Recently I am researching about RING-OPENING POLYMERIZATION; ALKALINE-EARTH METALS; INTRAMOLECULAR HYDROAMINATION; EPSILON-CAPROLACTONE; MAGNESIUM COMPLEXES; EFFICIENT CATALYSTS; HYDRIDE COMPLEXES; ZINC-COMPLEXES; RARE-EARTH; HYDROBORATION, Saw an article supported by the KIT; German Research Foundation (DFG)German Research Foundation (DFG) [INST 40/467-1 FUGG]; Projekt DEAL. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Goswami, B; Feuerstein, TJ; Yadav, R; Koppe, R; Lebedkin, S; Kappes, MM; Roesky, PW. The CAS is 100-19-6. Through research, I have a further understanding and discovery of 1-(4-Nitrophenyl)ethanone. Recommanded Product: 100-19-6
The synthesis of calcium complexes ligated by three different chiral iminophosphonamide ligands, L-H (L=[Ph2P{N(R)CH(CH3)Ph}(2)]), L ‘-H (L ‘=[Ph2P{NDipp}{N(R)CH(CH3)Ph}]), (Dipp=2,6-(Pr2C6H3)-Pr-i), and L ”-H (L ”=[Ph2P{N(R)CH(CH3)naph}(2)]), (naph=naphthyl) is presented. The resulting structures [L2Ca], [L ‘ Ca-2], and [L ” Ca-2] represent the first examples of enantiopure homoleptic calcium complexes based on this type of ligands. The calcium complexes show blue-green photoluminescence (PL) in the solid state, which is especially bright at low temperatures. Whereas the emission of [L ” Ca-2] is assigned to the fluorescence of naphthyl groups, the PL of [L2Ca] and [L ‘ Ca-2] is contributed by long-lived phosphorescence and thermally activated delayed fluorescence (TADF), with a strong variation of the PL lifetimes over the temperature range of 5-295 K. Furthermore, an excellent catalytic activity was found for these complexes in hydroboration of ketones at room temperature, although no enantioselectivity was achieved.
Welcome to talk about 100-19-6, If you have any questions, you can contact Goswami, B; Feuerstein, TJ; Yadav, R; Koppe, R; Lebedkin, S; Kappes, MM; Roesky, PW or send Email.. Recommanded Product: 100-19-6
Reference:
Benzodioxan,
,1,4-Benzodioxane | C8H8O2 – PubChem