)(2)(2-(2′-methoxyphenyl)-1,8-naphthyridine-kappa N8)(2)] have been established by X-ray single crystal diffraction studies, which indicate an octahedral geometry with two 1,8-naphthyridine ligands coordinated to the metal in a N-monodentate fashion. The ruthenium(II) complexes have been studied as catalysts in the transfer hydrogenation of acetophenone. We found that complexes show moderate activities and a 100% selectivity. The best turnover frequency (390 h(-1)) is found for cis-[RuCl2(CO)(2)(2-(4′-methoxyphenyl)-1,8-naphthyridine-kappa N8)(2)] when the substrate/catalysis ratio was 1000/1. The catalytic conditions were optimized using different substrate/catalyst and base/catalyst ratios.
SDS of cas: 100-19-6. Bye, fridends, I hope you can learn more about C8H7NO3, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem